By means of improved ligand-field theory, the ＂pure electronic＂ pressure-induced shift （PS） and the PS due to electron-phonon interaction （EPI） of R-line of MgO：Cr^3＋ have been calculated, respectively. The ca...By means of improved ligand-field theory, the ＂pure electronic＂ pressure-induced shift （PS） and the PS due to electron-phonon interaction （EPI） of R-line of MgO：Cr^3＋ have been calculated, respectively. The calculated results are in very good agreement with the experimental data. The behaviors of the pure electronic PS of R-line of MgO：Cr^3＋ and the PS of its R-line due to EPI are different. It is the combined effect of them that gives rise to the total PS of R-line, which has satisfactorily explained the experimental results. The comparison between the feature of R-line PS of MgO：Cr^3＋ and that of R1-line PS of ruby has been made.展开更多
Iron-based single-atom catalysts with nitrogen-doped carbon as support(Fe-SA/NPC)are considered effective alternatives to replace Pt-group metals for scalable application in fuel cells.However,synthesizing high-loadin...Iron-based single-atom catalysts with nitrogen-doped carbon as support(Fe-SA/NPC)are considered effective alternatives to replace Pt-group metals for scalable application in fuel cells.However,synthesizing high-loading Fe-SA catalysts by a simple procedure remains challenging.Herein,we report a high-loading(7.5 wt%)Fe-SA/NPC catalyst prepared by carbon-assisted pyrolysis of metal complexes.Both the nitrogen-doped porous carbon(NPC)support with high specific surface area and ο-phenylenediamine(o-PD)play key roles role in the preparation of high-loading Fe-SA/NPC catalysts.The results of X-ray photoelectron spectroscopy,high-angle annular dark-field scanning transmission electron microscopy,and X-ray absorption fine structure spectroscopy experiments show that the Fe atoms are anchored on the carbon carriers in a single-atom site configuration and coordinated with four of the doped nitrogen atoms of the carbon substrates(Fe-N_(4)).The activities of the Fe-SA/NPC catalysts in the oxygen reduction reaction increased with increasing iron loading.The optimized 250Fe-SA/NPC-800 catalyst exhibited an onset potential 0.97 V of and a half-wave potential of 0.85 V.Our study provides a simple approach for the large-scale synthesis of high-loading single-atom catalysts.展开更多
For the problem that the flow separation on the flap lowers the aerodynamic performance of high lift system,an investigation was carried out on using micro vortex generators(VGs) to control the separation on flap of t...For the problem that the flow separation on the flap lowers the aerodynamic performance of high lift system,an investigation was carried out on using micro vortex generators(VGs) to control the separation on flap of the swept constant chord half-model(SCCH) high-lift configuration,at a small to medium angle of attack,by experimental and numerical methods.The basic flow characteristics of SCCH landing configuration were analyzed by using numerical method to provide required information for the design of micro VGs.Then,by keeping the cruise configuration intact,the preliminary design procedure and design methods of micro VGs were established.In addition,the micro VGs were designed.The effects of VG's arrangement and geometric parameters,such as the arrangement mode,chordwise position,arrangement angle,height and spanwise distance,on controlling efficiency were investigated by using numerical method.Then the parameters of preliminary VGs were adjusted as the basis configuration for wind tunnel test.The experiments were accomplished in NH-2 wind tunnel for validating the numerical method,as well as obtaining the design principles and methods of micro VGs.The parameters of VGs were also optimized based on the experiments.The experimental results showed that the numerical design method can serve as an efficient and accurate design tool.The lift and drag were increased by 10% and 14%,respectively in landing state,which satisfied the requirements for landing.Finally,it was concluded that the established design principles and methods for micro VGs in this investigation can be used in engineering application.展开更多
文摘By means of improved ligand-field theory, the ＂pure electronic＂ pressure-induced shift （PS） and the PS due to electron-phonon interaction （EPI） of R-line of MgO：Cr^3＋ have been calculated, respectively. The calculated results are in very good agreement with the experimental data. The behaviors of the pure electronic PS of R-line of MgO：Cr^3＋ and the PS of its R-line due to EPI are different. It is the combined effect of them that gives rise to the total PS of R-line, which has satisfactorily explained the experimental results. The comparison between the feature of R-line PS of MgO：Cr^3＋ and that of R1-line PS of ruby has been made.
文摘Iron-based single-atom catalysts with nitrogen-doped carbon as support(Fe-SA/NPC)are considered effective alternatives to replace Pt-group metals for scalable application in fuel cells.However,synthesizing high-loading Fe-SA catalysts by a simple procedure remains challenging.Herein,we report a high-loading(7.5 wt%)Fe-SA/NPC catalyst prepared by carbon-assisted pyrolysis of metal complexes.Both the nitrogen-doped porous carbon(NPC)support with high specific surface area and ο-phenylenediamine(o-PD)play key roles role in the preparation of high-loading Fe-SA/NPC catalysts.The results of X-ray photoelectron spectroscopy,high-angle annular dark-field scanning transmission electron microscopy,and X-ray absorption fine structure spectroscopy experiments show that the Fe atoms are anchored on the carbon carriers in a single-atom site configuration and coordinated with four of the doped nitrogen atoms of the carbon substrates(Fe-N_(4)).The activities of the Fe-SA/NPC catalysts in the oxygen reduction reaction increased with increasing iron loading.The optimized 250Fe-SA/NPC-800 catalyst exhibited an onset potential 0.97 V of and a half-wave potential of 0.85 V.Our study provides a simple approach for the large-scale synthesis of high-loading single-atom catalysts.
文摘For the problem that the flow separation on the flap lowers the aerodynamic performance of high lift system,an investigation was carried out on using micro vortex generators(VGs) to control the separation on flap of the swept constant chord half-model(SCCH) high-lift configuration,at a small to medium angle of attack,by experimental and numerical methods.The basic flow characteristics of SCCH landing configuration were analyzed by using numerical method to provide required information for the design of micro VGs.Then,by keeping the cruise configuration intact,the preliminary design procedure and design methods of micro VGs were established.In addition,the micro VGs were designed.The effects of VG's arrangement and geometric parameters,such as the arrangement mode,chordwise position,arrangement angle,height and spanwise distance,on controlling efficiency were investigated by using numerical method.Then the parameters of preliminary VGs were adjusted as the basis configuration for wind tunnel test.The experiments were accomplished in NH-2 wind tunnel for validating the numerical method,as well as obtaining the design principles and methods of micro VGs.The parameters of VGs were also optimized based on the experiments.The experimental results showed that the numerical design method can serve as an efficient and accurate design tool.The lift and drag were increased by 10% and 14%,respectively in landing state,which satisfied the requirements for landing.Finally,it was concluded that the established design principles and methods for micro VGs in this investigation can be used in engineering application.
