Covalent organic framework （COF） is a porous material with low density and large BET （Brtmauer-Emmett-Teller） surface area. They have great potential in gas adsorption and separation. In this work, the adsorption ...Covalent organic framework （COF） is a porous material with low density and large BET （Brtmauer-Emmett-Teller） surface area. They have great potential in gas adsorption and separation. In this work, the adsorption of pure CO2 and CO2/CH4 mixture on modified COF-102 was simulated by using GCMC （grand canonical Monte Carlo）. Metal Li was incorporated into COF-102 through three doping methods, including charge exchange, O^--Li6＋ dipolar interaction and O^--Li^＋ chemical bonding. The influence of Li doping on the adsorption of CO2 was studied. The results showed that among the three methods, the dipole doping is the best way to improve CO2 adsorption performance. Further, the ligands of COF-102 were replaced by extended aromatic moieties, such as diphenyl and pyrene. The adsorption capacity of CO2 and CH4, and the selectivity of CO2/CH4 on the ligand-replaced COF-102 were studied. The capacity of CO2 and CH4 on the ligand-replaced COF-102 had obvious changes; hence the selectivity of CO2/CH4 can be adjusted accordingly.展开更多
Based on daily maximum temperature data from Chinese weather stations for the period 1960- 2013, the characteristics of the interdecadal variability of large-scale extreme hot event （EHE） frequency over the middle a...Based on daily maximum temperature data from Chinese weather stations for the period 1960- 2013, the characteristics of the interdecadal variability of large-scale extreme hot event （EHE） frequency over the middle and lower reaches of the Yangtze River basin （MLYR） are analyzed. It is found that the frequency of large-scale EHE over the MLYR experiences two significant interdecadal changes, around the early 1970s and early 2000s, having a more-less-more variability shape during the past half century. Furthermore, the EHE frequency interdecadal variability-related atmospheric circulation patterns are diagnosed. The results indicate the western Pacific subtropical high could not be the dominant atmospheric circulation associated with the interdecadal variability of the large-scale EHE frequency over the MLYR. In contrast, the dominant teleconnection pattern over the Eurasian continent, which is represented by the second empirical orthogonal function mode of the 200 hPa geopotential height, is closely related to the interdecadal variability of the EHE frequency over the MLYR. The results of this study deepen our understanding of the variability of the EHE frequency over the MLYR and its possible mechanism.展开更多
We present a facile and controllable method for the large-scale fabrication of highly-ordered octahedral Fe3O4 colloidal ＂single crystals＂ without the assistance of a substrate. Oleic acid is used to reduce the solu...We present a facile and controllable method for the large-scale fabrication of highly-ordered octahedral Fe3O4 colloidal ＂single crystals＂ without the assistance of a substrate. Oleic acid is used to reduce the solubility of the nano-building blocks in colloidal solution and to induce a ＂crystallization＂ process. Our colloidal crystals are of multimicron size and show typical crystallographic characteristics. They have a very robust structure and can serve as a novel ordered magnetic mesoporous material with a relatively narrow pore size distribution. The sample possesses an extremely high Verwey transition temperature （Tv） of 100 K and a high saturation magnetization （Ms） of 86 emu/g at 5 K based on its good crystallinity, as well as the interparticle dipolar interaction behavior arising from its unique structure. Electrochemical measurements have demonstrated the excellent capacity of the mesoporous colloidal crystals when used in lithium-ion batteries.展开更多
基金Supported by the National Natural Science Foundation of China （20736002）, the National High Technology Research and Development Program of China （2008AA062302） and Program for Changjiang Scholars and Innovative Research Team in University of China （IRT0721）.
文摘Covalent organic framework （COF） is a porous material with low density and large BET （Brtmauer-Emmett-Teller） surface area. They have great potential in gas adsorption and separation. In this work, the adsorption of pure CO2 and CO2/CH4 mixture on modified COF-102 was simulated by using GCMC （grand canonical Monte Carlo）. Metal Li was incorporated into COF-102 through three doping methods, including charge exchange, O^--Li6＋ dipolar interaction and O^--Li^＋ chemical bonding. The influence of Li doping on the adsorption of CO2 was studied. The results showed that among the three methods, the dipole doping is the best way to improve CO2 adsorption performance. Further, the ligands of COF-102 were replaced by extended aromatic moieties, such as diphenyl and pyrene. The adsorption capacity of CO2 and CH4, and the selectivity of CO2/CH4 on the ligand-replaced COF-102 were studied. The capacity of CO2 and CH4 on the ligand-replaced COF-102 had obvious changes; hence the selectivity of CO2/CH4 can be adjusted accordingly.
基金supported by the National Natural Science Foundation of China[grant number 41421004],[grant number41522503]the External Cooperation Program of the Bureau of International Co-operation,Chinese Academy of Sciences[grant number 134111KYSB20150016]
文摘Based on daily maximum temperature data from Chinese weather stations for the period 1960- 2013, the characteristics of the interdecadal variability of large-scale extreme hot event （EHE） frequency over the middle and lower reaches of the Yangtze River basin （MLYR） are analyzed. It is found that the frequency of large-scale EHE over the MLYR experiences two significant interdecadal changes, around the early 1970s and early 2000s, having a more-less-more variability shape during the past half century. Furthermore, the EHE frequency interdecadal variability-related atmospheric circulation patterns are diagnosed. The results indicate the western Pacific subtropical high could not be the dominant atmospheric circulation associated with the interdecadal variability of the large-scale EHE frequency over the MLYR. In contrast, the dominant teleconnection pattern over the Eurasian continent, which is represented by the second empirical orthogonal function mode of the 200 hPa geopotential height, is closely related to the interdecadal variability of the EHE frequency over the MLYR. The results of this study deepen our understanding of the variability of the EHE frequency over the MLYR and its possible mechanism.
文摘We present a facile and controllable method for the large-scale fabrication of highly-ordered octahedral Fe3O4 colloidal ＂single crystals＂ without the assistance of a substrate. Oleic acid is used to reduce the solubility of the nano-building blocks in colloidal solution and to induce a ＂crystallization＂ process. Our colloidal crystals are of multimicron size and show typical crystallographic characteristics. They have a very robust structure and can serve as a novel ordered magnetic mesoporous material with a relatively narrow pore size distribution. The sample possesses an extremely high Verwey transition temperature （Tv） of 100 K and a high saturation magnetization （Ms） of 86 emu/g at 5 K based on its good crystallinity, as well as the interparticle dipolar interaction behavior arising from its unique structure. Electrochemical measurements have demonstrated the excellent capacity of the mesoporous colloidal crystals when used in lithium-ion batteries.
