The amorphous boron powders with high activity were prepared by the high-energy ball milling-combustion synthesis method. The effects of the milling rate and milling time on the crystallinity, microscopic morphology a...The amorphous boron powders with high activity were prepared by the high-energy ball milling-combustion synthesis method. The effects of the milling rate and milling time on the crystallinity, microscopic morphology and reactivity of amorphous boron powder were studied. The results show that the crystallinity of amorphous nano-boron powder is only 22.5%, and its purity reaches 92.86%. The high-energy ball milling can significantly refine boron powder particle sizes, whose average particle sizes are smaller than 50 nm, and specific surface areas are of up to 70.03 m2/g. When the transmission electron beam irradiates the samples, they rapidly melt. It can be seen that the monomer amorphous boron size is less than 30 nm from the specimen melting traces, which indicates that the samples have high reactivity.展开更多
The difference of soluble sugar contents and starch synthetic key enzyme activities between high starch cultivar and low starch cultivar were studied in this experiment, of which FuXuan01, GR891, SC124, and SC201 were...The difference of soluble sugar contents and starch synthetic key enzyme activities between high starch cultivar and low starch cultivar were studied in this experiment, of which FuXuan01, GR891, SC124, and SC201 were used as materials. The results showed that the contents of reducing sugar in root tube of low starch cultivars were higher than those of high starch cultivars in all growth periods, the contents of sucrose in root tube of high starch cultivar were higher than those of low starch cultivars in the early growth period, but, lower in the late growth period, and there were almost no difference in the contents of soluble sugar in root tube between high starch cultivar and low starch cultivar in the early growth period, but notable difference in the late growth period and the soluble sugar contents of low starch cultivars were higher than those of high starch cultivars. It also-showed that the activities of ADPGPpase, SSS, and SBE (starch branching enzyme) of high starch cultivars were higher than those of low starch cultivars. It was evident that there were close correlations between the content of sucrose, reducing sugar and soluble sugar in root tube, and the activities of ADPGPpase, SSS, SBE, and the starch accumulation in the root tubers of cassava. It was quite evident in this experiment that the soluble sugar and starch synthetic key enzyme were main factors controlling starch accumulation in root tubers. These results provided important indication for physiological controlling in high starch cultivation and gene engineering breeding of high starch cultivar of cassava.展开更多
The mycotoxin, patulin (4-hydroxy-4H-furo [3, 2c] pyran-2 [6H]-one), is produced by a number of fungi common to fruit and vegetable-based products, most notably apples. Patulin contamination within apple products po...The mycotoxin, patulin (4-hydroxy-4H-furo [3, 2c] pyran-2 [6H]-one), is produced by a number of fungi common to fruit and vegetable-based products, most notably apples. Patulin contamination within apple products poses a serious health risk to consumers. Studies done on laboratory animals have demonstrated that patulin has a broad spectrum of toxicity, including mutagen city and carcinogenicity. The aim of the experiment was studying influence of selectively acting activated carbon powder--Ercarbon SH (Erbsloh, Germany) which is special produced for lowering HMF (hydroxy methyl furfural), on reduction of patulin content in clear apple juice. Industrial apple row material with some damaged parts was pressed, juice was pasteurized at 95 ℃ during 2 min. After cooling on 55 ℃, enzymatic treated and clarified juice were filtered by 0.45 [am pore sizes membrane filter, Apple clear juice sample was divided for five parts. The samples of apple juice were diluted to 11.5° Brix and contacted with concentrations of 2, 2.5, 3 and 3.5 g/L activated carbon powder for 30 min. After filtration in the experimental samples, putulin was quantitatively determined by HPLC (high performance liquid chromatography with UV) detector at 276 nm. The research revealed that the best results were achieved by treatment with activated carbon in its powder form at concentration of 2.5 g/L with 30 min contact time.展开更多
Reactive powder concrete (RPC) is vulnerable to explosive spalling when exposed to high temperature. The characteristics of micro pore structure and vapor pressure of RPC are closely related to the thermal spalling....Reactive powder concrete (RPC) is vulnerable to explosive spalling when exposed to high temperature. The characteristics of micro pore structure and vapor pressure of RPC are closely related to the thermal spalling. Applying mercury intrusion po- rosimetry (MIP) and scanning electron microscopy (SEM) techniques, the authors probed the characteristics of micro pore structures of plain RPC200 when heated from 20-350~C. The pore characteristics such as specific pore volume, threshold pore size and most probable pore size varying with temperatures were investigated. A vapor pressure kit was developed to measure the vapor pressure and its variation inside RPC200 at various temperatures. A thin-wall spherical pore model was proposed to ana- lyze the thermo-mechanical mechanism of spalling, by which the stresses varying with the vapor pressure q(T) and the character- istic size of wall (K) at any point of interest were determined. It is shown that the pore characteristics including specific pore volume, average pore size, threshold pore size and most probable pore size rise significantly with the increasing temperature. 200~C appears to be the threshold temperature above which the threshold pore size and the most probable pore size climb up dramatically. The increase in the specific pore volume results from the growth both in quantity and in volume of the transition pores and the capillary pores. The appearance of the explosive spalling in RPC200 is mainly attributed to being unable to form pathways in favor of releasing water steam in RPC and to thin-wall sphere domain where the vapor pressure governs the the rapid accumulation of high vapor pressures as well. The spalling is bounded through the pore model.展开更多
基金Project(51002025)supported by the National Natural Science Foundation of China
文摘The amorphous boron powders with high activity were prepared by the high-energy ball milling-combustion synthesis method. The effects of the milling rate and milling time on the crystallinity, microscopic morphology and reactivity of amorphous boron powder were studied. The results show that the crystallinity of amorphous nano-boron powder is only 22.5%, and its purity reaches 92.86%. The high-energy ball milling can significantly refine boron powder particle sizes, whose average particle sizes are smaller than 50 nm, and specific surface areas are of up to 70.03 m2/g. When the transmission electron beam irradiates the samples, they rapidly melt. It can be seen that the monomer amorphous boron size is less than 30 nm from the specimen melting traces, which indicates that the samples have high reactivity.
文摘The difference of soluble sugar contents and starch synthetic key enzyme activities between high starch cultivar and low starch cultivar were studied in this experiment, of which FuXuan01, GR891, SC124, and SC201 were used as materials. The results showed that the contents of reducing sugar in root tube of low starch cultivars were higher than those of high starch cultivars in all growth periods, the contents of sucrose in root tube of high starch cultivar were higher than those of low starch cultivars in the early growth period, but, lower in the late growth period, and there were almost no difference in the contents of soluble sugar in root tube between high starch cultivar and low starch cultivar in the early growth period, but notable difference in the late growth period and the soluble sugar contents of low starch cultivars were higher than those of high starch cultivars. It also-showed that the activities of ADPGPpase, SSS, and SBE (starch branching enzyme) of high starch cultivars were higher than those of low starch cultivars. It was evident that there were close correlations between the content of sucrose, reducing sugar and soluble sugar in root tube, and the activities of ADPGPpase, SSS, SBE, and the starch accumulation in the root tubers of cassava. It was quite evident in this experiment that the soluble sugar and starch synthetic key enzyme were main factors controlling starch accumulation in root tubers. These results provided important indication for physiological controlling in high starch cultivation and gene engineering breeding of high starch cultivar of cassava.
文摘The mycotoxin, patulin (4-hydroxy-4H-furo [3, 2c] pyran-2 [6H]-one), is produced by a number of fungi common to fruit and vegetable-based products, most notably apples. Patulin contamination within apple products poses a serious health risk to consumers. Studies done on laboratory animals have demonstrated that patulin has a broad spectrum of toxicity, including mutagen city and carcinogenicity. The aim of the experiment was studying influence of selectively acting activated carbon powder--Ercarbon SH (Erbsloh, Germany) which is special produced for lowering HMF (hydroxy methyl furfural), on reduction of patulin content in clear apple juice. Industrial apple row material with some damaged parts was pressed, juice was pasteurized at 95 ℃ during 2 min. After cooling on 55 ℃, enzymatic treated and clarified juice were filtered by 0.45 [am pore sizes membrane filter, Apple clear juice sample was divided for five parts. The samples of apple juice were diluted to 11.5° Brix and contacted with concentrations of 2, 2.5, 3 and 3.5 g/L activated carbon powder for 30 min. After filtration in the experimental samples, putulin was quantitatively determined by HPLC (high performance liquid chromatography with UV) detector at 276 nm. The research revealed that the best results were achieved by treatment with activated carbon in its powder form at concentration of 2.5 g/L with 30 min contact time.
基金supported by the National Science Foundation for Distin-guished Young Scholars of China (Grant No. 51125017)the National Natural Science Foundation of China (Grant No. 50974125)+1 种基金the ResearchFund for Doctoral Programs of Chinese Ministry of Education (Grant No.20110023110015)the National Basic Research Program of China("973" Project)(Grant Nos. 2010CB226804,2011CB201201)
文摘Reactive powder concrete (RPC) is vulnerable to explosive spalling when exposed to high temperature. The characteristics of micro pore structure and vapor pressure of RPC are closely related to the thermal spalling. Applying mercury intrusion po- rosimetry (MIP) and scanning electron microscopy (SEM) techniques, the authors probed the characteristics of micro pore structures of plain RPC200 when heated from 20-350~C. The pore characteristics such as specific pore volume, threshold pore size and most probable pore size varying with temperatures were investigated. A vapor pressure kit was developed to measure the vapor pressure and its variation inside RPC200 at various temperatures. A thin-wall spherical pore model was proposed to ana- lyze the thermo-mechanical mechanism of spalling, by which the stresses varying with the vapor pressure q(T) and the character- istic size of wall (K) at any point of interest were determined. It is shown that the pore characteristics including specific pore volume, average pore size, threshold pore size and most probable pore size rise significantly with the increasing temperature. 200~C appears to be the threshold temperature above which the threshold pore size and the most probable pore size climb up dramatically. The increase in the specific pore volume results from the growth both in quantity and in volume of the transition pores and the capillary pores. The appearance of the explosive spalling in RPC200 is mainly attributed to being unable to form pathways in favor of releasing water steam in RPC and to thin-wall sphere domain where the vapor pressure governs the the rapid accumulation of high vapor pressures as well. The spalling is bounded through the pore model.