It is proved that the treatment with white mulch and black thin films per- formed the best in terms of heat preservation in cultivation of strawberry with shelves. In winter, drip irrigation performed significantly in...It is proved that the treatment with white mulch and black thin films per- formed the best in terms of heat preservation in cultivation of strawberry with shelves. In winter, drip irrigation performed significantly in transporting hot water through solar energy. The combination of the two methods resolved the issue of heat preservation difficulty and guaranteed growth of strawberry in winter.展开更多
As is well known, deep mines are hot. As mining depth increases, the temperature of the surrounding rock also increases. This seriously affects mine safety and production and has restricted the exploitation of deep co...As is well known, deep mines are hot. As mining depth increases, the temperature of the surrounding rock also increases. This seriously affects mine safety and production and has restricted the exploitation of deep coal resources. Therefore, reducing the working face temperature to improve working conditions by controlling these heat hazards is an urgent problem. Considering problems in cooling deep mines both domestically and abroad along with the actual conditions of the Zhangshuanglou coal mine, we propose a HEMS technology that uses heat resources from deep mines in a stepwise manner. HEMS means a high temperature ex-change machinery system. Mine inrush-water is used as a source of cooling. Twice the energy is extracted from the mine inrush water. Heat is used for building heating in the winter and cold water is used for cooling buildings in the summer. This opens a new technology for stepwise utilization of heat energy in deep mines. Energy conservation and reduced pollution, an improved environment and sustainable economic development are realized by this technique. The economic and social effects are obvious and illustrate a good prospect for the application and extension of the method.展开更多
After the first concrete was poured on December 9, 2012 at the Shidao Bay site in Rongcheng, Shandong Province, China, the construction of the reactor building for the world's first high-temperature gas- cooled react...After the first concrete was poured on December 9, 2012 at the Shidao Bay site in Rongcheng, Shandong Province, China, the construction of the reactor building for the world's first high-temperature gas- cooled reactor pebble-bed module (HTR-PM) demonstration power plant was completed in June, 2015. Installation of the main equipment then began, and the power plant is currently progressing well to- ward connecting to the grid at the end of 2017. The thermal power of a single HTR-PM reactor module is 250 MW,h, the helium temperatures at the reactor core inlet/outlet are 250/750 ℃, and a steam of 13.25 MPa/567 ~C is produced at the steam generator outlet. Two HTR-PM reactor modules are connect- ed to a steam turbine to form a 210 MW nuclear power plant. Due to China's industrial capability, we were able to overcome great difficulties, manufacture first-of-a-kind equipment, and realize series ma- jor technological innovations. We have achieved successful results in many aspects, including planning and implementing R&D, establishing an industrial partnership, manufacturing equipment, fuel produc- tion, licensing, site preparation, and balancing safety and economics; these obtained experiences may also be referenced by the global nuclear community.展开更多
Poly ( m-phenylene isophthalamine) (PMIA) and Poly( p-phenylene terphthalamine) (PPTA) are among the most important high-temperature resistant aramid fibers. The pyrolysis behaviors of these two fibers under i...Poly ( m-phenylene isophthalamine) (PMIA) and Poly( p-phenylene terphthalamine) (PPTA) are among the most important high-temperature resistant aramid fibers. The pyrolysis behaviors of these two fibers under inert gases were studied using pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) and thermogravimetric analysis coupled with mass spectrometry ( TGA-DTA/MS ). The pyrolysis processes of PMIA and PPTA are distinguishing, and the stepwise pyrolysates reflect these differences. A mechanism system of pyrolysis is suggested, which involving hydrolysis and homolysis, At low pyrolysis temperatures, hydrolysis is a primary reaction, and it is very noticeable in the first-step pyrolysis region of PMIA. Elevating pyrolysis temperature, homolysis is enhanced and keep a large advantage in the high temperature range. On the other hand, at higher temperatures, carbonization happens and the homolysis and carbonization of PPTA are emphasized more than of PMIA.展开更多
In 2005, the US passed the Energy Policy Act of 2005 mandating the construction and operation of a high-temperature gas reactor (HTGR) by 2021. This law was passed after a multiyear study by national experts on what...In 2005, the US passed the Energy Policy Act of 2005 mandating the construction and operation of a high-temperature gas reactor (HTGR) by 2021. This law was passed after a multiyear study by national experts on what future nuclear technologies should be developed. As a result of the Act, the US Congress chose to develop the so-called Next-Generation Nuclear Plant, which was to be an HTGR designed to produce process heat for hydrogen production. Despite high hopes and expectations, the current status is that high temperature reactors have been relegated to completing research programs on advanced fuels, graphite and materials with no plans to build a demonstration plant as required by the US Con- gress in 2005. There are many reasons behind this diminution of HTGR development, including but not limited to insufficient government funding requirements for research, unrealistically high temperature requirements for the reactor, the delay in the need for a "hydrogen" economy, competition from light water small modular light water reactors, little utility interest in new technologies, very low natural gas prices in the US, and a challenging licensing process in the US for non-water reactors.展开更多
Naval ship deperming is effective to reduce the potential damage from sea mines some of which sense magnetic field of the ship, and thus, is an important treatment of naval ships in the recent world. Large electric cu...Naval ship deperming is effective to reduce the potential damage from sea mines some of which sense magnetic field of the ship, and thus, is an important treatment of naval ships in the recent world. Large electric current is required to impose the magnetic field on the ship hull, which in turn means that the deperming coil needs to be wound on ship hull when the coil is composed of conventional conductive materials, such as copper. We considered a few HTS (high temperature superconducting) coil systems to deperm naval ships because we expect the shorter deperming time and lower manual workload for ship deperming operation, compared conventional conductor coil systems. We have in the past presented a solution using a fiat two-coil system arranged on seabed with tightly bound HTS conductor by analytical calculation of magnetic field on the conductor. By considering present and already developed technologies, a conductor with cylindrically wound on the core arranged as fiat multi-turn coils on seabed was designed using analytical methods.展开更多
In the research of primary spectrum pyrometry, this paper discussed the definition problem of radiation temperature measurement area based on the measurement coordinates. For the linear spectrum emissivity model and i...In the research of primary spectrum pyrometry, this paper discussed the definition problem of radiation temperature measurement area based on the measurement coordinates. For the linear spectrum emissivity model and improved monotonic spectrum emissivity model, the characteristics of radiation temperature measurement area restricted by the measurement coordinates were theoretically analyzed, through the investigations of the temperature and emissivity coordinate axes. Choosing the specific primary spectrum pyrometer as an example in applications, the theoretical area of radiation temperature measurement of this pyrometer was given and it was verified through blackbody experiments. The discussions of this paper will provide the necessary foundation for the theory research development of primary spectrum pyrometry and the realization of technical applications.展开更多
A detailed mechanism analysis of cellulose pyrolysis was carried out according to the previous experimental results. On the basis of the Brodio-Shafizadeh model, a modified two-stage model was proposed to simulate the...A detailed mechanism analysis of cellulose pyrolysis was carried out according to the previous experimental results. On the basis of the Brodio-Shafizadeh model, a modified two-stage model was proposed to simulate the formation and decomposition of active cellulose (AC) and several main organic compounds, such as levoglucosan (LG), hydroxyl-acetaldehyde (HAA), acetol and furfural etc. During pryolysis, the temperature rise of cellulose can be divided into three stages. In the second stage, cellulose undergoes a main decomposition process in which the reaction temperature remains rather low because of the endothermic cracking of glucosidic bond of AC during the formation of LG. The components density of bio-oil, including LG and other competitive compounds, increased rapidly with the increase of temperature during the first stage. However, in the main decomposition process, LG density in bio-oil had an obvious decrease, while the competitive products appeared to increase gradually, which means the ring-opening and reforming reaction of pyranoid ring are superior to LG formation in high temperature.The secondary reaction of volatile components occurs largely in gaseous phase rather than in the solid phase. Short residence time of volatile materials in high temperature region will be advantageous to a high production of LG,which may otherwise decompose quickly under high temperature. An optimum yield of LG could be obtained when radiant source temperature is in the range of 730---920K and gas residence time is less than 1 s. In addition, the reaction temperature has a stronger effect than gas residence time on the formation of HAA, acetol, formaldehyde and furfural etc.展开更多
The pyrolysis mechanism of rice straw (RS) was investigated using a tube reactor with Fourier trans-form infrared (FTIR) spectroscopy and thermogravimetric analyzer. The results show that the maximum pyrolysis rate in...The pyrolysis mechanism of rice straw (RS) was investigated using a tube reactor with Fourier trans-form infrared (FTIR) spectroscopy and thermogravimetric analyzer. The results show that the maximum pyrolysis rate increases with increasing heating rate and the corresponding temperature also increases. The three-pseudocomponent model could describe the pyrolysis behavior of rice straw accurately. The main pyrolysis gas products are H2O, CO2, CO, CH4, HCHO (formaldehyde), HCOOH (formic acid), CH3OH (methanol), C6H5OH (phenol), etc. The releasing of H2O, CO2, CO and CH4 mainly focuses at 220-400°C. The H2O formation process is separated into two stages corresponding to the evaporation of free water and the formation of primary volatiles. The release of CO2 first increases with increasing temperature and gets the maximum at 309°C. The releasing behavior of CO is similar to H2O and CO2 between 200 and 400°C. The production of CH4 happens, compared to CO2 and CO, at higher temperatures of 275-400°C with the maximum at 309°C. When the temperature exceeds 200°C, hy-droxyl and aliphatic C H groups decrease significantly, while C O, olefinic C C bonds and ether structures in-crease first in the chars and then the aromatic structure develops with rising temperature. Above 500°C, the material becomes increasingly more aromatic and the ether groups decreases with an increase of temperature. The aromati-zation process starts at ≈350°C and continues to higher temperatures.展开更多
In order to define the development direction of safe blasting technology in high-temperature coal seams in China, this paper presents a systematic, state-of-the-art review on safe blasting technology. Information such...In order to define the development direction of safe blasting technology in high-temperature coal seams in China, this paper presents a systematic, state-of-the-art review on safe blasting technology. Information such as high-temperature coal fire extinguishment and cooling, anti-high-temperature blasting supplies, heat insulation blasting setting, operation procedures for high-temperature blasting, and so on, are presented. Analysis shows that the development of effective technology for coal seam fire extinguishing and cooling, the manufacture of anti-high-temperature blasting supplies, especially priming materials, the development of heat insulation blasting setting, and the establishment of technical specifications suit large-scale blasting design and construction work at high-temperature coal seams, are the essential methods for safe blasting at high temperature coal seams.展开更多
Post-combustion amine absorption and stripping can remove 90% of the CO2 from power plant flue gas, but systems can reduce electrical output by approximately 30% due to energy requirements for stripping CO2 from solve...Post-combustion amine absorption and stripping can remove 90% of the CO2 from power plant flue gas, but systems can reduce electrical output by approximately 30% due to energy requirements for stripping CO2 from solvent and CO2 compression. The CO2 capture energy penalty can be reduced while developing renewable energy technologies by meeting CO2 capture energy requirements with a solar thermal energy system, particularly when electricity demand and prices are the highest. This study presents an initial review of solar thermal technologies for supplying CO2 capture energy, with a focus on high temperature systems. Parabolic troughs and central receivers are technically able to provide energy for CO2 capture. However, the solar system's capital costs would be roughly half that of the base coal-fired plant with CO2 capture, and high electricity prices are required to offset the costs of operating the solar thermal system. For high temperature solar thermal systems, direct electricity generation is likely a more efficient way to use solar energy to replace output lost to CO2 capture energy. However, low temperature solar thermal systems might integrate better with solvent stripping equipment, and more rigorous analysis is required to definitively assess the feasibility of using solar energy for CO2 capture.展开更多
A kind of denitrifier HY-1 initially obtained from activated sludge was domesticated and inducted with UV and illumination to a new species bacterium HY-2 that has high bioactivity at low temperature. HY-2 was most ac...A kind of denitrifier HY-1 initially obtained from activated sludge was domesticated and inducted with UV and illumination to a new species bacterium HY-2 that has high bioactivity at low temperature. HY-2 was most active at 13 ℃. Nitrate and CODcr removal efficiency was investigated under different temperature and C/N ratio.展开更多
Oxidation behaviors of Ni(Cr)-TiB2 coating deposited by HVOF technique were studied at 800,900 and 1 000℃in air. The microstructures of as-sprayed and oxidized coatings were characterized by X-ray diffractometry(XRD)...Oxidation behaviors of Ni(Cr)-TiB2 coating deposited by HVOF technique were studied at 800,900 and 1 000℃in air. The microstructures of as-sprayed and oxidized coatings were characterized by X-ray diffractometry(XRD)and scanning electron microscopy(SEM).After oxidation at 800℃,a thin and adherent oxide layer was formed on the surface of the coating.With increasing exposure temperature,the thickness of the oxide layer increased;and at 1 000℃the oxide layer separated from the coating.Investigation of the kinetics of oxidation by using the thermogravimetric analysis(TGA)technique shows a parabolic oxidation rate.展开更多
Fluorosilicone oil is polysiloxane with alkyl side chains containing fluorine, and because of its excellent thermal oxidation stability, cold flow property and cryogenic property, it can be widely used as a high tempe...Fluorosilicone oil is polysiloxane with alkyl side chains containing fluorine, and because of its excellent thermal oxidation stability, cold flow property and cryogenic property, it can be widely used as a high temperature lubricant in the field of military aerospace industry. Two kinds of fluorosilicone oils, FSiO-a and FSiO-b, were synthesized by different pro- cessing means. FTICR MS was used to collect the information on composition and structure of the two polymers, respec- tively. The test results show that the two fluorosilicone oils have different contents of fluorine-containing chain segments (m/ n value), the maximum distribution of m/n value of FSiO-a oil ranges from 0.22 to 0.25, and that of FSiO-b oil ranges from 0.4 to 0.67. Difference in synthesis techniques makes this discrepancy and affects the quality and thermal stability of the fluoro- silicone oils.展开更多
we have developed ferroelectric capacitor fabrication technique to realize low-voltage and high-density ferroelectric random access memory (FRAM). High temperature deposited IrOxtop electrode reveals high crystallin...we have developed ferroelectric capacitor fabrication technique to realize low-voltage and high-density ferroelectric random access memory (FRAM). High temperature deposited IrOxtop electrode reveals high crystalline quality which drastically reduces the degradation of ferroelectric film by preventing hydrogen diffusion into ferroelectric film. This improvement enables us to commercialize highly-reliable 1T 1C FRAM with memory density of 4 Mb or larger.展开更多
With the self-made pyrolysis equipment in miniature, we experimented in different pyrolysis conditions to get different pyrolyzate yields ( carbon, vinegar and gas). It proved that with the rise of temperature, the av...With the self-made pyrolysis equipment in miniature, we experimented in different pyrolysis conditions to get different pyrolyzate yields ( carbon, vinegar and gas). It proved that with the rise of temperature, the average yield of carbon descends gradually while the yields of vinegar and gas rise gradually. As the temperature rises, the yield of gas increases much more than that of vinegar. When speeding up the rising temperature, yield of carbon goes down while yields of vinegar and gas go up.展开更多
Damage tolerance of titanium alloy structures is very important for the safety of modern aircraft under complex loading and environmental conditions. However, there is no available systematic knowledge about the effec...Damage tolerance of titanium alloy structures is very important for the safety of modern aircraft under complex loading and environmental conditions. However, there is no available systematic knowledge about the effect of alloy thickness under mixed-mode loading at elevated temperatures. In the present study, a newly developed fracture experimental technique based on high-temperature moiré interferometry was employed to investigate experimentally I-II mixed-mode fracture in titanium alloy TC11 of various thicknesses at room and elevated temperatures. Compact shear specimens with thickness ranging from 1.8 to 7.1 mm were tested. The effects of temperature, thickness, and loading angle on the load capacity and crack initiation angle were investigated systematically. The TC11 alloy was shown to possess varied fracture performance at elevated tem-perature, and an opposite thickness effect at room temperature. Increasing temperature would enhance the fracture load capacity of thick specimens but reduce the fracture load capacity of thin specimens. Crack initiation angles under I-II mixed-mode loading showed the thickness-temperature coupling effects. These complex effects call for new development in three-dimensional mixed-mode fracture theory and technologies for damage tolerance assessment.展开更多
Hydrous minerals are important water carriers in the crust and the mantle, especially in the subduction zone. With the recent development of the experimental technique, studies of the electrical conductivity of hydrou...Hydrous minerals are important water carriers in the crust and the mantle, especially in the subduction zone. With the recent development of the experimental technique, studies of the electrical conductivity of hydrous silicate minerals under controlled temperature, pressure and oxygen fugacity, have helped to constrain the water distribution in the Earth's interior. This paper introduces high pressure and temperature experimental study of electrical conductivity measurement of hydrous minerals such as serpentine, talc, brucite, phase A, super hydrous phase B and phase D, and assesses the data quality of the above minerals. The dehydration effect and the pressure effect on the bulk conductivity of the hydrous minerals are specifically emphasized. The conduction mechanism of hydrous minerals and the electrical structure of the subduction zone are discussed based on the available conductivity data. Finally, the potential research fields of the electrical conductivity of hydrous minerals is presented.展开更多
In view of the high voltage, the strong magnetic field environment of the high-voltage switchgear, the system based on the optical wireless sensing technology, realizes the isolated contact temperature monitoring of t...In view of the high voltage, the strong magnetic field environment of the high-voltage switchgear, the system based on the optical wireless sensing technology, realizes the isolated contact temperature monitoring of the high-voltage switchgear. In this scheme, the good thermal conductivity and insulation ceramic materials were selected as the outer jacket material sensing probe, and the program had a good solution to the problem of high and low voltage isolation; The combination of the optical fiber composite insulators for wireless sensing, not only solves the problem of high voltage insulation, but also avoids the "creeping" phenomenon due to dust. The package of the structure and reasonable installation solves the cross sensitivity of strain. The application showed that the precision of temperature measurement of the system could reach ± 0.5 ℃ and could work in a variety of harsh environments. It could improve the reliability of the operation of the electrical equipment significantly and has considerable practical value for the whole power system.展开更多
基金Supported by Zhenjiang Science&Technology Pillar Program(NY2013001)~~
文摘It is proved that the treatment with white mulch and black thin films per- formed the best in terms of heat preservation in cultivation of strawberry with shelves. In winter, drip irrigation performed significantly in transporting hot water through solar energy. The combination of the two methods resolved the issue of heat preservation difficulty and guaranteed growth of strawberry in winter.
基金Financial support for this project, provided by the National Basic Research Program of China (No. 2006CB202200)the National Major Project of Ministry of Education (No.304005) the Program for Changjiang Scholars and Innovative Research Team in University of China (No.IRT0656), is gratefully acknowledged
文摘As is well known, deep mines are hot. As mining depth increases, the temperature of the surrounding rock also increases. This seriously affects mine safety and production and has restricted the exploitation of deep coal resources. Therefore, reducing the working face temperature to improve working conditions by controlling these heat hazards is an urgent problem. Considering problems in cooling deep mines both domestically and abroad along with the actual conditions of the Zhangshuanglou coal mine, we propose a HEMS technology that uses heat resources from deep mines in a stepwise manner. HEMS means a high temperature ex-change machinery system. Mine inrush-water is used as a source of cooling. Twice the energy is extracted from the mine inrush water. Heat is used for building heating in the winter and cold water is used for cooling buildings in the summer. This opens a new technology for stepwise utilization of heat energy in deep mines. Energy conservation and reduced pollution, an improved environment and sustainable economic development are realized by this technique. The economic and social effects are obvious and illustrate a good prospect for the application and extension of the method.
文摘After the first concrete was poured on December 9, 2012 at the Shidao Bay site in Rongcheng, Shandong Province, China, the construction of the reactor building for the world's first high-temperature gas- cooled reactor pebble-bed module (HTR-PM) demonstration power plant was completed in June, 2015. Installation of the main equipment then began, and the power plant is currently progressing well to- ward connecting to the grid at the end of 2017. The thermal power of a single HTR-PM reactor module is 250 MW,h, the helium temperatures at the reactor core inlet/outlet are 250/750 ℃, and a steam of 13.25 MPa/567 ~C is produced at the steam generator outlet. Two HTR-PM reactor modules are connect- ed to a steam turbine to form a 210 MW nuclear power plant. Due to China's industrial capability, we were able to overcome great difficulties, manufacture first-of-a-kind equipment, and realize series ma- jor technological innovations. We have achieved successful results in many aspects, including planning and implementing R&D, establishing an industrial partnership, manufacturing equipment, fuel produc- tion, licensing, site preparation, and balancing safety and economics; these obtained experiences may also be referenced by the global nuclear community.
文摘Poly ( m-phenylene isophthalamine) (PMIA) and Poly( p-phenylene terphthalamine) (PPTA) are among the most important high-temperature resistant aramid fibers. The pyrolysis behaviors of these two fibers under inert gases were studied using pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) and thermogravimetric analysis coupled with mass spectrometry ( TGA-DTA/MS ). The pyrolysis processes of PMIA and PPTA are distinguishing, and the stepwise pyrolysates reflect these differences. A mechanism system of pyrolysis is suggested, which involving hydrolysis and homolysis, At low pyrolysis temperatures, hydrolysis is a primary reaction, and it is very noticeable in the first-step pyrolysis region of PMIA. Elevating pyrolysis temperature, homolysis is enhanced and keep a large advantage in the high temperature range. On the other hand, at higher temperatures, carbonization happens and the homolysis and carbonization of PPTA are emphasized more than of PMIA.
文摘In 2005, the US passed the Energy Policy Act of 2005 mandating the construction and operation of a high-temperature gas reactor (HTGR) by 2021. This law was passed after a multiyear study by national experts on what future nuclear technologies should be developed. As a result of the Act, the US Congress chose to develop the so-called Next-Generation Nuclear Plant, which was to be an HTGR designed to produce process heat for hydrogen production. Despite high hopes and expectations, the current status is that high temperature reactors have been relegated to completing research programs on advanced fuels, graphite and materials with no plans to build a demonstration plant as required by the US Con- gress in 2005. There are many reasons behind this diminution of HTGR development, including but not limited to insufficient government funding requirements for research, unrealistically high temperature requirements for the reactor, the delay in the need for a "hydrogen" economy, competition from light water small modular light water reactors, little utility interest in new technologies, very low natural gas prices in the US, and a challenging licensing process in the US for non-water reactors.
文摘Naval ship deperming is effective to reduce the potential damage from sea mines some of which sense magnetic field of the ship, and thus, is an important treatment of naval ships in the recent world. Large electric current is required to impose the magnetic field on the ship hull, which in turn means that the deperming coil needs to be wound on ship hull when the coil is composed of conventional conductive materials, such as copper. We considered a few HTS (high temperature superconducting) coil systems to deperm naval ships because we expect the shorter deperming time and lower manual workload for ship deperming operation, compared conventional conductor coil systems. We have in the past presented a solution using a fiat two-coil system arranged on seabed with tightly bound HTS conductor by analytical calculation of magnetic field on the conductor. By considering present and already developed technologies, a conductor with cylindrically wound on the core arranged as fiat multi-turn coils on seabed was designed using analytical methods.
基金This research was supported by the National Natural Science Foundation of China ( Grant No. 50606033);National High Technology Research and Development Program of China (Grant No. 2007AA04Z178 )
文摘In the research of primary spectrum pyrometry, this paper discussed the definition problem of radiation temperature measurement area based on the measurement coordinates. For the linear spectrum emissivity model and improved monotonic spectrum emissivity model, the characteristics of radiation temperature measurement area restricted by the measurement coordinates were theoretically analyzed, through the investigations of the temperature and emissivity coordinate axes. Choosing the specific primary spectrum pyrometer as an example in applications, the theoretical area of radiation temperature measurement of this pyrometer was given and it was verified through blackbody experiments. The discussions of this paper will provide the necessary foundation for the theory research development of primary spectrum pyrometry and the realization of technical applications.
基金Supported by the National Natural Science Foundation of China (No. 50176046)Guangdong Government Natural Science Foundation (No. 003045)The experiments in the paper were finished in Zhejiang University.
文摘A detailed mechanism analysis of cellulose pyrolysis was carried out according to the previous experimental results. On the basis of the Brodio-Shafizadeh model, a modified two-stage model was proposed to simulate the formation and decomposition of active cellulose (AC) and several main organic compounds, such as levoglucosan (LG), hydroxyl-acetaldehyde (HAA), acetol and furfural etc. During pryolysis, the temperature rise of cellulose can be divided into three stages. In the second stage, cellulose undergoes a main decomposition process in which the reaction temperature remains rather low because of the endothermic cracking of glucosidic bond of AC during the formation of LG. The components density of bio-oil, including LG and other competitive compounds, increased rapidly with the increase of temperature during the first stage. However, in the main decomposition process, LG density in bio-oil had an obvious decrease, while the competitive products appeared to increase gradually, which means the ring-opening and reforming reaction of pyranoid ring are superior to LG formation in high temperature.The secondary reaction of volatile components occurs largely in gaseous phase rather than in the solid phase. Short residence time of volatile materials in high temperature region will be advantageous to a high production of LG,which may otherwise decompose quickly under high temperature. An optimum yield of LG could be obtained when radiant source temperature is in the range of 730---920K and gas residence time is less than 1 s. In addition, the reaction temperature has a stronger effect than gas residence time on the formation of HAA, acetol, formaldehyde and furfural etc.
基金Supported by the Special Funds for Major State Basic Research Projects of China (2004CB217704)the National NaturalScience Foundation of China (50721005)
文摘The pyrolysis mechanism of rice straw (RS) was investigated using a tube reactor with Fourier trans-form infrared (FTIR) spectroscopy and thermogravimetric analyzer. The results show that the maximum pyrolysis rate increases with increasing heating rate and the corresponding temperature also increases. The three-pseudocomponent model could describe the pyrolysis behavior of rice straw accurately. The main pyrolysis gas products are H2O, CO2, CO, CH4, HCHO (formaldehyde), HCOOH (formic acid), CH3OH (methanol), C6H5OH (phenol), etc. The releasing of H2O, CO2, CO and CH4 mainly focuses at 220-400°C. The H2O formation process is separated into two stages corresponding to the evaporation of free water and the formation of primary volatiles. The release of CO2 first increases with increasing temperature and gets the maximum at 309°C. The releasing behavior of CO is similar to H2O and CO2 between 200 and 400°C. The production of CH4 happens, compared to CO2 and CO, at higher temperatures of 275-400°C with the maximum at 309°C. When the temperature exceeds 200°C, hy-droxyl and aliphatic C H groups decrease significantly, while C O, olefinic C C bonds and ether structures in-crease first in the chars and then the aromatic structure develops with rising temperature. Above 500°C, the material becomes increasingly more aromatic and the ether groups decreases with an increase of temperature. The aromati-zation process starts at ≈350°C and continues to higher temperatures.
文摘In order to define the development direction of safe blasting technology in high-temperature coal seams in China, this paper presents a systematic, state-of-the-art review on safe blasting technology. Information such as high-temperature coal fire extinguishment and cooling, anti-high-temperature blasting supplies, heat insulation blasting setting, operation procedures for high-temperature blasting, and so on, are presented. Analysis shows that the development of effective technology for coal seam fire extinguishing and cooling, the manufacture of anti-high-temperature blasting supplies, especially priming materials, the development of heat insulation blasting setting, and the establishment of technical specifications suit large-scale blasting design and construction work at high-temperature coal seams, are the essential methods for safe blasting at high temperature coal seams.
文摘Post-combustion amine absorption and stripping can remove 90% of the CO2 from power plant flue gas, but systems can reduce electrical output by approximately 30% due to energy requirements for stripping CO2 from solvent and CO2 compression. The CO2 capture energy penalty can be reduced while developing renewable energy technologies by meeting CO2 capture energy requirements with a solar thermal energy system, particularly when electricity demand and prices are the highest. This study presents an initial review of solar thermal technologies for supplying CO2 capture energy, with a focus on high temperature systems. Parabolic troughs and central receivers are technically able to provide energy for CO2 capture. However, the solar system's capital costs would be roughly half that of the base coal-fired plant with CO2 capture, and high electricity prices are required to offset the costs of operating the solar thermal system. For high temperature solar thermal systems, direct electricity generation is likely a more efficient way to use solar energy to replace output lost to CO2 capture energy. However, low temperature solar thermal systems might integrate better with solvent stripping equipment, and more rigorous analysis is required to definitively assess the feasibility of using solar energy for CO2 capture.
文摘A kind of denitrifier HY-1 initially obtained from activated sludge was domesticated and inducted with UV and illumination to a new species bacterium HY-2 that has high bioactivity at low temperature. HY-2 was most active at 13 ℃. Nitrate and CODcr removal efficiency was investigated under different temperature and C/N ratio.
文摘Oxidation behaviors of Ni(Cr)-TiB2 coating deposited by HVOF technique were studied at 800,900 and 1 000℃in air. The microstructures of as-sprayed and oxidized coatings were characterized by X-ray diffractometry(XRD)and scanning electron microscopy(SEM).After oxidation at 800℃,a thin and adherent oxide layer was formed on the surface of the coating.With increasing exposure temperature,the thickness of the oxide layer increased;and at 1 000℃the oxide layer separated from the coating.Investigation of the kinetics of oxidation by using the thermogravimetric analysis(TGA)technique shows a parabolic oxidation rate.
文摘Fluorosilicone oil is polysiloxane with alkyl side chains containing fluorine, and because of its excellent thermal oxidation stability, cold flow property and cryogenic property, it can be widely used as a high temperature lubricant in the field of military aerospace industry. Two kinds of fluorosilicone oils, FSiO-a and FSiO-b, were synthesized by different pro- cessing means. FTICR MS was used to collect the information on composition and structure of the two polymers, respec- tively. The test results show that the two fluorosilicone oils have different contents of fluorine-containing chain segments (m/ n value), the maximum distribution of m/n value of FSiO-a oil ranges from 0.22 to 0.25, and that of FSiO-b oil ranges from 0.4 to 0.67. Difference in synthesis techniques makes this discrepancy and affects the quality and thermal stability of the fluoro- silicone oils.
文摘we have developed ferroelectric capacitor fabrication technique to realize low-voltage and high-density ferroelectric random access memory (FRAM). High temperature deposited IrOxtop electrode reveals high crystalline quality which drastically reduces the degradation of ferroelectric film by preventing hydrogen diffusion into ferroelectric film. This improvement enables us to commercialize highly-reliable 1T 1C FRAM with memory density of 4 Mb or larger.
文摘With the self-made pyrolysis equipment in miniature, we experimented in different pyrolysis conditions to get different pyrolyzate yields ( carbon, vinegar and gas). It proved that with the rise of temperature, the average yield of carbon descends gradually while the yields of vinegar and gas rise gradually. As the temperature rises, the yield of gas increases much more than that of vinegar. When speeding up the rising temperature, yield of carbon goes down while yields of vinegar and gas go up.
基金supported by the Natural Science Foundation of Jiangxi Province of China (Grant No. 2009GZW0022)
文摘Damage tolerance of titanium alloy structures is very important for the safety of modern aircraft under complex loading and environmental conditions. However, there is no available systematic knowledge about the effect of alloy thickness under mixed-mode loading at elevated temperatures. In the present study, a newly developed fracture experimental technique based on high-temperature moiré interferometry was employed to investigate experimentally I-II mixed-mode fracture in titanium alloy TC11 of various thicknesses at room and elevated temperatures. Compact shear specimens with thickness ranging from 1.8 to 7.1 mm were tested. The effects of temperature, thickness, and loading angle on the load capacity and crack initiation angle were investigated systematically. The TC11 alloy was shown to possess varied fracture performance at elevated tem-perature, and an opposite thickness effect at room temperature. Increasing temperature would enhance the fracture load capacity of thick specimens but reduce the fracture load capacity of thin specimens. Crack initiation angles under I-II mixed-mode loading showed the thickness-temperature coupling effects. These complex effects call for new development in three-dimensional mixed-mode fracture theory and technologies for damage tolerance assessment.
基金supported by the National Natural Science Foundation of China(Grant Nos.41590623&41472040)the Fundamental Research Funds for the Central Universities+2 种基金China University of Geosciences(Grant No.CUGL150801)Special Fund from the State Key Laboratory of Geological Processes and Mineral ResourcesChina University of Geosciences(Grant No.MSFGPMR201408)
文摘Hydrous minerals are important water carriers in the crust and the mantle, especially in the subduction zone. With the recent development of the experimental technique, studies of the electrical conductivity of hydrous silicate minerals under controlled temperature, pressure and oxygen fugacity, have helped to constrain the water distribution in the Earth's interior. This paper introduces high pressure and temperature experimental study of electrical conductivity measurement of hydrous minerals such as serpentine, talc, brucite, phase A, super hydrous phase B and phase D, and assesses the data quality of the above minerals. The dehydration effect and the pressure effect on the bulk conductivity of the hydrous minerals are specifically emphasized. The conduction mechanism of hydrous minerals and the electrical structure of the subduction zone are discussed based on the available conductivity data. Finally, the potential research fields of the electrical conductivity of hydrous minerals is presented.
文摘In view of the high voltage, the strong magnetic field environment of the high-voltage switchgear, the system based on the optical wireless sensing technology, realizes the isolated contact temperature monitoring of the high-voltage switchgear. In this scheme, the good thermal conductivity and insulation ceramic materials were selected as the outer jacket material sensing probe, and the program had a good solution to the problem of high and low voltage isolation; The combination of the optical fiber composite insulators for wireless sensing, not only solves the problem of high voltage insulation, but also avoids the "creeping" phenomenon due to dust. The package of the structure and reasonable installation solves the cross sensitivity of strain. The application showed that the precision of temperature measurement of the system could reach ± 0.5 ℃ and could work in a variety of harsh environments. It could improve the reliability of the operation of the electrical equipment significantly and has considerable practical value for the whole power system.