TN16 98042768高分辨二次电子像中的成分衬度=Composition con-trast in high resolution secondary electron im-age[刊,中]/徐军,陈文雄,张会珍(北京大学电子显微镜实验室.北京(100871))∥电子显微学报.—1997,16(1).
Coal-based Magnetic Activated Carbons （CMAC＇s） were prepared from three representative coal samples of various ranks： Baorigele lignite from Inner Mongolia; Datong bitumite from Shanxi province; and Taixi anthraci...Coal-based Magnetic Activated Carbons （CMAC＇s） were prepared from three representative coal samples of various ranks： Baorigele lignite from Inner Mongolia; Datong bitumite from Shanxi province; and Taixi anthracite from Ningxia Hui Auto- nomous Region. Fe3O4 was used as a magnetic additive. A nitrogen-adsorption analyzer was used to determine the specific surface area and pore structure of the resulting activated carbons. The adsorption capacity was assessed by the adsorption of iodine and methylene blue. X-ray diffraction was used to measure the evolution behavior of Fe304 during the preparation process. Magnetic properties were characterized with a vibrating-sample magnetometer. The effect of the activation temperature on the performance of CMAC＇s was also studied. The results show that, compared to Baorigele lignite and Taixi anthracite, the Datong bitumite is more appropriate for the preparation of CMAC＇s with a high specific surface area, an advanced pore structure and suitable magnetic properties. Fe304 can effectively enhance the magnetic properties and control the pore structure by increasing the ratio of meso- pores. An addition of 6.0% Fe304 and an activation temperature of 880 ℃ produced a CMAC having a specific surface area, an iodine adsorption, a methylene blue adsorption and a specific saturation magnetization of 1152.0 m2/g, 1216.7 mg/g, 229.5 mg/g and 4.623 emu/g, respectively. The coal used to prepare this specimen was Datong bitumite.展开更多
Most economically important tungsten(W)deposits are of magmatic-hydrothermal origin.The species and partitioning of W during fluid exsolution,considered to be the controlling factors for the formation of ore deposits,...Most economically important tungsten(W)deposits are of magmatic-hydrothermal origin.The species and partitioning of W during fluid exsolution,considered to be the controlling factors for the formation of ore deposits,are thus of great significance to investigate.However,this issue has not been well addressed mainly due to the significant difference in reported partition coefficients(e.g.,from strongly incompatible to strongly compatible)between fluid and melt(D_(W)^(fluid/melt)).Here,we used an in situ Raman spectroscopic approach to describe the W speciation,and to quantitatively determine the Dfluid/melt of individual and total W species in granite melts and coexisting Na2WO4 solutions at elevated temperatures(T;700–800C)and pressures(P;0.35–1.08 GPa).Results show that WO_(4)^(2-)and HWO4are predominant W species,and the fractions of these two species are similar in melt and coexisting fluid.The partitioning behaviors of WO_(4)^(2-)and HWO4are comparable,exhibiting strong enrichment in the fluid.The total DW fluid/melt ranges from 8.6 to 37.1.Specifically,DW fluid/melt decreases with rising T–P,indicating that shallow exsolution favors enrichment of W in evolved fluids.Furthermore,Rayleigh fractionation modeling based on the obtained D_(W)^(fluid/melt)data was used to describe the fluid exsolution processes.Our results strongly support that fluid exsolution can serve as an important mechanism to generate W-rich oreforming fluids.This study also indicates that in situ approach can be used to further investigate the geochemical behavior of ore-forming elements during the magmatic-hydrothermal transition,especially for rare metals associated with granite and pegmatite.展开更多
N-type and p-type 6H-SiC metal oxide semiconductor (MOS) capacitor samples are fabricated with a typical method,and the high frequency capacitor voltage (C-V) curves of these samples are measured at temperatures rangi...N-type and p-type 6H-SiC metal oxide semiconductor (MOS) capacitor samples are fabricated with a typical method,and the high frequency capacitor voltage (C-V) curves of these samples are measured at temperatures ranging from 293 to 533 K.There exists huge difference between the n-type and p-type samples.Flat-band voltage shift of the n-type sample becomes larger with temperature rising,but that of the p-type sample have very little change.This may be caused by the residual Al in the p-type oxide.Both types of the SiC samples follow the same rule of flat-band voltage changing with temperature.But their mechanisms are different as temperature is above 453 K.Of both types the p-type SiC is more suitable for high temperature applications.展开更多
文摘TN16 98042768高分辨二次电子像中的成分衬度=Composition con-trast in high resolution secondary electron im-age[刊,中]/徐军,陈文雄,张会珍(北京大学电子显微镜实验室.北京(100871))∥电子显微学报.—1997,16(1).
基金supported by the National Natural Science Foundation of China (No20776150)the National High Technology Research and Development Program of China (No2008AA05Z308)
文摘Coal-based Magnetic Activated Carbons （CMAC＇s） were prepared from three representative coal samples of various ranks： Baorigele lignite from Inner Mongolia; Datong bitumite from Shanxi province; and Taixi anthracite from Ningxia Hui Auto- nomous Region. Fe3O4 was used as a magnetic additive. A nitrogen-adsorption analyzer was used to determine the specific surface area and pore structure of the resulting activated carbons. The adsorption capacity was assessed by the adsorption of iodine and methylene blue. X-ray diffraction was used to measure the evolution behavior of Fe304 during the preparation process. Magnetic properties were characterized with a vibrating-sample magnetometer. The effect of the activation temperature on the performance of CMAC＇s was also studied. The results show that, compared to Baorigele lignite and Taixi anthracite, the Datong bitumite is more appropriate for the preparation of CMAC＇s with a high specific surface area, an advanced pore structure and suitable magnetic properties. Fe304 can effectively enhance the magnetic properties and control the pore structure by increasing the ratio of meso- pores. An addition of 6.0% Fe304 and an activation temperature of 880 ℃ produced a CMAC having a specific surface area, an iodine adsorption, a methylene blue adsorption and a specific saturation magnetization of 1152.0 m2/g, 1216.7 mg/g, 229.5 mg/g and 4.623 emu/g, respectively. The coal used to prepare this specimen was Datong bitumite.
基金supported by the National Natural Science Foundation of China(41922023,41830428,42173038,41973055,and 42130109)the Research Funds for the Frontiers Science Center for Critical Earth Material Cycling(Nanjing University,China)the Fundamental Research Funds for the Central Universities,China(2022300192).
文摘Most economically important tungsten(W)deposits are of magmatic-hydrothermal origin.The species and partitioning of W during fluid exsolution,considered to be the controlling factors for the formation of ore deposits,are thus of great significance to investigate.However,this issue has not been well addressed mainly due to the significant difference in reported partition coefficients(e.g.,from strongly incompatible to strongly compatible)between fluid and melt(D_(W)^(fluid/melt)).Here,we used an in situ Raman spectroscopic approach to describe the W speciation,and to quantitatively determine the Dfluid/melt of individual and total W species in granite melts and coexisting Na2WO4 solutions at elevated temperatures(T;700–800C)and pressures(P;0.35–1.08 GPa).Results show that WO_(4)^(2-)and HWO4are predominant W species,and the fractions of these two species are similar in melt and coexisting fluid.The partitioning behaviors of WO_(4)^(2-)and HWO4are comparable,exhibiting strong enrichment in the fluid.The total DW fluid/melt ranges from 8.6 to 37.1.Specifically,DW fluid/melt decreases with rising T–P,indicating that shallow exsolution favors enrichment of W in evolved fluids.Furthermore,Rayleigh fractionation modeling based on the obtained D_(W)^(fluid/melt)data was used to describe the fluid exsolution processes.Our results strongly support that fluid exsolution can serve as an important mechanism to generate W-rich oreforming fluids.This study also indicates that in situ approach can be used to further investigate the geochemical behavior of ore-forming elements during the magmatic-hydrothermal transition,especially for rare metals associated with granite and pegmatite.
文摘N-type and p-type 6H-SiC metal oxide semiconductor (MOS) capacitor samples are fabricated with a typical method,and the high frequency capacitor voltage (C-V) curves of these samples are measured at temperatures ranging from 293 to 533 K.There exists huge difference between the n-type and p-type samples.Flat-band voltage shift of the n-type sample becomes larger with temperature rising,but that of the p-type sample have very little change.This may be caused by the residual Al in the p-type oxide.Both types of the SiC samples follow the same rule of flat-band voltage changing with temperature.But their mechanisms are different as temperature is above 453 K.Of both types the p-type SiC is more suitable for high temperature applications.
