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焦炭高温热性质的研究
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作者 任玉明 王元生 +1 位作者 鲍俊芳 陈昊 《燃料与化工》 CAS 2023年第4期11-15,共5页
研究了焦炭在不同反应温度、不同气体流量、不同气体成分、不同熔损率下的热性质变化规律。通过研究发现焦炭在1100℃时的反应模式主要为渗透反应;热强度随着熔损率的升高呈降低的趋势;气体成分、气体流量变化对热强度影响不大。1 200... 研究了焦炭在不同反应温度、不同气体流量、不同气体成分、不同熔损率下的热性质变化规律。通过研究发现焦炭在1100℃时的反应模式主要为渗透反应;热强度随着熔损率的升高呈降低的趋势;气体成分、气体流量变化对热强度影响不大。1 200℃时的反应模式是以渗透反应为主,兼有一定程度的表面反应;热强度先随着熔损率的升高呈降低的趋势,当熔损率> 25%时热强度急剧下降;CO_(2)比例≥25%后,气体成分变化对热强度影响不大;气体流量变化对热强度影响不大。1 350℃时反应模式主要为表面反应;热强度随着熔损率的升高变化不大,始终能够保持较高的热强度;随着CO_(2)比例的增加,焦炭热强度呈减小的趋势;气体流量变化对热强度影响不大。 展开更多
关键词 焦炭 高温热性质 反应温度 气体流量 气体成分 熔损率
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焦炭高温热性质测定装置的研发与验证
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作者 任玉明 薛改凤 +1 位作者 王元生 宋子逵 《武钢技术》 CAS 2017年第2期46-48,57,共4页
介绍了焦炭高温热性质测定装置的特点以及主要功能,并通过应用建立了焦炭起始反应温度的测定方法,可以用来表征高炉热储备区的开始温度,指导高炉生产。通过对焦炭在不同温度下的反应速率的测定,发现随着混合反应气体中CO_2比例增加,焦... 介绍了焦炭高温热性质测定装置的特点以及主要功能,并通过应用建立了焦炭起始反应温度的测定方法,可以用来表征高炉热储备区的开始温度,指导高炉生产。通过对焦炭在不同温度下的反应速率的测定,发现随着混合反应气体中CO_2比例增加,焦炭反应速率呈增加的趋势;随着反应温度增加,焦炭反应速率呈增加的趋势;反应温度越高,随着CO_2比例增加,焦炭反应速率增加越快;在CO_2比例较低时,不同反应温度下的焦炭反应速率都不大,但当CO_2比例达到50%时,焦炭反应速率随温度升高而明显提高,从0.43g/min提高到2.00g/min。 展开更多
关键词 焦炭 高温热性质 反应速率 起始反应温度
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碱金属对焦炭高温热性质的影响研究 被引量:1
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作者 任玉明 陈昊 +1 位作者 王元生 鲍俊芳 《河南冶金》 2022年第3期1-3,30,共4页
通过将一定粒度的焦炭与不同比例的碱金属进行焦炭反应性实验,研究了碱金属蒸气对焦炭高温热性质的影响。研究结果表明,随着碱金属钾、钠蒸汽含量的增加,焦炭的开始反应温度呈降低的趋势,反应速率呈增加的趋势;随着碱金属钾、钠蒸汽含... 通过将一定粒度的焦炭与不同比例的碱金属进行焦炭反应性实验,研究了碱金属蒸气对焦炭高温热性质的影响。研究结果表明,随着碱金属钾、钠蒸汽含量的增加,焦炭的开始反应温度呈降低的趋势,反应速率呈增加的趋势;随着碱金属钾、钠蒸汽含量的增加,会导致焦炭的反应性急剧增加,但主要增加的是焦炭的表面反应性,对焦炭内部结构影响不大,故反应后焦炭粒度减小,热强度降低幅度不大。 展开更多
关键词 焦炭 高温热性质 碱金属
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基于气动悬浮激光加热技术YAG熔体高温热物理性能评测 被引量:3
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作者 丰盛 单志涛 +3 位作者 潘瑞琨 徐博 祖成奎 陶海征 《无机材料学报》 SCIE EI CAS CSCD 北大核心 2018年第12期1297-1302,共6页
钇铝石榴石Y_3Al_5O_(12)(Yttrium Aluminum Garnet,简记为YAG)材料具有优异的光、热和电学性能,引起了广泛关注。但高熔点和冷却过程中复杂的相选择机制,使YAG熔体特别是熔点以下过冷区内的热物理性能参数获得困难。利用自主搭建的气... 钇铝石榴石Y_3Al_5O_(12)(Yttrium Aluminum Garnet,简记为YAG)材料具有优异的光、热和电学性能,引起了广泛关注。但高熔点和冷却过程中复杂的相选择机制,使YAG熔体特别是熔点以下过冷区内的热物理性能参数获得困难。利用自主搭建的气动悬浮无容器激光加热装置,基于受迫振动和光学描影等原理,在1750~2650 K宽达900 K的温区内,评测了YAG熔体的黏度、表面张力和密度。研究表明,与Al_2O_3熔体相比,YAG熔体密度具有更高的温度敏感性,具有高约1倍的平均线膨胀系数;不同于表面张力随温度变化不敏感的Al_2O_3熔体,YAG熔体的表面张力随温度升高产生略微降低;与Al_2O_3熔体的黏温关系相比,在熔点以下的过冷区内发现YAG熔体具有更陡峭的黏温变化趋势。 展开更多
关键词 温热物理性质 YAG 气动悬浮技术 过冷区
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Comparison of mechanical properties in high temperature and thermal treatment granite 被引量:20
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作者 尹土兵 舒荣华 +2 位作者 李夕兵 王品 刘希灵 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2016年第7期1926-1937,共12页
Static mechanical experiments were carried out on granite after and under different temperatures using an electro-hydraulic and servo-controlled material testing machine with a heating device. Variations in obvious fo... Static mechanical experiments were carried out on granite after and under different temperatures using an electro-hydraulic and servo-controlled material testing machine with a heating device. Variations in obvious form, stress-strain curve, peak strength, peak strain and elastic modulus with temperature were analyzed and the essence of rock failure modes was explored. The results indicate that, compared with granite after the high temperature treatment, the brittle-ductile transition critical temperature is lower, the densification stage is longer, the elastic modulus is smaller and the damage is larger under high temperature. In addition, the peak stress is lower and the peak strain is greater, but both of them change more obviously with the increase of temperature compared with that of granite after the high temperature treatment. Furthermore, the failure modes of granite after the high temperature treatment and under high temperature show a remarkable difference. Below 100 ℃, the failure modes of granite under both conditions are the same, presenting splitting failure. However, after 100 ℃, the failure modes of granite after the high temperature treatment and under high temperature present splitting failure and shear failure, respectively. 展开更多
关键词 GRANITE thermal treatment high temperature effect static mechanical properties failure properties
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Ab initio Predictions of Structural and Thermodynamic Properties of Zr2AIC Under High Pressure and High Temperature 被引量:1
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作者 Fen Luo Zhi-cheng Guo +2 位作者 Xiu-lu Zhang Chang-ying Yuan Ling-cang Cai 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2015年第3期263-268,I0001,共7页
The structural and thermodynamic properties of Zr2A1C at high pressure and high temper- ature are investigated by first principles density functional theory method. The calculated lattice parameters of Zr2A1C are in g... The structural and thermodynamic properties of Zr2A1C at high pressure and high temper- ature are investigated by first principles density functional theory method. The calculated lattice parameters of Zr2A1C are in good agreement with the available theoretical data. The pressure dependences of the elastic constants, bulk modulus, shear modulus, Young's mod- ulus, and Vickers hardness of Zr2A1C are successfully obtained. The elastic anisotropy is examined through the computation of the direction dependence of Young's modulus. By using the quasiharmonic Debye model, the thermodynamic properties including the Debye temperature, heat capacity, volume thermal expansion coefficient, and Griineisen parameter at high pressure and temperature are predicted for the first time. 展开更多
关键词 Elastic property Thermodynamic property Density functional theory
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Evolution of microstructure and high temperature tensile properties of as-extruded Ti Bw reinforced near-α titanium matrix composite subjected to heat treatments 被引量:5
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作者 WANG Bo ZHANG HaoBiao +3 位作者 HUANG LuJun HE JianLi ZHANG YouFeng WANG Wei 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2018年第9期1340-1345,共6页
The Ti Bw reinforced near-α titanium matrix composite(Ti-5.8 Al-3.4 Zr-4.0 Sn-0.4 Mo-0.4 Nb-0.4 Si-0.06 C) was successfully synthesized by powder metallurgy and hot extrusion route. The effects of solution and agin... The Ti Bw reinforced near-α titanium matrix composite(Ti-5.8 Al-3.4 Zr-4.0 Sn-0.4 Mo-0.4 Nb-0.4 Si-0.06 C) was successfully synthesized by powder metallurgy and hot extrusion route. The effects of solution and aging temperature on the microstructure and high temperature tensile properties of the composite were investigated. The results revealed that the fine transformed β phase can be obtained by the solution treatment at β phase region and aging treatment, no other precipitates were observed. The α2 phase(Ti3 Al) can be acquired when the solution treated at α+β phase region followed by aging treatment. With increasing the aging temperature from 500 to 700℃ for 5 h, the size of α2 precipitates increases from about 5 to about 30 nm. The Ti Bw are stable without any interfacial reaction during the heat treatments. The high temperature tensile properties show that the composite performed by solution and aging treatment exhibits good strengthening effects. With increasing the aging temperature from 500 to 700℃, the strength of the composite increases at the expense of elongation due to the increment of α2 precipitates.The strength of the composite at 600℃ increases by 17% to 986 MPa after 1000℃/2 h/AC and 700℃/5 h/AC heat treatment. 展开更多
关键词 titanium matrix composite solution AGING PRECIPITATE microstrueture high temperature tensile property
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Shock relations in gases of heterogeneous thermodynamic properties
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作者 HU ZongMin ZHOU Kai +2 位作者 PENG Jun LI JinPing JIANG ZongLin 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2017年第7期1050-1057,共8页
Shock relations usually found in literatures are derived theoretically under the assumption of homogeneous thermodynamic properties, i.e., constant ratio of specific heats, γ. However, high temperature effects post a... Shock relations usually found in literatures are derived theoretically under the assumption of homogeneous thermodynamic properties, i.e., constant ratio of specific heats, γ. However, high temperature effects post a strong shock wave may result in thermodynamic heterogeneities and failure to the original shock relations. In this paper, the shock relations are extended to take account of high-temperature effects. Comparison indicates that the present approach is more feasible than other analytical approaches to reflect the influence of γ heterogeneity on the post-shock parameters. 展开更多
关键词 shock wave imperfect gas heterogeneous theoretical solution
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