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氨氧化装置非稳态瞬间反应的高热效应与催化网失活 被引量:7
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作者 宁远涛 《贵金属》 CAS CSCD 2003年第2期42-48,共7页
分析了生产硝酸的氨氧化装置中的基本反应和非稳态反应。在开炉点火初期 ,由于脉冲式供应过量氨气 ,导致氨从催化网低温 (低活性 )区旁路到钯合金捕集网表面 ,在Pd的催化作用下 ,旁路氨与催化网所产生的NOx 发生非稳态瞬间高放热反应 ,... 分析了生产硝酸的氨氧化装置中的基本反应和非稳态反应。在开炉点火初期 ,由于脉冲式供应过量氨气 ,导致氨从催化网低温 (低活性 )区旁路到钯合金捕集网表面 ,在Pd的催化作用下 ,旁路氨与催化网所产生的NOx 发生非稳态瞬间高放热反应 ,导致钯合金捕集网熔化和铂合金催化网粘连失效。我国高压氨氧化装置在反应初期所出现的Pt催化网失效事故 ,就是因非稳态瞬间反应导致Pd捕集网熔化及底层铂合金催化网熔蚀和全部催化网粘连烧结所致。笔者提出了几点改进措施。 展开更多
关键词 催化化学 硝酸 催化网 捕集网 铂合金 钯合全 氨氧化装置 失活 非稳态瞬间反应 高热效应
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MODAL FREQUENCY CHARACTERISTICS OF AXIALLY MOVING BEAM WITH SUPERSONIC/HYPERSONIC SPEED 被引量:4
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作者 王亮 陈怀海 贺旭东 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2011年第2期163-168,共6页
The vibration characteristics of transverse oscillation of an axially moving beam with high velocity is in- vestigated. The vibration equation and boundary conditions of the free-free axially moving beam are derived u... The vibration characteristics of transverse oscillation of an axially moving beam with high velocity is in- vestigated. The vibration equation and boundary conditions of the free-free axially moving beam are derived using Hamilton's principle. Furthermore, the linearized equations are set up based on Galerkinl s method for the ap- proximation solution. Finally, three influencing factors on the vibration frequency of the beam are considered: (1) The axially moving speed. The first order natural frequency decreases as the axial velocity increases, so there is a critical velocity of the axially moving beam. (2) The mass loss. The changing of the mass density of some part of the beam increases the beam natural frequencies. (3) The thermal effect.' The temperature increase will decrease the beam elastic modulus and induce the vibration frequencies descending. 展开更多
关键词 axially moving beam VIBRATION thermal effect supersonic/hypersonic
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Effects of High Temperature Treatment on Seed Germination of Dodonaea viscosa(L.) Jacq 被引量:1
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作者 Guangfei ZHANG Dongfang HUO +4 位作者 Boqiang HUANG Huihong ZHANG Ting YU Liyuan MENG Wenhua SU 《Agricultural Science & Technology》 CAS 2017年第1期82-86,共5页
Seeds of Dodonaea viscosa (L.) Jacq, a representative species in dry and hot valleys in Southwest China, were chosen as experimental materials. In this experiment, the D. viscosa seeds were treated at 40, 60, 80 and... Seeds of Dodonaea viscosa (L.) Jacq, a representative species in dry and hot valleys in Southwest China, were chosen as experimental materials. In this experiment, the D. viscosa seeds were treated at 40, 60, 80 and 100℃ respectively before germination to study impacts of high temperature treatment on their generation rate and to further discuss the roles of fire during the process of vegetation formation in dry and hot valley areas of China. The results show that when the temperature was higher than 40 ℃, the germination rate of D. viscosa seeds was significantly higher than that of the control group, and the heat shock effect was apparent. The germination rate was the highest when the seeds were treated at 80 ℃ for 10 min, reaching 63.00%±2.55%. There was still a significant heat shock effect on the D. viscosa seeds which were stored for one year. In comparison with the conventional method of soaking seeds in hot water, the germination rate of D. viscose seeds which were treated at high temperature before germination increased significantly. 展开更多
关键词 High temperature treatment Dodonaea viscose (L.) Jacq Germination rate Heat shock effect Vegetation restoration
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Synergistic effects of hyperthermia and cisplatin on human lung adenocarcinoma cell line H1299
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作者 Xueqin Ghen Shenglin Ma +1 位作者 Hanzhou Mou Jianguo Feng 《The Chinese-German Journal of Clinical Oncology》 CAS 2007年第1期5-8,共4页
Objective: To observe the synergistic effects of hyperthernia and cisplatin on human lung adenocarcinoma cell line H 1299. Methods: Cells treated with or without hyperthermia at 42 ℃ for 2 h were detected cisplatin... Objective: To observe the synergistic effects of hyperthernia and cisplatin on human lung adenocarcinoma cell line H 1299. Methods: Cells treated with or without hyperthermia at 42 ℃ for 2 h were detected cisplatin sensitivity with CCK-8 assay. After managed with hyperthermia at 42 ℃ for 2 h, ciplatin 10 μg/mL for 24 h or both of two sides, inhibition ratio was detected with CCK-8 assay and flow cytometry analyzed DNA contents in every phase of cell proliferation. Results: After hyperthermia, IC50 values of cell to cisplatin decreased from 9.51 μg/mL to 6.07 μg/mL. CCK-8 assay showed hyperthermia and ciplatin had synergistic killing effects, and FCM also showed hyperthermia had significant effects on cell cycle with increase of Go/G1 phase population and reduction of S phase population. Conclusion: Hyperthermia can significantly increase the sensitivity of H1299 cell line to cisplatin. 展开更多
关键词 HYPERTHERMIA CISPLATIN lung neoplasms CYTOTOXICITY cell cycle
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Effects of Preheat on the Thermodynamics of the ICF Hot Spot
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作者 Jeremy Melvin Hyunkyung Lim +4 位作者 Verinder Rana Baolian Cheng James Glimm David H. Sharp Doug C.Wilson 《Journal of Physical Science and Application》 2015年第1期24-28,共5页
We determine the dependence of key inertial confinement fusion (ICF) hot spot properties on the deuterium-tritium (DT) fuel adiabat accomplished by addition of heat to the cold shell. Our main result is to observe... We determine the dependence of key inertial confinement fusion (ICF) hot spot properties on the deuterium-tritium (DT) fuel adiabat accomplished by addition of heat to the cold shell. Our main result is to observe that variation of this parameter reduces the simulation to experiment discrepancy in several experimentally inferred quantities. Simulations are continued from capsule only l D simulations using the Lawrence Livermore National Laboratory ICF code, HYDRA. The continuations employ the high energy density physics (HEDP) University of Chicago code, FLASH, and a hydro only code, FronTier, modified with a radiation equation of state (EOS) model. Hot spot densities, burn-weighted ion temperatures and pressures show a decreasing trend, while the hot spot radius shows an increasing trend in response to added heat to the cold shell. Instantaneous quantities are assessed at the time of maximum neutron production within each simulation. 展开更多
关键词 ICF Rayleigh-Taylor instabilities hot spot deceleration phase adiabat.
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Dynamics of Discrete Bubble in Nucleate Pool Boiling on Thin Wires in Microgravity 被引量:3
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作者 Shixin WAN Jianfu ZHAO Gang LIU 《Journal of Thermal Science》 SCIE EI CAS CSCD 2009年第1期13-19,共7页
A space experiment on bubble behavior and heat transfer in subcooled pool boiling phenomenon has been performedutilizing the temperature-controlled pool boiling (TCPB) device both in normal gravity in the laboratoryan... A space experiment on bubble behavior and heat transfer in subcooled pool boiling phenomenon has been performedutilizing the temperature-controlled pool boiling (TCPB) device both in normal gravity in the laboratoryand in microgravity aboard the 22^(nd) Chinese recoverable satellite. The fluid is degassed R113 at 0.1 MPa andsubcooled by 26℃ nominally. A thin platinum wire of 60 μm in diameter and 30 mm in length is simultaneouslyused as heater and thermometer. Only the dynamics of the vapor bubbles, particularly the lateral motion and thedeparture of discrete vapor bubbles in nucleate pool boiling are reported and analyzed in the present paper. It'sfound that these distinct behaviors can be explained by the Marangoni convection in the liquid surrounding vaporbubbles. The origin of the Marangoni effect is also discussed. 展开更多
关键词 bubble dynamics pool boiling MICROGRAVITY Marangoni effect
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Large magnetocaloric effect in metamagnetic HoPdAl 被引量:1
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作者 XU ZhiYi SHEN BaoGen 《Science China(Technological Sciences)》 SCIE EI CAS 2012年第2期445-450,共6页
Magnetic properties and magnetocaloric effects (MCEs) of the HoPdA1 compounds with the hexagonal ZrNiAl-type and the orthorhombic TiNiSi-type structures are investigated. Both the compounds are found to be antiferro... Magnetic properties and magnetocaloric effects (MCEs) of the HoPdA1 compounds with the hexagonal ZrNiAl-type and the orthorhombic TiNiSi-type structures are investigated. Both the compounds are found to be antiferromagnet with the Nrel tem- perature TN=12 and 10 K, respectively. A field-induced metamagnetic transition from antiferromagnetic (AFM) state to ferro- magnetic (FM) state is observed below TN. For the hexagonal HoPdA1, a small magnetic field can induce an FM-like state due to a weak AFM coupling, which leads to a high saturation magnetization and gives rise to a large MCE around TN. The maxi- mal value of magnetic entropy change (ASM) is -20.6 J/kg K with a refrigerant capacity (RC) value of 386 J/kg for a field change of 0-5 T. For the orthorhombic HoPdA1, the critical field required for metamagnetic transition is estimated to be about 1.5 T, showing a strong AFM coupling. However, the maximal ASM value is still -13.7 J/kg K around TN for a field change of 0-5 T. The large reversible ASM and considerable RC suggest that HoPdA1 may be an appropriate candidate for magnetic re- frigerant in a low temperature range. 展开更多
关键词 HoPdAI compound magnetocaloric effect metamagnetic transition
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Shock relations in gases of heterogeneous thermodynamic properties
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作者 HU ZongMin ZHOU Kai +2 位作者 PENG Jun LI JinPing JIANG ZongLin 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2017年第7期1050-1057,共8页
Shock relations usually found in literatures are derived theoretically under the assumption of homogeneous thermodynamic properties, i.e., constant ratio of specific heats, γ. However, high temperature effects post a... Shock relations usually found in literatures are derived theoretically under the assumption of homogeneous thermodynamic properties, i.e., constant ratio of specific heats, γ. However, high temperature effects post a strong shock wave may result in thermodynamic heterogeneities and failure to the original shock relations. In this paper, the shock relations are extended to take account of high-temperature effects. Comparison indicates that the present approach is more feasible than other analytical approaches to reflect the influence of γ heterogeneity on the post-shock parameters. 展开更多
关键词 shock wave imperfect gas heterogeneous theoretical solution
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