Microparticle formation and crystallization rate of 1,3,5,7-tetranitro-l,3,5,7-tetraazacyclooctane (HMX) in acetone solution using supercritical carbon dioxide antisolvent (GAS) recrystallization were studied. Scannin...Microparticle formation and crystallization rate of 1,3,5,7-tetranitro-l,3,5,7-tetraazacyclooctane (HMX) in acetone solution using supercritical carbon dioxide antisolvent (GAS) recrystallization were studied. Scanning electronic microscopy, X-ray diffraction and infrared radiation were used to examine particle size, crystallinity and chemical structure. The results show that B-HMX microparticle in different average size (2-9.5um) and with narrow size distribution were obtained by controlling the expansibility, expansion speed, initial concentration and temperature during recrystallization of HMX. The formation of nuclei may be a main cause of consumption of solute when the solution is expanded rapidly enough and the equilibrium concentration is lower, in which almost monodisperse microparticle can be obtained.展开更多
Inert metal explosive,a new kind of explosive,is a mixture of high explosive and inert metal particle.When this kind of explosive is detonated,an inert metal particle flow will be formed by the ex-plosive product driv...Inert metal explosive,a new kind of explosive,is a mixture of high explosive and inert metal particle.When this kind of explosive is detonated,an inert metal particle flow will be formed by the ex-plosive product driving.To determine the characteristics of the movement of the metal particle flow,a series of aluminium plates were designed to be the targets on which the metal particle flow impacted.The test result was presented and a numerical model was set up to analyze the impact of the high speed inert metal particles on aluminium plate.Based on the numerical analysis,the relationship between the characteristic of the mark on the target plate and the initial condition of the inert metal particles was pro-posed.From the analysis of the impact on target plates,more information about the movement of the metal particles could be reconstructed.展开更多
A large-scale experimental for multiphase combustion and explosion study was developed and manufactured. The explosion tank consists of a 2 m diameter, 3.5 m long tube and ellipsoidai dames on both ends. The volume of...A large-scale experimental for multiphase combustion and explosion study was developed and manufactured. The explosion tank consists of a 2 m diameter, 3.5 m long tube and ellipsoidai dames on both ends. The volume of the experimental tank is 10 ma. Pressure histories of the explosion pressure can be measured at different locations in the tank. High pressure glass windows of 200～300 mm were used to have access to the visualization of the explosion process. The explosion process of methane/air mixture and methane/coal dust/air mixture initiated by a 40 J electric spark at the center of the tank was studied in the large^scale experimental system. Five pressure sonsars were arranged in the tank with different distances from the ignition point. Ton dust dispersion traits were equipped to eject dust into the tank. A high-speed camera system was used to visualize the flame propagation during the explosion process. The characteristics of the pressure wave and flame propagated in methane/air mixtures and methane/coal dust/air mixtures have been展开更多
基金the National Natural Science Foundation of China (No. 29376233).
文摘Microparticle formation and crystallization rate of 1,3,5,7-tetranitro-l,3,5,7-tetraazacyclooctane (HMX) in acetone solution using supercritical carbon dioxide antisolvent (GAS) recrystallization were studied. Scanning electronic microscopy, X-ray diffraction and infrared radiation were used to examine particle size, crystallinity and chemical structure. The results show that B-HMX microparticle in different average size (2-9.5um) and with narrow size distribution were obtained by controlling the expansibility, expansion speed, initial concentration and temperature during recrystallization of HMX. The formation of nuclei may be a main cause of consumption of solute when the solution is expanded rapidly enough and the equilibrium concentration is lower, in which almost monodisperse microparticle can be obtained.
基金Supported by National Natural Science Foundation of China (No.10772032).
文摘Inert metal explosive,a new kind of explosive,is a mixture of high explosive and inert metal particle.When this kind of explosive is detonated,an inert metal particle flow will be formed by the ex-plosive product driving.To determine the characteristics of the movement of the metal particle flow,a series of aluminium plates were designed to be the targets on which the metal particle flow impacted.The test result was presented and a numerical model was set up to analyze the impact of the high speed inert metal particles on aluminium plate.Based on the numerical analysis,the relationship between the characteristic of the mark on the target plate and the initial condition of the inert metal particles was pro-posed.From the analysis of the impact on target plates,more information about the movement of the metal particles could be reconstructed.
基金supported by the National Natural Science Foundation of China(No.10772032)the Foundation of State Key Lab of Explosion Science and Technology(No.ZDKT08-02-6,and YBKT09-1)
文摘A large-scale experimental for multiphase combustion and explosion study was developed and manufactured. The explosion tank consists of a 2 m diameter, 3.5 m long tube and ellipsoidai dames on both ends. The volume of the experimental tank is 10 ma. Pressure histories of the explosion pressure can be measured at different locations in the tank. High pressure glass windows of 200～300 mm were used to have access to the visualization of the explosion process. The explosion process of methane/air mixture and methane/coal dust/air mixture initiated by a 40 J electric spark at the center of the tank was studied in the large^scale experimental system. Five pressure sonsars were arranged in the tank with different distances from the ignition point. Ton dust dispersion traits were equipped to eject dust into the tank. A high-speed camera system was used to visualize the flame propagation during the explosion process. The characteristics of the pressure wave and flame propagated in methane/air mixtures and methane/coal dust/air mixtures have been
