国产高电密离子膜电解槽的应用

介绍了离子膜烧碱装置采用国产化生产的自然循环复极式高电流密度电解槽在生产中的应用情况。

低电密自然循环复极槽高电密化改造及运行总结

在低电密自然循环复极槽电极更新时,进行阴极零极距改造和阳极高电密化改造,达到降低电耗并提高产能的目的。

三元正极材料清洗废水资源化回收零排放处理工艺

锂电三元正极材料在清洗过程中产生含有Li^(+)、Al^(3+)、SO_(4)^(2-)、镍钴锰氧化物及少量其他离子的废水,对该三元正极材料清洗废水的资源化回收零排放处理工艺进行了阐述。该废水处理系统涉及的成套工艺包括预处理单元、废水减量化单元、沉锂单元和制纯水单元。重点对Al^(3+)的去除、膜浓缩、沉锂等关键工艺进行了重点描述,最后通过实际与理论对比分析,达到了预期的设计目标——锂资源得到有效回收、废水实现全部回用。通过对实际案例的相关数据的例举和分析,证明了本套废水处理工艺的可行性和可靠性,为锂电三元正极材料清洗废水的治理提供了典型的参考工艺路线。

离子膜电解槽泄漏着火原因分析

以旭化成/北化机电解槽为例,分析了可能造成电解槽泄漏的各种原因并介绍了电解槽泄漏的应对方法和预防措施。

Production of carbon anodes by high-temperature mould pressing

Laboratory-scale carbon anodes were produced by a new method of high temperature mould pressing, and their physico-chemical properties were studied. The influence of mould pressing conditions and coal pitch addition on the bulk density, crushing strength, and oxidation resistance was analyzed. The mierostructure of carbon anodes was investigated by scanning electron microscopy （SEM）, and the mechanism of producing carbon anodes by high-temperature mould pressing was analyzed. The results show that when the anodes are produced by high-temperature mould pressing, coal pitch can expand into the coke particles and fill the pores inside the particles, which is beneficial for improving the quality of prebaked anodes. The bulk density of carbon anodes is 1.64-1.66 g/cm3, which is 0.08-0.12 g/cm3 higher than that of industrial anodes, and the oxidation resistance of carbon anodes is also significantly improved.

Contrast between 2D inversion and 3D inversion based on 2D high-density resistivity data

The 2D data processing adopted by the high-density resistivity method regards the geological structures as two degrees, which makes the results of the 2D data inversion only an approximate interpretation;the accuracy and effect can not meet the precise requirement of the inversion. Two typical models of the geological bodies were designed, and forward calculation was carried out using finite element method. The forward-modeled profiles were obtained. 1% Gaussian random error was added in the forward models and then 2D and 3D inversions using a high-density resistivity method were undertaken to realistically simulate field data and analyze the sensitivity of the 2D and 3D inversion algorithms to noise. Contrast between the 2D and 3D inversion results of least squares inversion shows that two inversion results of high-density resistivity method all can basically reflect the spatial position of an anomalous body. However, the 3D inversion can more effectively eliminate the influence of interference from Gaussian random error and better reflect the distribution of resistivity in the anomalous bodies. Overall, the 3D inversion was better than 2D inversion in terms of embodying anomalous body positions, morphology and resistivity properties.

离子膜电解槽膜极距改造及运行总结

介绍了将高电密电解槽变为膜极距电解槽的改造内容,针对试运行过程中存在的问题制定了应对措施。

Fabricating a Micro Electromagnetic Actuator with High Energy Density

This paper introduces a new technology to fabricate a micro electromagnetic actuator with high energy density without an enclosed magnetic circuit. This technology includes fabricating multi-turns planar micro coils and fabricating the thick magnetic （NiFe） core on the silicon wafer. The multi-turns planar micro coils are fabricated by the electroplating method from the surface along the line and by dynamically controlling the current density of the copper electrolytes. In order to fabricate thick NiFe plating,the adhesion properties between the NiFe plating and the silicon substrates are improved by changing the surface roughness of the silicon substrates and increasing the thickness of the seed layer. Furthermore,the micro electromagnetic actuator is tested and the energy density of the actuator is evaluated by force testing. The experiments show that the microactuator is efficient in producing high magnetic energy density and high magnetic force.

On-line Measurement for Ohmic Resistance in Direct Methanol Fuel Cell by Current Interruption Method

Electrochemical impedance spectroscopy (EIS) is widely used in fuel cell impedance analysis. However, for ohmic resistance (R Ω), EIS has some disadvantages such as long test period and complex data analysis with equivalent circuits. Therefore, the current interruption method is explored to measure the value of RΩ in direct methanol fuel cells (DMFC) at different temperatures and current densities. It is found that RΩ decreases as temperature increase, and decreases initially and then increases as current density increases. These results are consistent with those measured by the EIS technique. In most cases, the ohmic resistances with current interruption (R iR ) are larger than those with EIS (R EIS ), but the difference is small, in the range from –0.848% to 5.337%. The errors of R iR at high current densities are less than those of R EIS . Our results show that the R iR data are reliable and easy to obtain in the measurement of ohmic resistance in DMFC.

Testing with high density resistivity method in prevention and cure for mine water disaster and its applied effect

The detecting examples using the high density resistivity method, about the evaluation of containing water characteristic from the floor rock and the height of overburden failure, were given. It expresses that the high density resistivity method has good effect with strong maneuverability and continuous observing section during the prevention and cure for mine water disaster. At the same time, the article pointed out that the study of space data inversion and dynamic watching technology about the high density resistivity method must be enhanced in the future because of special condition of data collecting in mine.

False anomaly recognition with horizontal differential field lines method in high-density electrical technique and its application in Xinlei Quarry,Jiuquan

As an important geophysical tool,high density electrical technique infers the underground geological structures by processing and inverting the apparent resistivity data.Currently,the false anomalies have been frequently occurred in the graph of apparent resistivity pseudo-section or inverted geoelectrical section obtained from high-density electrical technique,and are difficult to remove.In this study,the authors explain the mechanism of the false anomalies and put forward the horizontal differential field method to identify the false anomalies.Based on the analysis of modeling results,this method is applied in the surveying data in Xinlei Quarry of Jiuquan,and the results confirm the effectiveness of the horizontal differential field method.

Attenuation-compensated reverse time migration of GPR data constrained by resistivity

The high-frequency electromagnetic waves of ground-penetrating radar(GPR)attenuate severely when propagated in an underground attenuating medium owing to the influence of resistivity,which remarkably decreases the resolution of reverse time migration(RTM).As an effective high-resolution imaging method,attenuation-compensated RTM(ACRTM)can eff ectively compensate for the energy loss caused by the attenuation related to media absorption under the influence of resistivity.Therefore,constructing an accurate resistivity-media model to compensate for the attenuation of electromagnetic wave energy is crucial for realizing the ACRTM imaging of GPR data.This study proposes a resistivity-constrained ACRTM imaging method for the imaging of GPR data by adding high-density resistivity detection along the GPR survey line and combining it with its resistivity inversion profile.The proposed method uses the inversion result of apparent resistivity data as the GPR RTM-resistivity model for imposing resistivity constraints.Moreover,the hybrid method involving image minimum entropy and RTM is used to estimate the medium velocity at the diff raction position,and combined with the distribution characteristics of the reflection in the GPR profile,a highly accurate velocity model is built to improve the imaging resolution of the ACRTM.The accuracy and eff ectiveness of the proposed method are verified using the ACRTM test of the GPR simulated data of a typical attenuating media model.On this basis,the GPR and apparent resistivity data were observed on a field survey line,and use the GPR resistivity-constrained ACRTM method to image the observed data.A comparison of the proposed method with the conventional ACRTM method shows that the proposed method has better imaging depth,stronger energy,and higher resolution,and the obtained results are more conducive for subsequent data analysis and interpretation.

The Application of High-density Resistivity Method to the Evaluation on the Stability of Gongchangling Open Pit＇s Slope

High-density resistivity method is a new, efficient electrical prospecting method, which can complete a two-dimensional （vertical and horizontal） prospecting process, possesses certain imaging functions for the geo-electric structure, and integrates electric profiling method with electric sounding method together. In this paper, the basic principle, data processing, and result explanation and inference of high- density resistivity method are introduced by taking the application of high-density resistivity method to the prospecting project in the slope of Gongchangling Open Pit, Liaoyang. The result of the prospecting result map analysis showed that the prospecting result was basically in line with the actual situation and proved the great significance of high-density resistivity method to the evaluation on the slope stability of Gongchangling open pit.

Energy Storage System with Ultracapacitors for Thermal Underwater Glider

A power system with proton exchange membrane fuel cells (PEMFC) was designed for thermal underwater glider.Heat generated by PEMFC is used as the propulsion power of the glider,and the electricity is used in the control and sensor system.An electric energy storage system (ESS) is required which possesses high power density with good cycle life.Ultracapacitors which exhibit high power density and cycle life are considered as energy storage devices.Simulations based on a specific voyage condition indicate that ESS with ultracapacitors has positive effects on reducing the output power demand of PEMFC and lightening the power system.Experimental results show that the state of charge (SOC) is related to the capacitance and resistance in ultracapacitor ESS.

Investigation of condition-induced bubble size and distribution in electroflotation using a high-speed camera

In the flotation process, bubble is a key factor in studying bubble-particle interaction and fine particle flo- tation. Knowledge on size distribution of bubbles in a flotation system is highly important. In this study, bubble distributions in different reagent concentrations, electrolyte concentrations, cathode apertures, and current densities in electroflotation are determined using a high-speed camera. Average bubble sizes under different conditions are calculated using Image-Pro@ Plus （Media Cybernetics@, MD, USA） and SigmaScan@ Pro （Systat Software, CA, USA） software. Results indicate that the average sizes of bubbles, which were generated through 38, 50, 74, 150, 250, 420, and 1000 μm cathode apertures, are 20.2, 29.5, 44.6, 59.2, 68.7, 78.5, and 88.8 μm, respectively. The optimal current density in electroflotation is 20 A/m2. Reagent and electrolyte concentrations, current density, and cathode aperture are important factors in controlling bubble size and nucleation. These factors also contribute to the control of fine- Particle flotation.

A Methodology for Producing Uniform Distribution of UO2 in a Tungsten Matrix

We report a method to produce a uniform mixture of uranium dioxide spherical particles in a tungsten matrix. This method involves mixing 0.5 weight percent of high density polyethylene binder with 60 volume percent uranium dioxide spheres and 40 volume percent tungsten powders. Initially, hafnium oxide spheres were used as a surrogate for uranium dioxide spheres. The HfO2/W/PE powders were thoroughly mixed in a Turbula, then mixed on a hot plate above the drop point of the binder. These powders were then densified using spark plasma sintering. Microstructure was evaluated using scanning electron microscopy, density was measured and hardness measurements were made. Initial carbon content of the powders were measured and carbon content of the sintered materials was measured. Subsequently, W/UO2/Binder powders were mixed using the same methodology to ensure the process could be used for this system. These powders were sintered using hot isostatic pressing and microstructures evaluated. The resultant microstructures contained uniform distribution of HfO2 and UO2 particles in the tungsten matrix with very low carbon content.

Application of transient electromagnetic method in tunnel exploration

Along with the economic development,large tunnels need to be constructed in many high mountains or complex structure regions,and the design and construction of detailed tunnel exploration become particularly important.Transient electromagnetic method( TEM) uses a non-grounded loop or an electrode to send a primary electromagnetic pulse into the ground,and observes spatial and temporal distribution of secondary electromagnetic field,which is widely applied in mineral resource exploration,engineering geology,etc.The application of TEM in the tunnel construction of Kaiyuan Temple is researched in this study.The smoke loop inversion is adopted for inverting the transient electromagnetic data.The drilling data and high density resistivity method data are combined for comparison.The obtained inversion result greatly coincides with the actual conditions.Therefore,the geophysical prospecting basis can be provided for the division of stratum,delineation of geological structure,and design and construction of tunnel pavement.By virtue of TEM,drilling data and high density resistivity method,the tunnel construction of Kaiyuan Temple has obtained satisfactory results.

Application of high density resistivity method in accuracy of goaf detection

Based on the relationship between the diameter and buried depth of goal, the authors establish the forward modeling by Res2dmod and inverse the model by Res2dinv. Thus, three kinds of models are obtained ： the model of single resistivity anomalous body, model of double different distance resistivity anomalous body, and model of layered resistivity anomalous body. Using forward and inversion, the image of detection is simulated, and the reliability is proved by comparing with the engineering examples.

Modeling Relative Humidity Effects on Power Electronic Performance

Variations in the behavior of power supplies caused electrical behavior dependence with environmental conditions. by environmental conditions require accurate characterization of the This paper introduces models to help predict relative humidity （Rtt） and other environmental factors influence on sensitive circuitry in power electronic systems. The resistivity and permittivity of an insulator have been modeled using different water contents i.e. RH, such model also included the mechanical properties of the design. An application example of a high power density, high voltage DC-DC converter is used to verify the results.

Electrochemical Energy Storage Technologies and Applications

The current need to fasten the implementation of renewable energies greatly depends on the development of competitive storage devices, and while there is not a single technology which is likely capable to competitively cover the wide range of possible demands, electrochemical technologies are one of the most promising for many of them. For the realization of this promise, new materials fulfilling criteria such as high energy density, high power density, competitive cost, reliability, and environmental compatibility need to be developed in the near future. Electrochemical energy storage devices can be classified into two main technologies： supercapacitors and batteries （including redox flow batteries）. Materials and applications for these technologies are discussed and compared, listing current status, technical and strategic challenges.