In order to study the corrosion resistance of high-speed laser cladding(HLC) coating while improving production efficiency,a CoCrFeNiMo_(0.2)high-entropy alloy(HEA) coating was prepared by HLC.The optimized parameters...In order to study the corrosion resistance of high-speed laser cladding(HLC) coating while improving production efficiency,a CoCrFeNiMo_(0.2)high-entropy alloy(HEA) coating was prepared by HLC.The optimized parameters of HLC are laser power of 880 W,scanning speed of 18 m/min,overlapping ratio of 60%,and powder feed speed of 3 r/min.Then,the surface roughness,microstructure,phase composition,element distribution,and electrochemical properties in 3.5 wt% NaCl solution of the coatings were analyzed,respectively.The local surface roughness of the CoCrFeNiMo_(0.2)HEA coating was found to be 15.53 μm.A distinct metallurgical bond could be observed between the coating and the substrate.Compared to the conventional laser cladding(CLC),the results of electrochemical tests showed that CoCrFeNiMo_(0.2)HEA coating exhibited a significant passivation.The corrosion current density of 5.4411 × 10^(-6)A·cm^(-2) and the corrosion potential of-0.7445 V for the HLC coating were calculated by the Tafel extrapolation method.The CLC coating’s corrosion current density and corrosion potential are 2.7083×10^(-5)A·cm^(-2) and-0.9685 V,respectively.The HLC coating shows a superior corrosion resistance,crucially due to the uniform and fine grains.Under various complex and harsh working conditions,this method can be widely used in the field of repairing and remanufacturing of corro sion-proof workpiece s.展开更多
A comparative study of amorphous electroless Ni-W-P coatings on mild steel substrate treated by a high power diode laser and furnace annealing was presented.Effects of different laser operating parameters and furnace-...A comparative study of amorphous electroless Ni-W-P coatings on mild steel substrate treated by a high power diode laser and furnace annealing was presented.Effects of different laser operating parameters and furnace-annealing conditions on microstructures,in terms of crystallisation,pores formation and grain growth,were investigated using SEM/EDX and XRD. Corrosion behaviours of these coatings before and after various treatments were evaluated with anodic polarisation in 0.5 mol/L H2SO4 solution.The results show that the furnace-annealing produces either a mixture of nanocrystallined Ni and amorphous phases or precipitated Ni3P phase distributed in nanocrystallined Ni-based matrix,depending on annealing temperatures,whilst the laser treatment under the operating conditions only produces nanocrystallined Ni-based matrix with Ni3P precipitates.Corrosion performance of the coatings treated by both the laser and the furnace-annealing is dependent on the annealing temperature and laser operating conditions.Corrosion mechanisms of various treated-coatings were discussed in the consideration of phase constitutes and proportion,grain sizes of both Ni and Ni3P phases,pores formation and residual stresses.展开更多
基金Project(2020E0264) supported by the Xinjiang Science and Technology Project Plan of Autonomous Region,ChinaProject(2020D01C030) supported by the Autonomous Region Natural Science Foundation,China。
文摘In order to study the corrosion resistance of high-speed laser cladding(HLC) coating while improving production efficiency,a CoCrFeNiMo_(0.2)high-entropy alloy(HEA) coating was prepared by HLC.The optimized parameters of HLC are laser power of 880 W,scanning speed of 18 m/min,overlapping ratio of 60%,and powder feed speed of 3 r/min.Then,the surface roughness,microstructure,phase composition,element distribution,and electrochemical properties in 3.5 wt% NaCl solution of the coatings were analyzed,respectively.The local surface roughness of the CoCrFeNiMo_(0.2)HEA coating was found to be 15.53 μm.A distinct metallurgical bond could be observed between the coating and the substrate.Compared to the conventional laser cladding(CLC),the results of electrochemical tests showed that CoCrFeNiMo_(0.2)HEA coating exhibited a significant passivation.The corrosion current density of 5.4411 × 10^(-6)A·cm^(-2) and the corrosion potential of-0.7445 V for the HLC coating were calculated by the Tafel extrapolation method.The CLC coating’s corrosion current density and corrosion potential are 2.7083×10^(-5)A·cm^(-2) and-0.9685 V,respectively.The HLC coating shows a superior corrosion resistance,crucially due to the uniform and fine grains.Under various complex and harsh working conditions,this method can be widely used in the field of repairing and remanufacturing of corro sion-proof workpiece s.
基金Project(Y2006F40) supported by the Natural Science Foundation of Shandong Province, ChinaProject(N00003) supported by UK Northwest Science Council through Northwest Laser Engineering Consortium (NWLEC)
文摘A comparative study of amorphous electroless Ni-W-P coatings on mild steel substrate treated by a high power diode laser and furnace annealing was presented.Effects of different laser operating parameters and furnace-annealing conditions on microstructures,in terms of crystallisation,pores formation and grain growth,were investigated using SEM/EDX and XRD. Corrosion behaviours of these coatings before and after various treatments were evaluated with anodic polarisation in 0.5 mol/L H2SO4 solution.The results show that the furnace-annealing produces either a mixture of nanocrystallined Ni and amorphous phases or precipitated Ni3P phase distributed in nanocrystallined Ni-based matrix,depending on annealing temperatures,whilst the laser treatment under the operating conditions only produces nanocrystallined Ni-based matrix with Ni3P precipitates.Corrosion performance of the coatings treated by both the laser and the furnace-annealing is dependent on the annealing temperature and laser operating conditions.Corrosion mechanisms of various treated-coatings were discussed in the consideration of phase constitutes and proportion,grain sizes of both Ni and Ni3P phases,pores formation and residual stresses.