Alkali leaching was employed to investigate the separation of alumina and silica in roasted kaolin obtained by roasting kaolin alone in air at 1273 K for 60 min and in clinker prepared by roasting the mixed raw meal o...Alkali leaching was employed to investigate the separation of alumina and silica in roasted kaolin obtained by roasting kaolin alone in air at 1273 K for 60 min and in clinker prepared by roasting the mixed raw meal of kaolin,ferric oxide and coal powder with Fe2O3/Al2O3/C molar ratio of 1.2:2.0:1.2 in reducing atmosphere at 1373 K for 60 min.The thermodynamic analyses and alkali leaching results show that the composition of the Al-Si spinel in roasted kaolin is close to that of 3Al2O3·2SiO2 and the spinel is dissolved with increasing leaching time,resulting in difficulty in deeply separating alumina and silica in kaolin by the traditional roasting-leaching process.On the contrary,the efficient separation of alumina and silica in kaolin can be reached by fully converting kaolinite into insoluble hercynite and soluble free silica,namely quartz solid solution and cristobalite solid solution,during reduction roasting,followed by alkali leaching of the obtained clinker.Furthermore,experimental results from treating high-silica diasporic bauxite indicate that the reduction roasting-alkali leaching process is potential to separate silica and alumina in aluminosilicates.展开更多
A prototype of large-area position sensitive neutron detector was designed and constructed according to the requirements of the Small-Angle Scattering spectrometer of China Spallation Neutron Source(CSNS).The detector...A prototype of large-area position sensitive neutron detector was designed and constructed according to the requirements of the Small-Angle Scattering spectrometer of China Spallation Neutron Source(CSNS).The detector was based on the 3He neutron convertor and MWPC with an effective area of 650 mm×650 mm.A prototype was completed and tested with 55Fe X-ray.The high-pressure vessel was designed and constructed with high-strength aluminum alloy.A position resolution of about 4.6mm×2.3 mm(FWHM)and efficiency>65%for neutrons with wavelength of 1.8?was determined after the operational gas filled.展开更多
基金Project(51604309) supported by the National Natural Science Foundation of China
文摘Alkali leaching was employed to investigate the separation of alumina and silica in roasted kaolin obtained by roasting kaolin alone in air at 1273 K for 60 min and in clinker prepared by roasting the mixed raw meal of kaolin,ferric oxide and coal powder with Fe2O3/Al2O3/C molar ratio of 1.2:2.0:1.2 in reducing atmosphere at 1373 K for 60 min.The thermodynamic analyses and alkali leaching results show that the composition of the Al-Si spinel in roasted kaolin is close to that of 3Al2O3·2SiO2 and the spinel is dissolved with increasing leaching time,resulting in difficulty in deeply separating alumina and silica in kaolin by the traditional roasting-leaching process.On the contrary,the efficient separation of alumina and silica in kaolin can be reached by fully converting kaolinite into insoluble hercynite and soluble free silica,namely quartz solid solution and cristobalite solid solution,during reduction roasting,followed by alkali leaching of the obtained clinker.Furthermore,experimental results from treating high-silica diasporic bauxite indicate that the reduction roasting-alkali leaching process is potential to separate silica and alumina in aluminosilicates.
基金supported by the National Natural Science Foundation of China (Grant No.11127508)
文摘A prototype of large-area position sensitive neutron detector was designed and constructed according to the requirements of the Small-Angle Scattering spectrometer of China Spallation Neutron Source(CSNS).The detector was based on the 3He neutron convertor and MWPC with an effective area of 650 mm×650 mm.A prototype was completed and tested with 55Fe X-ray.The high-pressure vessel was designed and constructed with high-strength aluminum alloy.A position resolution of about 4.6mm×2.3 mm(FWHM)and efficiency>65%for neutrons with wavelength of 1.8?was determined after the operational gas filled.
