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高镍铜镍矿床的特征、形成机制与勘查展望 被引量:10
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作者 毛亚晶 秦克章 唐冬梅 《岩石学报》 SCIE EI CAS CSCD 北大核心 2018年第8期2410-2424,共15页
岩浆铜镍矿床100%硫化物中的Ni含量与赋矿岩石和成矿过程紧密相关,记录岩浆成分、分异程度与硫化物演化过程。硫化物异常高镍(高镍硫化物)往往被认为与科马提质岩浆或者后期热液作用密切相关。近年研究结合勘查证实,赋含高镍硫化物的矿... 岩浆铜镍矿床100%硫化物中的Ni含量与赋矿岩石和成矿过程紧密相关,记录岩浆成分、分异程度与硫化物演化过程。硫化物异常高镍(高镍硫化物)往往被认为与科马提质岩浆或者后期热液作用密切相关。近年研究结合勘查证实,赋含高镍硫化物的矿床(高镍铜镍矿床)不仅限于科马提岩,还与苦橄质、玄武质岩浆有关,另外,热液富集作用并不是必要因素。本文总结了世界上高镍铜镍矿床的基本特征和形成机制,分析提出了不同机制的判别标志,并展望了其勘查前景。详细对比高镍铜镍矿床的产出环境、赋矿岩相、矿石特征、矿物组合等特征,该类矿床往往产于大陆裂谷和造山带环境,与基性程度较高的岩浆有关,以橄榄岩赋矿为主,含镍硫化物组合主要为镍黄铁矿-磁黄铁矿-黄铜矿组合,少数为针镍矿-镍黄铁矿-黄铁矿组合。科马提岩相关矿床可将Ni含量大于16%的硫化物定义为高镍硫化物,苦橄质-玄武质岩浆相关矿床的硫化物可分为高镍硫化物(Ni>10%)、中镍硫化物(5%~10%)和富铜硫化物(Ni<5%,Cu>Ni)。原生高镍硫化物可由富镍岩浆熔离、硫化物从橄榄石中吸取Ni、硫化物结晶分异、硫化物与硫不饱和岩浆反应等机制形成。苦橄质-玄武质岩浆相关的矿床,硫化物与橄榄石的Fe-Ni交换反应是高镍硫化物形成的重要机制。辉石岩源区地幔部分熔融形成富镍岩浆是否为高镍硫化物形成的必要条件尚存争议。不同机制形成的高镍硫化物具有迥异的岩石-矿物组合和地化特征。硫化物矿物组合、橄榄石成分(Fo值、Ni含量、Fo值-Ni含量的相关性)、伴生元素(铜、铂族元素)丰度-配分模式等特征可作为区分不同高镍硫化物形成机制的有效指标。我国新疆黄山南、坡一和青海夏日哈木矿床(部分浸染状矿化橄榄岩)以赋含高镍硫化物为特征,新疆喀拉通克矿床的硫化物则以富铜为特征,中国其余矿床的硫化物均属中镍硫化物。目前研究指示中国的高镍铜镍矿床与母岩浆相对富镍、硫化物与橄榄石Fe-Ni交换作用密切相关,后者可使硫化物Ni含量提升3%~5%。在铜镍矿床勘查方面,稀疏-中等浸染状高镍硫化物矿石即可达到工业品位,稠密浸染状-块状高镍硫化物矿石可达到很高的Ni品位(10%),是高品位镍矿勘查的一个重要方向。造山带环境富水、相对高氧逸度(可高达QFM+1)的岩浆可能是形成高镍硫化物的有利条件,该环境橄榄石Fo值较高(>87mol%)的岩体有利于形成高镍硫化物。 展开更多
关键词 岩浆铜矿床 高镍硫化物 黄山南 坡一 夏日哈木 造山带铜矿勘查
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Application of response surface methodology in optimization of bioleaching parameters for high-magnesium nickel sulfide ore 被引量:3
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作者 SUN Jian-zhi WU Biao +1 位作者 CHEN Bo-wei WEN Jian-kang 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第5期1488-1499,共12页
The response surface methodology(RSM)was used to optimize the operating parameters during the bioleaching of Jinchuan high-magnesium nickel sulfide ore.The particle size,acid addition,pulp density and inoculation amou... The response surface methodology(RSM)was used to optimize the operating parameters during the bioleaching of Jinchuan high-magnesium nickel sulfide ore.The particle size,acid addition,pulp density and inoculation amount were chosen as the investigated parameters.To maximize the leaching efficiency of nickel,copper,cobalt and minimize the dissolution of magnesium and iron ions,the model suggested a combination of optimal parameters of particles less than 0.074 mm being 72.11%,sulfuric acid addition being 300 kg/t,pulp density being 5%and inoculation amount being 12.88%.Under the conditions,the average results of three parallel experiments were 89.43%of nickel leaching efficiency,36.78%of copper leaching efficiency,84.07%of cobalt leaching efficiency,49.19%of magnesium leaching efficiency and 0.20 g/L of iron concentration.The model indicated that the most significant factor in response of the leaching efficiency of valuable metal is the particle size,and the most significant factor in response to the leaching efficiency of harmful ions(Mg2+)is the amount of sulfuric acid addition.And according to the suggested models,no significance of the interaction effect between particle size and acid addition was shown.Under the optimized parameters suggested by models,the valuable metals could be separated from harmful ions during the bioleaching process. 展开更多
关键词 high-magnesium nickel sulfide ore BIOLEACHING response surface methodology particle size acid consumption
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