The microstructure of an alloy is affected intensively by the cooling process.To figure out the inherent relation between the cooling rate and microstructure of an advanced nickel-based superalloy,experimental and num...The microstructure of an alloy is affected intensively by the cooling process.To figure out the inherent relation between the cooling rate and microstructure of an advanced nickel-based superalloy,experimental and numerical studies on the cooling process were conducted.Specifically,the measurement was performed concerning both the temperature of the specimen during the end-quench test and the size of the secondaryγ′phase of the specimen after that.The heat transfer coefficient of the quenched surface was determined by the inverse heat transfer method for simulation.The results show that the cooling rate of the quenched surface exceeds 1574 K/min.Based on the averaged cooling rate obtained from the simulation and the measured size of the secondaryγ′phase,an empirical correlation in a double logarithmic relationship between them is proposed.The relationship is verified by the experiment with specified cooling rates.展开更多
By electrodeposition in organic system,NiO films with reversible electrochromic property were fabricated.Fluorine-doped tin oxide glass slices were used as substrates,i.e.cathodes.Cyclic voltammetry and ultraviolet-vi...By electrodeposition in organic system,NiO films with reversible electrochromic property were fabricated.Fluorine-doped tin oxide glass slices were used as substrates,i.e.cathodes.Cyclic voltammetry and ultraviolet-visible transmission spectroscopy were adopted to study the electrochromic properties of the films.High resolution transmission electron microscopy(HRTEM) was employed to analyze the composition and structure of the films.It is found that the films are composed of fine NiO crystal grains of a few nanometers in diameter,endowing them with large visible light transmittance variation,rapid switch rate(i.e.rapid response time) between the bleached and colored states.Their cycling durability reached 6000 cycles.展开更多
基金Project(2016YFB0700300) supported by the National Key Research and Development Program of ChinaProject(2019zzts262) supported by the Postgraduate Independent Exploration and Innovation Program of Central South University,China
文摘The microstructure of an alloy is affected intensively by the cooling process.To figure out the inherent relation between the cooling rate and microstructure of an advanced nickel-based superalloy,experimental and numerical studies on the cooling process were conducted.Specifically,the measurement was performed concerning both the temperature of the specimen during the end-quench test and the size of the secondaryγ′phase of the specimen after that.The heat transfer coefficient of the quenched surface was determined by the inverse heat transfer method for simulation.The results show that the cooling rate of the quenched surface exceeds 1574 K/min.Based on the averaged cooling rate obtained from the simulation and the measured size of the secondaryγ′phase,an empirical correlation in a double logarithmic relationship between them is proposed.The relationship is verified by the experiment with specified cooling rates.
基金sponsored by the Natural Science Foundation of Shandong Province of China (Grant No. ZR2010EM027)the Applied and Basic Research Project (11-2-4-1-(2)-jch) of Qingdao Municipal Science Technology Commission of China
文摘By electrodeposition in organic system,NiO films with reversible electrochromic property were fabricated.Fluorine-doped tin oxide glass slices were used as substrates,i.e.cathodes.Cyclic voltammetry and ultraviolet-visible transmission spectroscopy were adopted to study the electrochromic properties of the films.High resolution transmission electron microscopy(HRTEM) was employed to analyze the composition and structure of the films.It is found that the films are composed of fine NiO crystal grains of a few nanometers in diameter,endowing them with large visible light transmittance variation,rapid switch rate(i.e.rapid response time) between the bleached and colored states.Their cycling durability reached 6000 cycles.
