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用于中间相沥青制备的两种催化裂化油浆组成分析 被引量:1
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作者 张彪 董森 +6 位作者 唐亚昆 刘浪 刘宏博 李杨俊迪 何平 刘景梅 马凤云 《新疆大学学报(自然科学版)(中英文)》 CAS 2023年第6期704-708,723,共6页
中间相沥青作为制备高性能碳材料的重要前驱体,研究影响中间相沥青结构的因素(原料组成和制备工艺)对推动碳材料发展具有重要意义.以新疆两种催化裂化油浆为原料,经凝胶渗透色谱(GPC)、核磁共振氢谱(^(1)H-NMR)、元素分析、气相色谱-质... 中间相沥青作为制备高性能碳材料的重要前驱体,研究影响中间相沥青结构的因素(原料组成和制备工艺)对推动碳材料发展具有重要意义.以新疆两种催化裂化油浆为原料,经凝胶渗透色谱(GPC)、核磁共振氢谱(^(1)H-NMR)、元素分析、气相色谱-质谱联用(GC-MS)等系统表征,明晰了其组成与结构特点.针对油浆高饱和分特性(>47%),一改传统原料溶剂精制策略,采用先热解优化原料组成,再热缩聚两步法制得软化点为290℃的广域型中间相沥青. 展开更多
关键词 催化裂化油浆 中间相沥青 高饱和分 两步法
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Measurement of Two Phase Flow in Porous Medium Using High-resolution Magnetic Resonance Imaging 被引量:4
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作者 蒋兰兰 宋永臣 +4 位作者 刘瑜 杨明军 朱宁军 王晓静 豆斌林 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2013年第1期85-93,共9页
Measurement of two phase flow in porous medium for sequestration was carried out using high-resolution magnetic resonance imaging (MRI) technique. The porous medium was a packed bed of glass beads. Spin echo multi seq... Measurement of two phase flow in porous medium for sequestration was carried out using high-resolution magnetic resonance imaging (MRI) technique. The porous medium was a packed bed of glass beads. Spin echo multi sequence was used to measure the distribution of CO2 and water in the porous medium. The intensity images show that the fluid distribution is non-uniform due to its viscosity and pore structure of porous medium. The velocity distribution of fluids is calculated from the saturation of water and porosity of porous medium. The experimental results show that fluid velocities vary with time and position. The capillary dispersion rate donated the effects of capillary, which was largest at water saturations of 0.45. The displacement process is different between in BZ-02 and BZ-2. The final water residual saturation depends on permeability and porosity. 展开更多
关键词 two phase flow porous medium magnetic resonance imaging SATURATION CO2 velocity DISPLACEMENT
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Characteristics of CO_2 in unsaturated zone(~90 m) of loess tableland, Northwest China 被引量:1
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作者 Chao Song Guilin Han +2 位作者 Yingchun Shi Congqiang Liu Pan Wang 《Acta Geochimica》 EI CAS CSCD 2017年第3期489-493,共5页
In order to observe CO_2 characteristics in the unsaturated zone of loess tableland and further understand the carbon cycle,a series of tubes for gas monitoring and sampling were installed in an approximately 90-m dee... In order to observe CO_2 characteristics in the unsaturated zone of loess tableland and further understand the carbon cycle,a series of tubes for gas monitoring and sampling were installed in an approximately 90-m deep Qiushe loess section of Lingtai County,Northwestern China.The results show that the concentration of CO_2 was higher in loess than in the atmosphere,reaching a maximum of 6970 lmol·mol^(-1).CO_2 concentrations in loess were higher in summer than in winter.The CO_2 in loess was related to organic carbon decomposed by microbes,and to the CaCO_3–H_2O–CO_2 system in the interface between the saturated and unsaturated zones. 展开更多
关键词 Unsaturated zone Soil CO2 Carbon stock in deep loess Quantitative paleoclimate reconstruction LOESS
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Profile Distributions of Dissolved and Colloidal Phosphorus as Affected by Degree of Phosphorus Saturation in Paddy Soil 被引量:6
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作者 ZANG Ling TIAN Guang-Ming +3 位作者 LIANG Xin-Qing HE Miao-Miao BAO Qi-Bei YAO Jin-Hua 《Pedosphere》 SCIE CAS CSCD 2013年第1期128-136,共9页
Soil dissolved phosphorus (P) and colloidal P mobilization could be closely related to the degree of phosphorus saturation (DPS). Effects of a wide range of DPS on the distributions of dissolved P and colloidal P in a... Soil dissolved phosphorus (P) and colloidal P mobilization could be closely related to the degree of phosphorus saturation (DPS). Effects of a wide range of DPS on the distributions of dissolved P and colloidal P in a paddy soil profile were investigated in this study. Dissolved P and colloidal P in water-dispersible soil colloid suspension increased obviously with increasing DPS. The change point of DPS was at 0.12 by using a split-line model. Above the value, dissolved P (3.1 mg P kg-1 ) in soil profile would increase sharply and then transfer downward. Compared with dissolved P, colloidal P was the dominant fraction (78%-91%) of P in soil colloid suspension, and positively related to DPS without a significant change point. The high release of colloids in subsoils with low DPS was attributed to the low ionic strength and high pH value in subsoils. The DPS also had a significant and positive correlation with electrical conductivity (EC), but it showed a negative correlation with pH value. However, the concentration of colloidal P was not greatly correlated to the pH value, EC and optical density of the soil colloid suspension. The results indicated that DPS was an important factor that may affect the accumulation and mobilization of water-extractable colloidal P and dissolved P. 展开更多
关键词 inorganic fertilizer ionic strength MANURE split-line model water-dispersible soil colloid
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