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Influence of minor Sc additions on grain refinement and microstructure characteristics of a high Zn-containing Al-Zn-Mg-Cu-Zr alloy 被引量:3
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作者 WEN Kai LI Xi-wu +5 位作者 XIONG Bai-qing LIU Hong-lei WANG Ying-jun LI Zhi-hui ZHANG Yong-an LI Ya-nan 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第3期780-794,共15页
In the present work, scandium elements with a series of contents(0.06 wt.%, 0.10 wt.%, 0.14 wt.%,0.17 wt.%, 0.20 wt.% and 0.25 wt.%) were added in a high Zn-containing Al-Zn-Mg-Cu-Zr alloy and the corresponding as-cas... In the present work, scandium elements with a series of contents(0.06 wt.%, 0.10 wt.%, 0.14 wt.%,0.17 wt.%, 0.20 wt.% and 0.25 wt.%) were added in a high Zn-containing Al-Zn-Mg-Cu-Zr alloy and the corresponding as-cast microstructure characteristics including grains and phases were thoroughly investigated. The results indicated that fine grain boundaries existed in these alloys and fine MgZn2phases discontinuously distributed on them. Besides,AlZnMgCu eutectic phases and Sc, Zr-containing phases with flocculent morphology were observed. As scandium contents vary from 0.06 wt.% to 0.17 wt.%, the average grain size continuously decreased and its equiaxial characteristics were strengthened. Meanwhile, the content of AlZnMgCu eutectic phase showed a decrease trend. When scandium contents were 0.20 wt.% and 0.25 wt.%, no further enhancement on grain refinement was observed, so as to the reduction of AlZnMgCu eutectic phase content. Besides, Sc, Zr-containing phases with blocky morphology were observed and the alloy with a scandium content of 0.25 wt.% possessed a larger amount of blocky Sc, Zr-containing phase than the alloy with a scandium content of 0.20 wt.%. Grain refinement and reduction of AlZnMgCu eutectic phase content associated with scandium addition were discussed. 展开更多
关键词 Al-Zn-Mg-Cu-Zr alloy high zinc content microstructure sc addition grain refinement phase evolution
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高Sc掺杂AlN薄膜铁电性能的研究
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作者 习娟 周大雨 吕天明 《功能材料与器件学报》 CAS 2024年第5期239-246,共8页
纤锌矿铁电材料因其大的剩余极化(P_(r))、优良的高温稳定性以及与半导体工艺的良好兼容性,受到了广泛的关注。然而,纤锌矿钪掺杂氮化铝(AlScN)铁电薄膜应用于非易失性存储器的主要挑战是其较大的矫顽场(E_(c)),以及在高电场下较大的漏... 纤锌矿铁电材料因其大的剩余极化(P_(r))、优良的高温稳定性以及与半导体工艺的良好兼容性,受到了广泛的关注。然而,纤锌矿钪掺杂氮化铝(AlScN)铁电薄膜应用于非易失性存储器的主要挑战是其较大的矫顽场(E_(c)),以及在高电场下较大的漏电流。为制备具有低E_(c)和高电场下低漏电流的AlScN薄膜,本文采用反应磁控溅射的方法,在不同底电极(Mo、TiN和Al)上沉积了高钪含量的Al_(0.57)Sc_(0.43)N铁电薄膜。通过X射线光电子能谱、X射线衍射仪、原子力显微镜、扫描电镜和铁电测试仪对薄膜的成分、微观结构及电性能进了分析。实验结果表明:在不同底电极上沉积的Al_(0.57)Sc_(0.43)N薄膜均表现出明显的c轴取向,并展现出显著的铁电性,E_(c)^(-)分别为2.6、3.5和2.3 MV/cm。TiN作为底电极时,AlScN铁电薄膜获得较大的剩余极化值且薄膜的漏电流较小。 展开更多
关键词 AlscN铁电薄膜 C轴取向 高sc含量
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