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轨道车辆用硅酮密封胶的黄变行为研究
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作者 张静 张晓成 +3 位作者 张俊美 沈鹤飞 郑自芹 梁景恒 《橡胶工业》 CAS 2024年第10期723-730,共8页
研究轨道车辆用硅酮密封胶与橡胶基材粘接时产生的黄变行为。结果表明:在空气、高温(80℃)和紫外光环境下静置5 d,挤涂在橡胶基材A上的硅酮密封胶发生不同程度的黄变,挤涂在铝合金基材和橡胶基材B上的硅酮密封胶未发生黄变;黄变前后硅... 研究轨道车辆用硅酮密封胶与橡胶基材粘接时产生的黄变行为。结果表明:在空气、高温(80℃)和紫外光环境下静置5 d,挤涂在橡胶基材A上的硅酮密封胶发生不同程度的黄变,挤涂在铝合金基材和橡胶基材B上的硅酮密封胶未发生黄变;黄变前后硅酮密封胶1#和2#的傅里叶红外光谱特征峰和元素相对含量均无明显变化,即硅酮密封胶的黄变不是其自身分子结构改变导致的;硅酮密封胶与橡胶基材A粘接时发生黄变行为主要是由于橡胶基材A中的小分子物质迁移至硅酮密封胶导致的;含有苯环和羧基等不饱和键基团的邻苯二甲酸酯类增塑剂以及胺类物质二丁基胺在紫外光环境下易发生分子结构变化,进而导致硅酮密封胶黄变。 展开更多
关键词 黄变行为 硅酮密封胶 橡胶基材 粘接
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Humidification vibration deformation behavior of intact loess 被引量:1
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作者 CHENG Da-wei LUO Ya-sheng +2 位作者 WU Cai-ping CHEN Xi GUO Hong 《Journal of Central South University》 SCIE EI CAS 2013年第7期1985-1991,共7页
A parameter, known as the parameter of humidification vibration deformation, was proposed, describing quantitatively the impact of water content on vibration settlement deformation, and its relationship with humidific... A parameter, known as the parameter of humidification vibration deformation, was proposed, describing quantitatively the impact of water content on vibration settlement deformation, and its relationship with humidification water content, dynamic shear stress peak value, initial consolidation stress and vibration frequency was built. The result shows that 1) the parameter of humidification vibration deformation increases with the vibration shear stress peak value increasing. 2) The humidification water content has significant influence on the curve of the parameter of humidification vibration deformation and the peak vibration shear stress. When the humidification water content is low, the curve increases slowly. However, when the humidification water content is high, the curve increases rapidly. 3) Initial consolidation stress has significant influence on the humidification vibration deformation coefficient. When initial consolidation stress is not large enough to destroy the loess structure, with initial consolidation stress increasing, the humidification vibration deformation coefficient decreases. On the contrary, the humidification vibration deformation coefficient increases with initial consolidation stress increasing. 4) With the increase of vibration time, the parameter of humidification vibration settlement shows an increasing trend overall. The initial dynamic shear stress peak value and humidification water content all have significant effects on the curve of the parameter of humidification vibration settlement and vibration time. However, the humidification water content is even more significant. 展开更多
关键词 intact loess vibration deformation humidification vibration deformation coefficient
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Analysis of mechanical behaviors of big pipe roof for shallow buried large-span tunnel
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作者 Li Jian Tan Zhongsheng +1 位作者 Yu Yu Guo Xiaohong 《Engineering Sciences》 EI 2013年第6期32-37,共6页
A series of researches on mechanical behaviors of big pipe roof for shallow large-span loess tunnel were carried out based on the Wenxiang tunnel in Zhengzhou—Xi'an Special Passenger Railway. The longitudinal def... A series of researches on mechanical behaviors of big pipe roof for shallow large-span loess tunnel were carried out based on the Wenxiang tunnel in Zhengzhou—Xi'an Special Passenger Railway. The longitudinal deformations of the pipe roofs were monitored and the mechanical behaviors of the pipe roofs were analyzed at the test section. A new double-parameter elastic foundation beam model for pipe roof in shallow tunnels was put forward in Wenxiang tunnel. The measured values and the calculation results agreed well with each other,revealing the force-deformation law of big pipe roof in loess tunnel:At about 15 m in front of the excavating face,the pipe roof starts to bear the load;at about 15 m behind the excavating face,the force of the pipe roof tends to be stabilized;the longitudinal deformation of the whole pipe roofs is groove-shaped distribution,and the largest force of pipe roofs is at the excavating face. Simultaneously,the results also indicate that mechanical behaviors of pipe roof closely relate to the location of the excavation face,the footage of the tunnelling cycle and the mechanics parameters of pipe roof and rock. The conclusions can be reference for the design parameter optimization and the construction scheme selection of pipe roofs,and have been verified by the result of numerical analysis software FLAC3Dand deformation monitoring. 展开更多
关键词 shallow burying mining underpass construction loess tunnel pipe roof deformation monitoring mechanical behavior
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