A new triterpenoid saponin was isolated from Lonicera fulvotomentosa.The structure of the new tri-terpenoid saponin,named Fulvotomentoside B,was elucidated as 3-O-β-D-xylopyranosyl(1→3)-α-L-rhamnopyranosyl(1→2)-α...A new triterpenoid saponin was isolated from Lonicera fulvotomentosa.The structure of the new tri-terpenoid saponin,named Fulvotomentoside B,was elucidated as 3-O-β-D-xylopyranosyl(1→3)-α-L-rhamnopyranosyl(1→2)-α-L-arabinopyranosyl hederagenin-28-O-β-D-xylopyranosyl(1→6)-β-D-glucopyranosyl ester on the basis of spectroscopic analysis as well as chemical methods.In addition,the structure of Fulvotomentoside A,the previously reported major saponin,was revised,and it should be 3-O-β-D-xylopyranosyl(1→3)-α-L-rhamnopyranosyl(1→2)-α-L-arabinopyranosyl hederagenin-28-O-β-D-glucopyranosy(1→6)-β-D-glucopyranosyl ester(Decaisoside E) on the basis of careful analyses of new spectroscopical data.展开更多
文摘A new triterpenoid saponin was isolated from Lonicera fulvotomentosa.The structure of the new tri-terpenoid saponin,named Fulvotomentoside B,was elucidated as 3-O-β-D-xylopyranosyl(1→3)-α-L-rhamnopyranosyl(1→2)-α-L-arabinopyranosyl hederagenin-28-O-β-D-xylopyranosyl(1→6)-β-D-glucopyranosyl ester on the basis of spectroscopic analysis as well as chemical methods.In addition,the structure of Fulvotomentoside A,the previously reported major saponin,was revised,and it should be 3-O-β-D-xylopyranosyl(1→3)-α-L-rhamnopyranosyl(1→2)-α-L-arabinopyranosyl hederagenin-28-O-β-D-glucopyranosy(1→6)-β-D-glucopyranosyl ester(Decaisoside E) on the basis of careful analyses of new spectroscopical data.