在300—500℃,300—10000巴条件下实验测定了0—8N NaCl溶液中辉钼矿的溶解度。结果表明:温度增加100℃。C或压力增加100巴,溶解度分别增加10倍和5倍。低盐度条件下增加7 N NaCl溶解度增加5—10倍。高盐度时钼以氯的络合物形式迁移.在P...在300—500℃,300—10000巴条件下实验测定了0—8N NaCl溶液中辉钼矿的溶解度。结果表明:温度增加100℃。C或压力增加100巴,溶解度分别增加10倍和5倍。低盐度条件下增加7 N NaCl溶解度增加5—10倍。高盐度时钼以氯的络合物形式迁移.在PH值为6和350℃、300巴时,若S^(2-)离子浓度为10^(-8)M,则钼的临界浓度值为10^(-8)M(1 PPm)。因此,当温度、压力、盐度和PH值变化导致其中任一离子浓度增高都将使辉钼矿析出沉淀。展开更多
The more oxidized mantle peridotites above subducting slabs than stable continental areas have been attributed to the infiltration of some oxidizing fluids released from the subducting slabs. However, knowledge for th...The more oxidized mantle peridotites above subducting slabs than stable continental areas have been attributed to the infiltration of some oxidizing fluids released from the subducting slabs. However, knowledge for the redox states of the slabs itself is very limited. Until now, few oxybarometers can be directly used to constrain the redox states of the subducting slabs.The rutile-ilmenite oxybarometer was proposed and successfully applied to constrain the oxygen fugacity of mantle assemblages.However, its application to rocks equilibrated at crustal P-T conditions has been hampered by some uncertainties in an early solid solution model of ilmenite. With a newly-released solid solution model for the ilmenite, we have conducted high-P experiments(at 3 and 5 GPa, and 900–1300°C) to test the accuracy of this oxybarometer. The experiments were performed with their oxygen fugacities controlled by the CCO buffer(i.e., C+O_2=CO_2). We demonstrated that the oxygen fugacities calculated for our high-P experimental products by using the rutile-ilmenite oxybarometer were in excellent agreement with the fO_2 dictated by the CCO buffer, suggesting a wide applicability of this oxybarometer to crust rocks. As examples, the rutile-ilmenite oxybarometer has been used to constrain the oxygen fugacities of some metamorphic rocks such as eclogite, granulite and amphibolite usually observed from the subduction zones.展开更多
文摘在300—500℃,300—10000巴条件下实验测定了0—8N NaCl溶液中辉钼矿的溶解度。结果表明:温度增加100℃。C或压力增加100巴,溶解度分别增加10倍和5倍。低盐度条件下增加7 N NaCl溶解度增加5—10倍。高盐度时钼以氯的络合物形式迁移.在PH值为6和350℃、300巴时,若S^(2-)离子浓度为10^(-8)M,则钼的临界浓度值为10^(-8)M(1 PPm)。因此,当温度、压力、盐度和PH值变化导致其中任一离子浓度增高都将使辉钼矿析出沉淀。
基金supported by the National Natural Science Foundation of China(Grant Nos.41520104004&41502038)the China Postdoctoral Science Foundation(Grant No.2015M570009)
文摘The more oxidized mantle peridotites above subducting slabs than stable continental areas have been attributed to the infiltration of some oxidizing fluids released from the subducting slabs. However, knowledge for the redox states of the slabs itself is very limited. Until now, few oxybarometers can be directly used to constrain the redox states of the subducting slabs.The rutile-ilmenite oxybarometer was proposed and successfully applied to constrain the oxygen fugacity of mantle assemblages.However, its application to rocks equilibrated at crustal P-T conditions has been hampered by some uncertainties in an early solid solution model of ilmenite. With a newly-released solid solution model for the ilmenite, we have conducted high-P experiments(at 3 and 5 GPa, and 900–1300°C) to test the accuracy of this oxybarometer. The experiments were performed with their oxygen fugacities controlled by the CCO buffer(i.e., C+O_2=CO_2). We demonstrated that the oxygen fugacities calculated for our high-P experimental products by using the rutile-ilmenite oxybarometer were in excellent agreement with the fO_2 dictated by the CCO buffer, suggesting a wide applicability of this oxybarometer to crust rocks. As examples, the rutile-ilmenite oxybarometer has been used to constrain the oxygen fugacities of some metamorphic rocks such as eclogite, granulite and amphibolite usually observed from the subduction zones.
