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新型中、远红外波段非线性光学晶体磷化锗锌 被引量:18
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作者 杨春晖 张建 《人工晶体学报》 EI CAS CSCD 北大核心 2004年第2期141-143,共3页
中、远红外波段黄铜矿类半导体晶体磷化锗锌(ZnGeP2,ZGP)非线性系数、热导率、光损伤阈值高,在中、远红外波段的频率转换方面有广阔的应用前景,特别是其非线性系数是KDP的160倍,是已知非线性光学晶体中最高者之一。该晶体的生长及其应... 中、远红外波段黄铜矿类半导体晶体磷化锗锌(ZnGeP2,ZGP)非线性系数、热导率、光损伤阈值高,在中、远红外波段的频率转换方面有广阔的应用前景,特别是其非线性系数是KDP的160倍,是已知非线性光学晶体中最高者之一。该晶体的生长及其应用研究正在逐渐引起各国政府和科研人员的高度重视,并成为材料与光电子(激光)领域的研究热点之一。本文全面综述了该晶体的物性与电光性能,以及多晶原料的合成与单晶的生长方法和其应用前景。 展开更多
关键词 光学晶体 磷化锗锌 晶体生长机理 黄铜矿类化合物 电光性能 生长方法
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Characterization of CulnS2 Thin Films with Different Cu/In Ratio
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作者 Mutlu Kundakcl 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2010年第5期582-586,622,共6页
Thin films of CuInS2 were grown on glass reaction method with different [Cu]/[In] substrate by successive ionic layer adsorption and ratios and annealed at 400℃ for 30 rain. The crystal structure and grain sizes of t... Thin films of CuInS2 were grown on glass reaction method with different [Cu]/[In] substrate by successive ionic layer adsorption and ratios and annealed at 400℃ for 30 rain. The crystal structure and grain sizes of the thin films were characterized by X-ray diffraction method. Atomic force microscopy was used to determine surface morphology of the films. Optical and electrical properties of these films were investigated as a function of [Cu]/[In] ratios. The electrical resistivity of CuInS~ of thin films was determined using a direct current- two probe method in the temperature range of 300-470 K. It is observed that, the electrical resistivity values show a big decreasing with increasing [Cu]/[In] ratio. Hence, the [Cu]/[In] ratio in the solution can drastically affect the structural, electrical, and optical properties of thin films of CuInS2. 展开更多
关键词 Thin filml Successive ionic layer adsorption Chalcopyrite compound
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