为了进一步揭示影响泡沫封堵性能的根本原因,首先通过泡沫驱替实验研究了温度对泡沫封堵性能的影响,然后利用界面流变仪分析了界面参数随温度的变化,在此基础上,建立起泡沫封堵性能与界面性质之间的联系,考察界面性质对泡沫封堵性能的...为了进一步揭示影响泡沫封堵性能的根本原因,首先通过泡沫驱替实验研究了温度对泡沫封堵性能的影响,然后利用界面流变仪分析了界面参数随温度的变化,在此基础上,建立起泡沫封堵性能与界面性质之间的联系,考察界面性质对泡沫封堵性能的影响。结果表明:当温度由20℃升高到80℃时,泡沫封堵能力先增后减,40℃时达到最大,80℃时阻力因子减小80%以上,有效倍数降低至40℃时的六分之一。相同温度变化范围内,平衡界面张力先减后增,40℃时界面张力最小为28.6 m N×m^(-1),而扩张模量和界面弹性模量先增后减,界面黏性模量则逐渐减小,40℃时工作频率0.1 Hz对应的最大扩张模量、界面弹性模量和界面黏性模量分别为9.24、8.74、2.97 m N×m^(-1)。界面流变性表征了泡沫液膜性质,封堵性能好的泡沫应同时具有一定的高黏度和良好的弹性,界面弹性模量和界面黏性模量共同影响泡沫封堵性能;界面张力与泡沫封堵性能呈负相关关系,界面张力越小,越有利于泡沫再生,并对应越大界面模量,因而泡沫封堵性能越好。展开更多
This study examined the mechanisms for improving the adhesion performance of the asphalt-aggregate interface with two anti-stripping agents and two coupling agents.The investigation of contact behavior between various...This study examined the mechanisms for improving the adhesion performance of the asphalt-aggregate interface with two anti-stripping agents and two coupling agents.The investigation of contact behavior between various asphalt-aggregate surfaces was conducted using molecular dynamics(MD)simulations.The interaction energy and the relative concentration distribution were employed as the parameters to analyze the enhancement mechanisms of anti-stripping agents and coupling agents on the asphalt-aggregate interface.Results indicated that the adhesion at the asphalt-aggregate interface could be strengthened by both anti-stripping agents and coupling agents.Anti-stripping agents primarily improve adhesion through the reinforcement of electrostatic attraction,while coupling agents primarily upgrade adhesion by strengthening the van der Waals.Hence,the molecular dynamics modeling and calculation techniques presented in this study can be utilized to elucidate the development mechanism of the asphalt-aggregate interface through the use of anti-stripping agents and coupling agents.展开更多
文摘为了进一步揭示影响泡沫封堵性能的根本原因,首先通过泡沫驱替实验研究了温度对泡沫封堵性能的影响,然后利用界面流变仪分析了界面参数随温度的变化,在此基础上,建立起泡沫封堵性能与界面性质之间的联系,考察界面性质对泡沫封堵性能的影响。结果表明:当温度由20℃升高到80℃时,泡沫封堵能力先增后减,40℃时达到最大,80℃时阻力因子减小80%以上,有效倍数降低至40℃时的六分之一。相同温度变化范围内,平衡界面张力先减后增,40℃时界面张力最小为28.6 m N×m^(-1),而扩张模量和界面弹性模量先增后减,界面黏性模量则逐渐减小,40℃时工作频率0.1 Hz对应的最大扩张模量、界面弹性模量和界面黏性模量分别为9.24、8.74、2.97 m N×m^(-1)。界面流变性表征了泡沫液膜性质,封堵性能好的泡沫应同时具有一定的高黏度和良好的弹性,界面弹性模量和界面黏性模量共同影响泡沫封堵性能;界面张力与泡沫封堵性能呈负相关关系,界面张力越小,越有利于泡沫再生,并对应越大界面模量,因而泡沫封堵性能越好。
文摘This study examined the mechanisms for improving the adhesion performance of the asphalt-aggregate interface with two anti-stripping agents and two coupling agents.The investigation of contact behavior between various asphalt-aggregate surfaces was conducted using molecular dynamics(MD)simulations.The interaction energy and the relative concentration distribution were employed as the parameters to analyze the enhancement mechanisms of anti-stripping agents and coupling agents on the asphalt-aggregate interface.Results indicated that the adhesion at the asphalt-aggregate interface could be strengthened by both anti-stripping agents and coupling agents.Anti-stripping agents primarily improve adhesion through the reinforcement of electrostatic attraction,while coupling agents primarily upgrade adhesion by strengthening the van der Waals.Hence,the molecular dynamics modeling and calculation techniques presented in this study can be utilized to elucidate the development mechanism of the asphalt-aggregate interface through the use of anti-stripping agents and coupling agents.