本文根据Hansford(1946,1961)的分类系统和鉴定方法,采集鉴定和整理了福建省黑煤菌共4属43种;附丝壳属(Appendiculella)4种、小光壳炱属(Asteridiella)9种、隔孢炱属(Balladynastrum)1种以及小煤炱属(Meliola)29种,其中包括1个新种和13...本文根据Hansford(1946,1961)的分类系统和鉴定方法,采集鉴定和整理了福建省黑煤菌共4属43种;附丝壳属(Appendiculella)4种、小光壳炱属(Asteridiella)9种、隔孢炱属(Balladynastrum)1种以及小煤炱属(Meliola)29种,其中包括1个新种和13个在中国分布的新记录,新种是(?)木生小煤炱Meliola loropetalicola Y.X.Hu et Y.S.Ouyang,新种有中文、拉丁文描述和显微结构图。模式标本藏于广东省微生物研究所。展开更多
The hydrophobic flocculation of marmatite fines in aqueous suspensions induced by butyl xanthate （KBX） and ammonium dibutyl dithiophosphate （ADD） was investigated using laser particle size analysis, microscopy ana...The hydrophobic flocculation of marmatite fines in aqueous suspensions induced by butyl xanthate （KBX） and ammonium dibutyl dithiophosphate （ADD） was investigated using laser particle size analysis, microscopy analysis, electrophoretic light scattering, contact angle measurement and infrared spectroscopy. The studies were performed on single minerals with size 〈20 μm by varying several parameters, including pH, collector concentration and kerosene addition. The results show that the floc fotation closely correlated with the size of flocs and the particle hydrophobicity, but was not lowered with increasing the particle surface charges due to collector adsorption. Under good operating conditions, the floc flotation of marmatite fines as a function of KBX and ADD can all reach floatability over 90%, in comparison with conventional flotation obtaining floatability of about 60%. It also has been found that a small addition of kerosene greatly improved the floc flotation because of the formation of oil films on marmatite particles. The results of FTIR spectra indicate that adsorption of the two collectors onto marmatite were chemical adsorption.展开更多
CO2 gasification of Fuijian high-metamorphous anthracite with black liquor （BL） and/or mixture of BL and calcium stuff （BL＋Ca） as catalyst was studied by using a thermogravimetry under 750-950℃ at ambient pressu...CO2 gasification of Fuijian high-metamorphous anthracite with black liquor （BL） and/or mixture of BL and calcium stuff （BL＋Ca） as catalyst was studied by using a thermogravimetry under 750-950℃ at ambient pressure. When the coal was impregnated with an appropriate quantity of Ca and BL mixture, the catalytic activity of CO2 gasification was enhanced obviously. With a loading of 8%Na-BL＋2%Ca, the carbon conversion of three coal samples tested reaches up to 92.9%-99.3% at 950℃ within 30min. The continuous formation of alkali surface compounds such as （[-COM], [-CO2M]） and the presence of exchanged Ca, such as calcium phenolate and calcium carboxylates （COO）2Ca, contribute to the increase in catalytic efficiency, and using BL＋Ca is more efficient than that adding BL only, The homogeneous model and shrinking-core model were applied to correlate the data of conversion with time and to estimate the reaction rate constants under different temperature. The corresponding reaction activation energy （Ea） and pre-exponential factor of three anthracites were estimated. It is found that Ea is in the range from 73.6 to 121.4kJ·mol^-1 in the case of BL＋Ca, and 74.3 to 104.2kJ·mol^-1 when only BL was used as the catalyst, both of which are much less than that from 143.5 to 181.4kJ·mol^-1 if no catalyst used. It is clearly demonstrated that both of BL＋Ca mixture and BL could be the source of cheap and effective catalyst for coal gasification.展开更多
After three-stage pulverization, dry-distillated activation and coupling agent surface modification, the kaolinite-typed gangue of Sichuan Hongni Coal Mine（SHCM） can be manufactured into activated gangue＇s carbon b...After three-stage pulverization, dry-distillated activation and coupling agent surface modification, the kaolinite-typed gangue of Sichuan Hongni Coal Mine（SHCM） can be manufactured into activated gangue＇s carbon black. Its surface area is 〉25 m^2/g, and possesses carbon black＇s carbon framework and structure. It can be used as strengthening agent of high polymer material such as rubber.展开更多
The sustainable development of coal mining cities in Heilongjiang province has important effect on the economic stability and development of Heilongjiang, Northeast China, and China at large. To further the sustainabl...The sustainable development of coal mining cities in Heilongjiang province has important effect on the economic stability and development of Heilongjiang, Northeast China, and China at large. To further the sustainable development evaluation system of coal mining cities in Heilongjiang province, based on the analytic hierarchy process （AHP） method combined with operational and scientific principles using Saaty＇s 1-9 scale method to construct the judgment matrix from five aspects, such as economic development and environmental quality, this paper establishes the comprehensive evaluation index sys- tem of sustainable development of coal mining cities in Heilongjiang province, including comprehensive index of industrial economic benefits and the contribution rate of science and technology. In addition, using fuzzy comprehensive evaluation method, a comprehensive evaluation is made on the indices of the four major coal mining cities of Heilongjiang. The result shows that the coal mining cities are not bet- ter than Datong of Shanxi province in many indices. The economic development and environment quality are the most important indices of the targeted layer influencing the sustainable development of coal min- ing cities of HeilonKiiang, and their index weights are 0.4358 and 0.2844, respectively. These two indices including comprehensive index of industrial economic benefit and the ratio of environmental protection investment to GDP are the key elements influencing the two aspects.展开更多
The aim of this work was to study the effect of condensed tannins （CT） on the kinetic of gas production in vitro, on the three main species of Azorean pasture： Trifolium repens, Lotus corniculatus and Lolium perenn...The aim of this work was to study the effect of condensed tannins （CT） on the kinetic of gas production in vitro, on the three main species of Azorean pasture： Trifolium repens, Lotus corniculatus and Lolium perenne, using Quebracho extract as the source of CT, and also to calculate total tannins and condensed tannins on the species studied. Lotus corniculatus, Lolium perenne and Trifolium repens were tested in vitro with the inclusion of Quebracho extract in doses of 0%, 2.5% and 5% DM. The total content in tannins was determined in the 3 species. We have found, in comparison with standard tannic acid, that tannins exist in the flower of T. repens （0.81 equivalents of tannic acid） and in L .corniculatus （1.07 equivalents of tannic acid） but not in L .perenne （0 equivalents of tannic acid）. The concentration of condensed tannins in the 3 species was： 0.34 mg/mL for T. repens; 0.83 mg/mL for L. corniculatus and 0 mg/ml for L. perenne. We verified that a significant reduction （P 〈 0.05） of gas production happened for doses of 5% of CT in comparison with the other two concentrations： 0% and 2.5% of CT. The results of this study express a reduction of the fermentation rate, which implies a reduction of gas production, so, a reduction of methane emission to the atmosphere and an increase of exploitation of the protein by ruminants.展开更多
In this paper, changes in the amounts of organic carbon and black carbon in reclaimed soil were studied. The subsidence area was in a Xuzhou coal mining area that is part of a national land reclamation demonstration a...In this paper, changes in the amounts of organic carbon and black carbon in reclaimed soil were studied. The subsidence area was in a Xuzhou coal mining area that is part of a national land reclamation demonstration area. The significance of the paper is to explain the law of quality changes of reclaimed soil, improve the soil reclamation process and promote the sustainable use of soil in mining areas. In the study, four kinds of soils were collected using four land reclamation methods： coal gangue filling（CGF）, mixed flat reclamation（MFR）, mud pump filling（MPF） and fly ash filling（FAF）; soil from the subsided area（SS） was used as the control. Organic carbon and black carbon on content were determined by elemental analysis, potassium dichromate titration and other methods. The result shows that reclamation methods do have an influence on the organic carbon and black carbon content in subsidence soil. The content of organic carbon and black carbon at different soil depths varies the most in FAF. Regression analysis of black carbon and organic carbon contents from the four different reclamation methods show that the levels are significant in all cases. Therefore, there is no obvious relationship between the proportion of black carbon and the accumulation of organic carbon in the study area.展开更多
文摘本文根据Hansford(1946,1961)的分类系统和鉴定方法,采集鉴定和整理了福建省黑煤菌共4属43种;附丝壳属(Appendiculella)4种、小光壳炱属(Asteridiella)9种、隔孢炱属(Balladynastrum)1种以及小煤炱属(Meliola)29种,其中包括1个新种和13个在中国分布的新记录,新种是(?)木生小煤炱Meliola loropetalicola Y.X.Hu et Y.S.Ouyang,新种有中文、拉丁文描述和显微结构图。模式标本藏于广东省微生物研究所。
基金Project(51274255)supported by the National Natural Science Foundation of ChinaProject supported by the Foundation of State Key Laboratory of Comprehensive Utilization of Low-Grade Ores(Zijin Mining Group Co.,Ltd),China
文摘The hydrophobic flocculation of marmatite fines in aqueous suspensions induced by butyl xanthate （KBX） and ammonium dibutyl dithiophosphate （ADD） was investigated using laser particle size analysis, microscopy analysis, electrophoretic light scattering, contact angle measurement and infrared spectroscopy. The studies were performed on single minerals with size 〈20 μm by varying several parameters, including pH, collector concentration and kerosene addition. The results show that the floc fotation closely correlated with the size of flocs and the particle hydrophobicity, but was not lowered with increasing the particle surface charges due to collector adsorption. Under good operating conditions, the floc flotation of marmatite fines as a function of KBX and ADD can all reach floatability over 90%, in comparison with conventional flotation obtaining floatability of about 60%. It also has been found that a small addition of kerosene greatly improved the floc flotation because of the formation of oil films on marmatite particles. The results of FTIR spectra indicate that adsorption of the two collectors onto marmatite were chemical adsorption.
基金Supported by the National Natural Science Foundation of China （No.20376014） and Fujian Science and Technology Council Grant （HG99-01）.
文摘CO2 gasification of Fuijian high-metamorphous anthracite with black liquor （BL） and/or mixture of BL and calcium stuff （BL＋Ca） as catalyst was studied by using a thermogravimetry under 750-950℃ at ambient pressure. When the coal was impregnated with an appropriate quantity of Ca and BL mixture, the catalytic activity of CO2 gasification was enhanced obviously. With a loading of 8%Na-BL＋2%Ca, the carbon conversion of three coal samples tested reaches up to 92.9%-99.3% at 950℃ within 30min. The continuous formation of alkali surface compounds such as （[-COM], [-CO2M]） and the presence of exchanged Ca, such as calcium phenolate and calcium carboxylates （COO）2Ca, contribute to the increase in catalytic efficiency, and using BL＋Ca is more efficient than that adding BL only, The homogeneous model and shrinking-core model were applied to correlate the data of conversion with time and to estimate the reaction rate constants under different temperature. The corresponding reaction activation energy （Ea） and pre-exponential factor of three anthracites were estimated. It is found that Ea is in the range from 73.6 to 121.4kJ·mol^-1 in the case of BL＋Ca, and 74.3 to 104.2kJ·mol^-1 when only BL was used as the catalyst, both of which are much less than that from 143.5 to 181.4kJ·mol^-1 if no catalyst used. It is clearly demonstrated that both of BL＋Ca mixture and BL could be the source of cheap and effective catalyst for coal gasification.
文摘After three-stage pulverization, dry-distillated activation and coupling agent surface modification, the kaolinite-typed gangue of Sichuan Hongni Coal Mine（SHCM） can be manufactured into activated gangue＇s carbon black. Its surface area is 〉25 m^2/g, and possesses carbon black＇s carbon framework and structure. It can be used as strengthening agent of high polymer material such as rubber.
基金supported by the Philosophy and Social Science Program of Heilongjiang Province (No. 10D051)the Science and Technology Plan Program of Heilongjiang Province (No. GC10D209)the General Humanity and Social Science Program of Heilongjiang Provincial Universities in 2012 (HET-based energy sustainable development research of Heilongjiang province) (No. 12522258)
文摘The sustainable development of coal mining cities in Heilongjiang province has important effect on the economic stability and development of Heilongjiang, Northeast China, and China at large. To further the sustainable development evaluation system of coal mining cities in Heilongjiang province, based on the analytic hierarchy process （AHP） method combined with operational and scientific principles using Saaty＇s 1-9 scale method to construct the judgment matrix from five aspects, such as economic development and environmental quality, this paper establishes the comprehensive evaluation index sys- tem of sustainable development of coal mining cities in Heilongjiang province, including comprehensive index of industrial economic benefits and the contribution rate of science and technology. In addition, using fuzzy comprehensive evaluation method, a comprehensive evaluation is made on the indices of the four major coal mining cities of Heilongjiang. The result shows that the coal mining cities are not bet- ter than Datong of Shanxi province in many indices. The economic development and environment quality are the most important indices of the targeted layer influencing the sustainable development of coal min- ing cities of HeilonKiiang, and their index weights are 0.4358 and 0.2844, respectively. These two indices including comprehensive index of industrial economic benefit and the ratio of environmental protection investment to GDP are the key elements influencing the two aspects.
文摘The aim of this work was to study the effect of condensed tannins （CT） on the kinetic of gas production in vitro, on the three main species of Azorean pasture： Trifolium repens, Lotus corniculatus and Lolium perenne, using Quebracho extract as the source of CT, and also to calculate total tannins and condensed tannins on the species studied. Lotus corniculatus, Lolium perenne and Trifolium repens were tested in vitro with the inclusion of Quebracho extract in doses of 0%, 2.5% and 5% DM. The total content in tannins was determined in the 3 species. We have found, in comparison with standard tannic acid, that tannins exist in the flower of T. repens （0.81 equivalents of tannic acid） and in L .corniculatus （1.07 equivalents of tannic acid） but not in L .perenne （0 equivalents of tannic acid）. The concentration of condensed tannins in the 3 species was： 0.34 mg/mL for T. repens; 0.83 mg/mL for L. corniculatus and 0 mg/ml for L. perenne. We verified that a significant reduction （P 〈 0.05） of gas production happened for doses of 5% of CT in comparison with the other two concentrations： 0% and 2.5% of CT. The results of this study express a reduction of the fermentation rate, which implies a reduction of gas production, so, a reduction of methane emission to the atmosphere and an increase of exploitation of the protein by ruminants.
基金National Natural Science Foundation of China(41201186)
文摘In this paper, changes in the amounts of organic carbon and black carbon in reclaimed soil were studied. The subsidence area was in a Xuzhou coal mining area that is part of a national land reclamation demonstration area. The significance of the paper is to explain the law of quality changes of reclaimed soil, improve the soil reclamation process and promote the sustainable use of soil in mining areas. In the study, four kinds of soils were collected using four land reclamation methods： coal gangue filling（CGF）, mixed flat reclamation（MFR）, mud pump filling（MPF） and fly ash filling（FAF）; soil from the subsided area（SS） was used as the control. Organic carbon and black carbon on content were determined by elemental analysis, potassium dichromate titration and other methods. The result shows that reclamation methods do have an influence on the organic carbon and black carbon content in subsidence soil. The content of organic carbon and black carbon at different soil depths varies the most in FAF. Regression analysis of black carbon and organic carbon contents from the four different reclamation methods show that the levels are significant in all cases. Therefore, there is no obvious relationship between the proportion of black carbon and the accumulation of organic carbon in the study area.
