A novel high performance MgCl2/TiCl4 catalyst with tetrabutyloxsilicane as electron donor was pre-pared for ethylene slurry polymerization process. The properties of the catalyst such as particle size distribution, ca...A novel high performance MgCl2/TiCl4 catalyst with tetrabutyloxsilicane as electron donor was pre-pared for ethylene slurry polymerization process. The properties of the catalyst such as particle size distribution, catalytic activity, hydrogen responsibility and copolymerization performance were investigated and compared with commercial catalyst (imported catalyst). Copolymerization of ethylene and 1-butylene using the catalyst was stud-ied in a pilot plant. The composition, structure and property of the copolymer were characterized by 13C nuclear magnetic resonance (13C NMR) and gel permeation chromatography-Infrared (GPC-IR), and compared with those of the copolymer obtained from a commercial catalyst. In comparison with the commercial catalyst, the novel cata-lyst had a higher activity (up to 34.6 kg·g-1) and a better particle size distribution (PSD), and produced polymers having higher bulk density (up to 0.37 g·cm-3) with less fine resin. Meanwhile, the novel catalyst showed a higher hydrogen responsibility and better copolymerization performance. The results indicated that the copolymer obtained from the novel catalyst has a higher branch in the high molecular weight fraction and lower branch in the low mo-lecular weight fraction.展开更多
Novel MgCl2-supported Ziegler-Natta (Z-N) catalysts prepared using a new one-pot ball milling method can effectively control the amounts of Ti-loading in the catalysts. Complex GPC data on polypropylene synthesized by...Novel MgCl2-supported Ziegler-Natta (Z-N) catalysts prepared using a new one-pot ball milling method can effectively control the amounts of Ti-loading in the catalysts. Complex GPC data on polypropylene synthesized by these novel catalysts were analyzed using the method of fitting the molecular weight distribution (MWD) curves with a multiple Flory-Schulz function. It was found that multiple active centers exist in these novel catalysts. Detailed study of the effects of the Ti-loadings in the catalysts on the distribution of the active centers showed that the Ti-loadings in the novel MgCl2-supported Z-N catalysts might affect the proportion of each type of active centers; and might be the main factor responsible for the effect of the Ti-loadings on the microstructure, the molecular weight and molecular weight distribution width of the resultant polymer, the catalytic activity and polymerization kinetics.展开更多
We report a facile coagglomeration method for preparing graphene (G)/MgCl2‐supported Ti‐based Ziegler‐Natta catalysts. The effects of graphene feed ratio on catalyst morphology and ethylene polymerization behavior ...We report a facile coagglomeration method for preparing graphene (G)/MgCl2‐supported Ti‐based Ziegler‐Natta catalysts. The effects of graphene feed ratio on catalyst morphology and ethylene polymerization behavior were examined. The synthesized catalyst exhibited very high activity for ethylene polymerization. The resultant polyethylene (PE)/G nanocomposites showed a layered morphology, and the graphene fillers were well dispersed in the PE matrix. In addition, the thermal stability and mechanical properties of PE were significantly enhanced with the introduction of a very small amount of G fillers (0.05 wt%). This work provides a facile approach to the production o fhigh‐performance PE.展开更多
文摘A novel high performance MgCl2/TiCl4 catalyst with tetrabutyloxsilicane as electron donor was pre-pared for ethylene slurry polymerization process. The properties of the catalyst such as particle size distribution, catalytic activity, hydrogen responsibility and copolymerization performance were investigated and compared with commercial catalyst (imported catalyst). Copolymerization of ethylene and 1-butylene using the catalyst was stud-ied in a pilot plant. The composition, structure and property of the copolymer were characterized by 13C nuclear magnetic resonance (13C NMR) and gel permeation chromatography-Infrared (GPC-IR), and compared with those of the copolymer obtained from a commercial catalyst. In comparison with the commercial catalyst, the novel cata-lyst had a higher activity (up to 34.6 kg·g-1) and a better particle size distribution (PSD), and produced polymers having higher bulk density (up to 0.37 g·cm-3) with less fine resin. Meanwhile, the novel catalyst showed a higher hydrogen responsibility and better copolymerization performance. The results indicated that the copolymer obtained from the novel catalyst has a higher branch in the high molecular weight fraction and lower branch in the low mo-lecular weight fraction.
基金Project supported by the National Natural Science Foundation ofChina (No. 20172045) Science and Technology Plan Fund of Zhe-jiang Province (No. 001101116) and Foundation for Doctors ofNingbo City (No. 2003A62012) China
文摘Novel MgCl2-supported Ziegler-Natta (Z-N) catalysts prepared using a new one-pot ball milling method can effectively control the amounts of Ti-loading in the catalysts. Complex GPC data on polypropylene synthesized by these novel catalysts were analyzed using the method of fitting the molecular weight distribution (MWD) curves with a multiple Flory-Schulz function. It was found that multiple active centers exist in these novel catalysts. Detailed study of the effects of the Ti-loadings in the catalysts on the distribution of the active centers showed that the Ti-loadings in the novel MgCl2-supported Z-N catalysts might affect the proportion of each type of active centers; and might be the main factor responsible for the effect of the Ti-loadings on the microstructure, the molecular weight and molecular weight distribution width of the resultant polymer, the catalytic activity and polymerization kinetics.
基金supported by the National Research Foundation of Korea (NRF-2015R1D1A1A0161012)the National Natural Science Foundation of China (U1462124)~~
文摘We report a facile coagglomeration method for preparing graphene (G)/MgCl2‐supported Ti‐based Ziegler‐Natta catalysts. The effects of graphene feed ratio on catalyst morphology and ethylene polymerization behavior were examined. The synthesized catalyst exhibited very high activity for ethylene polymerization. The resultant polyethylene (PE)/G nanocomposites showed a layered morphology, and the graphene fillers were well dispersed in the PE matrix. In addition, the thermal stability and mechanical properties of PE were significantly enhanced with the introduction of a very small amount of G fillers (0.05 wt%). This work provides a facile approach to the production o fhigh‐performance PE.
