Review on the design of high-strength and hydrogen-embrittlement-resistant steels

Given the carbon peak and carbon neutrality era,there is an urgent need to develop high-strength steel with remarkable hydrogen embrittlement resistance.This is crucial in enhancing toughness and ensuring the utilization of hydrogen in emerging iron and steel materials.Simultaneously,the pursuit of enhanced metallic materials presents a cross-disciplinary scientific and engineering challenge.Developing high-strength,toughened steel with both enhanced strength and hydrogen embrittlement(HE)resistance holds significant theoretical and practical implications.This ensures secure hydrogen utilization and further carbon neutrality objectives within the iron and steel sector.Based on the design principles of high-strength steel HE resistance,this review provides a comprehensive overview of research on designing surface HE resistance and employing nanosized precipitates as intragranular hydrogen traps.It also proposes feasible recommendations and prospects for designing high-strength steel with enhanced HE resistance.

Atomistic study on the microscopic mechanism of grain boundary embrittlement induced by small dense helium bubbles in iron

The helium bubbles induced by 14 MeV neutron irradiation can cause intergranular fractures in reduced activation ferritic martensitic steel,which is a candidate structural material for fusion reactors.In order to elucidate the susceptibility of different grain boundaries(GBs)to helium-induced embrittlement,the tensile fracture processes of 10 types of GBs with and without helium bubbles in body-centered cubic(bcc)iron at the relevant service temperature of 600 K were investigated via molecular dynamics methods.The results indicate that in the absence of helium bubbles,the GBs studied here can be classified into two distinct categories:brittle GBs and ductile GBs.The atomic scale analysis shows that the plastic deformation of ductile GB at high temperatures originates from complex plastic deformation mechanisms,including the Bain/Burgers path phase transition and deformation twinning,in which the Bain path phase transition is the most dominant plastic deformation mechanism.However,the presence of helium bubbles severely inhibits the plastic deformation channels of the GBs,resulting in a significant decrease in elongation at fractures.For bubble-decorated GBs,the ultimate tensile strength increases with the increase in the misorientation angle.Interestingly,the coherent twin boundary∑3{112}was found to maintain relatively high fracture strength and maximum failure strain under the influence of helium bubbles.

Effects of Si on the stability of retained austenite and temper embrittlement of ultrahigh strength steels

Effects of silicon （Si） content on the stability of retained austenite and temper embrittlement of ultrahigh strength steels were investigated using X-ray diffraction （XRD）,transmission electron microscopy （TEM）,and other experimental methods.The results show that Si can suppress temper embrittlement,improve temper resistance,and hinder the decomposition of retained austenite.Reversed austenite appears gradually with the increase of Si content during tempering.Si has a significant effect on enhancing carbon （C） partitioning and improving the stability of retained austenite.Si and C atoms are mutually exclusive in lath bainite,while they attract each other in austenite.ε-carbides are found in 1.8wt% Si steel tempered at 250℃,and they get coarsened obviously when tempered at 400℃,leading to temper embrittlement.Not ε-carbides but acicular or lath carbides lead to temper embrittlement in 0.4wt% Si steel,which can be inferred as cementites and composite compounds.Temper embrittlement is closely related to the decomposition of retained austenite and the formation of reversed austenite.

Critical Time and Temper Embrittlement Isotherms

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KINETICS OF TEMPER EMBRITTLEMENT IN 2.25Cr-1Mo STEEL USED FOR HOT-WALL HYDROFINING REACTORS

Based on the theory of grain boundary segregation, a kinetics model of temper em-brittlement caused by long-term service for hot-wall hydrofining reactors was studied.The kinetics model was applied to phosphorus (P) segregation in 2.25Cr-1Mo steelused for a hot-wall hydrofining reactor, and the kinetics of grain boundary segrea-tion of impurity P in the steel exposed to the process environment of the hydrofiningreactor was calculated on the basis of the model. The Auger electron spectroscopytest was performed in order to determine the grain boundary concentration of P. Theexperimental result is agreement with the theoretical calculated data. The results showthat the kinetics equation is reasonable for predicting the levels of grain boundarysegregation of impurity P in 2.25Cr-1Mo steel used for hot-wall hydrofining reactors.

Study on temper embrittlement control technique in steel 12Cr1MoV

Failure may occur catastrophically by fracture along grain boundaries when temper embrittlement induced by non-equilibrium grain-boundary segregation (NGS) of phosphorus atoms. Temper embrittlement control technigue based on the theory of NGS and deformation induced phase transformation method was studied in this paper. Grain refinement technique by deformation induced phase transformation in low-alloy steel,12Cr1MoV( which is used in steam pipeline of ships),was experimentally investigated. A single-pass hot rolling process by using a Gleeble-1500 system was performed and the experimental results showed that the grain sizes were obviously affected by the deforming temperature,strain,strain rate and the quenching cooling rate. Temper embrittlement may be controlled and obviously improved by grain refinement.

TEMPERED BAINITE EMBRITTLEMENT IN SOME STRUCTURAL STEELS

The variations of microstructures and mechanical properties of steels 15CrMnMoV, 18Mn2CrMoB,18Cr2Ni4W,30CrMnSi,30CrMnSiNi2 and 40CrMnSiMoV,which were tempered at different temperatures after austempering and continuous cooling at given rates, have been investigated.Based on the experimental results,the behaviour and mechanism of tempered bainite embrittlement(TBE)have been discussed.Finally,the theoretical and prac- tical basis for selecting the optimum tempering temperature of steels with bainite structure af- ter heat treatment are proposed.

Hydrogen Embrittlement of Nitrogenating Layer on Martensitic Alloys

Nitriding of the surface in martensitic stainless steels is commonly carried out to improve their wear resistance. The process of plasma nitriding in stainless steel is influenced by two mechanisms: physical diffusion through the surface and chemical gas-metal reaction. The inner nitriding interaction involves the simultaneous penetration and formation of a solid solution, as well as the interaction of nitrogen with specific alloying elements, resulting in the development of homogeneous and heterogeneous structures. Our study concludes that the observed intergranular hydrogen embrittlement and crack formation during the surface nitridation process of AMS 5719 martensite alloy steel can be attributed to the ammonium concentration of approximately 50% at a temperature of 530˚C.

Electron Theory Study on the Room TemperatureEmbrittlement in Fe＿3Al and FeAl

Considering the intrinsic and environmental embrittlement(IE and EE).the room temperature embrittlement of Fe_3Al and FeAl is analysed by means of empirical electron theory of solids and molecules.It is found that both IE and EE exist in Fe_3Al and FeAl.The IE is determined by the characteristic of bond structure and electron distribution;and the EE results from the remarkable decrease of local metallicity and the formation of severe anisotropy bonds when the interstitial sites have been occupied by solute hydrogen.On the basis of analysis results,the effective methods are proposed to improve the ductilities in Fe_3Al and FeAl.

EMBRITTLEMENT OF A Cr-Mo LOW-ALLOY STEEL DUE TO LOW-TEMPERATURE NEUTRON IRRADIATION

Embrittlement of a Cr-Mo2.25CrlMo steel stemming from neutron irradiation at 270℃ is studied by virtue of small punch testing in conjunction with scanning electron microscopy. The ductile-brittle transition temperature determined by the small punch test is much lower than that determined by the standard Charpy test. There is some irradiation-induced embrittlement effect after the steel is irradiated for 46 days with a neutron dose rate of 1.05×10^18dpa/s （displacement per atom per second）.

Low Temperature Environmental Embrittlement in Ordered Intermetallics

A comprehensive review of low temperature environmental embrittlement in intermetallics is pres- ented. Moisture and hydrogen are shown to severely embrittle many intermetallics, including iron, nickel and titanium aluminides. The roles of composition, microstructure and external test variables are emphasized. Several methods to reduce or avoid embrittlement are described.

Environmental Embrittlement and Preferred Orientation of Cold-Rolled and Annealed Fe_3 (Al,Cr,Zr) Alloy at Ambient Temperature

The room temperature tensile properties of cold rolled and annealed Fe 3(Al,Cr,Zr) alloy are similar to those of warm rolled Fe 3Al alloys. The cold rolled Fe 3(Al,Cr,Zr) alloy is also susceptible to test environments. It has been shown that the ductility in various environments decreases in sequence of oxygen—oil—air—distilled water. The results of X ray diffraction analysis show that (211) preferred orientation of B 2 phase appears in cold rolled Fe 3(Al,Cr,Zr) alloy after recrystallization annealing.

Grouping tree species to estimate basal area increment in temperate multispecies forests in Durango,Mexico

Multispecies forests have received increased scientific attention,driven by the hypothesis that biodiversity improves ecological resilience.However,a greater species diversity presents challenges for forest management and research.Our study aims to develop basal area growth models for tree species cohorts.The analysis is based on a dataset of 423 permanent plots(2,500 m^(2))located in temperate forests in Durango,Mexico.First,we define tree species cohorts based on individual and neighborhood-based variables using a combination of principal component and cluster analyses.Then,we estimate the basal area increment of each cohort through the generalized additive model to describe the effect of tree size,competition,stand density and site quality.The principal component and cluster analyses assign a total of 37 tree species to eight cohorts that differed primarily with regard to the distribution of tree size and vertical position within the community.The generalized additive models provide satisfactory estimates of tree growth for the species cohorts,explaining between 19 and 53 percent of the total variation of basal area increment,and highlight the following results:i)most cohorts show a"rise-and-fall"effect of tree size on tree growth;ii)surprisingly,the competition index"basal area of larger trees"had showed a positive effect in four of the eight cohorts;iii)stand density had a negative effect on basal area increment,though the effect was minor in medium-and high-density stands,and iv)basal area growth was positively correlated with site quality except for an oak cohort.The developed species cohorts and growth models provide insight into their particular ecological features and growth patterns that may support the development of sustainable management strategies for temperate multispecies forests.

Secondary work embrittlement of cold-rolled 05CuPCrNi sheet at low temperature

Due to the rapid development of China＇ s rail transportation equipment manufacturing industry and related international distribution, important material suppliers such as Baoshan Iron ＆ Steel Co., Ltd. carries on investigating the stability of material under extremely cold conditions. In this study, mechanical properties and secondary work embrittlement of weathering steel 05CuPCrNi were tested at low temperature. Compared to the mechanical properties at room temperature, the yield and tensile strength increase slightly with decreasing temperature. However, the variation of elongation is not obvious. The experimental results also show that the secondary work embrittlement transition temperature of 05CuPCrNi is lower than - 60 ℃. These results provide the basis for the use of this train body material in extremely cold regions.

Instrumented oscillographic study on impact toughness of an axle steel DZ2 with different tempering temperatures

Compared with the conventional Charpy impact test method,the oscillographic impact test can help in the behavioral analysis of materials during the fracture process.In this study,the trade-off relationship between the strength and toughness of a DZ2 axle steel at various tempering temperatures and the cause of the improvement in impact toughness was evaluated.The tempering process dramatically influenced carbide precipitation behavior,which resulted in different aspect ratios of carbides.Impact toughness improved along with the rise in tempering temperature mainly due to the increase in energy required in impact crack propagation.The characteristics of the impact crack propagation process were studied through a comprehensive analysis of stress distribution,oscilloscopic impact statistics,fracture morphology,and carbide morphology.The poor impact toughness of low-tempering-temperature specimens was attributed to the increased number of stress concentration points caused by carbide morphology in the small plastic zone during the propagation process,which resulted in a mixed distribution of brittle and ductile fractures on the fracture surface.

EFFECT OF ALLOYING ELEMENTS ON SENSITIVITY TO ENVIRONMENTAL EMBRITTLEMENT OF L1_2 INTERMETALLICS

The effect of Zr doping in Ni 3Al and B doping in Co 3Ti intermetallics on the sensitivity to moisture induced environmental embrittlement and on the hydrogen diffusivity was investigated. The results show that both B in Co 3Ti and Zr in Ni 3Al do not reduce the hydrogen diffusivity along the grain boundaries, therefore can not suppress the moisture induced environmental embrittlement. The above mentioned behavior of Zr in Ni 3Al and B in Co 3Ti is attributed to the fact that Zr and B are not segregated on the grain boundaries.

EFFECT OF CHROMIUM AND BORON ON ENVIRONMENTAL EMBRITTLEMENT OF FORGED Fe_3Al

The effects of addition of chromium or boron on room temperature tensile properties,fracture behavior and susceptibility to test environments (air vs. vacuuwi of forged Fe3Al have been investigated. The results indicated that both chromium and boron result in increasing room temperuture ductility and fracture strength of the Fe3Al alloy whether tested in air or in vacuum. The susceptibility to test envimnment was described with the embrittlement index I: I=(δv-δA)/δv. The embrittlement indexes, for Fe-30Al, Fe-30Al-4Cr and Fe-30Al-0. 13B (at. %), are 24%, 37% and 29%,respectively. Scanning electron microscope examination of fracture surface revealed that the fracture mode of the three alloys remains unchanged, and all of them exhibited a transgranular cleavage fracture mode when tested in vacuum or air.

Hydrogen embrittlement of X80 pipeline steel in H2S environment: Effect of hydrogen charging time, hydrogen-trapped state and hydrogen charging–releasing–recharging cycles

This study investigated the susceptibility of X80 pipeline steel to hydrogen embrittlement given different hydrogen pre-charging times and hydrogen charging–releasing–recharging cycles in H2S environment.The fracture strain of the steel samples decreased with increasing hydrogen pre-charging time;this steel degradation could almost be recovered after diffusible hydrogen was removed when the hydrogen pre-charging time was<8 d.However,unrecoverable degeneration occurred when the hydrogen pre-charging time extended to 16–30 d.Moreover,nanovoid formation meant that the hydrogen damage to the steel under intermittent hydrogen pre-charging–releasing–recharging conditions was more serious than that under continuous hydrogen pre-charging conditions.This study illustrated that the mechanical degradation of steel is inevitable in an H2S environment even if diffusible hydrogen is removed or visible hydrogen-induced cracking is neglected.Furthermore,the steel samples showed premature fractures and exhibited a hydrogen fatigue effect because the repeated entry and release of diffusible hydrogen promoted the formation of vacancies that aggregated into nanovoids.Our results provide valuable information on the mechanical degradation of steel in an H2S environment,regarding the change rules of steel mechanical properties under different hydrogen pre-charging times and hydrogen charging–releasing–recharging cycles.

First-principles Study on the Ductility Effect of Zirconium and Its Distinct Behavior from Boron to Restrain Hydrogen-induced Embrittlement in Ni-Ni3Al Alloys

By studying a cluster model containing Ni region （phase）, NiaAI region （phase） and Ni/Ni3Al region （interface） with a first-principles method, the occupation behavior and the ductility effect of zirconium in a Ni-Ni3Al system were investigated. It is found that zirconium has a stronger segregation tendency to Ni region than to Ni3Al region. The bond order analyses based on Rice-Wang model and the maximum theoretical shear stress model, however, show that zirconium has different degrees of ductility effect in these three regions, which originates from its different ability to increase the Griffith work of interracial cleavage 2γint and to decrease the maximum theoretical shear stress τmax. In addition, it is revealed in this paper that the distinct behavior of zirconium from boron to restrain hydrogen-induced embrittlement can be attributed to their different influences on the crystalline and electronic structures in Ni-Ni3Al alloys.

ELECTRONIC STATES AND HYDROGEN EMBRITTLEMENTIN TRANSITION METALS

An electronic approach to the mechanism of hydrogen embrittlement in metals is pre-sented and discussed. Some problems of the mechanism of hydrogen embrittlement are pointed out from an electronic point of view. Electronic structure calculations in a periodically cleaved or slipped lattice are developed in orker to identofy deformation-sensitive electronic states in the absence of hydrogen. The calculational results are given and discussed for a trunsition metal, Pd. Electronic structure calculations in the presence of hydrogen are outlined and hydrogen embrittlement in transition metals is discussed in terms of electronic states.