模型水轮机初生空化的特征谱提取识别方法

目前水轮机模型初生空化识别方法仍采用人工识别法,这种方法获得结果的周期较长、主观性强、准确度及效率都较低。针对于此,对水轮机模型初生空化识别方法进行了研究与优化创新,提出了一种基于炮声谱与特殊脉动谱特征提取的水轮机空化智能识别方法,即多态泡音智能识别方法 PSVFR。该方法依据自主开发的水轮机空化噪声多态算法MTCSPC,对数据进行处理,通过采集初生空化音态特征向量,建立矩阵模型,与样本数据库中的定性矩阵进行特征比对、计算、判断,以帮助机器完成对模型水轮机空化噪声的学习和识别。与现有技术相比,该方法能够提高机器对水轮机初生空化现象的识别准确度和识别效率,识别效率可达80%。

《空同集》明刊本与文渊阁《四库全书》本之差异

收入文渊阁《四库全书》中的《空同集》66卷,是明代著名作家李梦阳的别集,其所依据的底本是明万历三十年至三十一年邓云霄、潘之恒校刻本,此本甚佳,但因"违碍"原因,馆臣对其中文字如"胡""虏""夷""狄"等字句有所改篡。通过校勘考查,发现《四库全书》本中有改字、改句、删字句、增诗句4种情况,且改动之处较多。不过,该本中也有保留而不改的情形。不仅如此,四库馆臣还利用明刊善本对底本进行了认真校勘。因此在利用《四库全书》时不仅要谨慎对待其中所改文字,还要正确、客观地看待《四库全书》本身所具有的文献价值。

Vacancy engineering mediated hollow structured ZnO/ZnS S-scheme heterojunction for highly efficient photocatalytic H_(2) production

Designing a step-scheme(S-scheme)heterojunction photocatalyst with vacancy engineering is a reliable approach to achieve highly efficient photocatalytic H_(2)production activity.Herein,a hollow ZnO/ZnS S-scheme heterojunction with O and Zn vacancies(VO,Zn-ZnO/ZnS)is rationally constructed via ion-exchange and calcination treatments.In such a photocatalytic system,the hollow structure combined with the introduction of dual vacancies endows the adequate light absorption.Moreover,the O and Zn vacancies serve as the trapping sites for photo-induced electrons and holes,respectively,which are beneficial for promoting the photo-induced carrier separation.Meanwhile,the S-scheme charge transfer mechanism can not only improve the separation and transfer efficiencies of photo-induced carrier but also retain the strong redox capacity.As expected,the optimized VO,Zn-ZnO/ZnS heterojunction exhibits a superior photocatalytic H_(2) production rate of 160.91 mmol g^(-1)h^(-1),approximately 643.6 times and 214.5 times with respect to that obtained on pure ZnO and ZnS,respectively.Simultaneously,the experimental results and density functional theory calculations disclose that the photo-induced carrier transfer pathway follows the S-scheme heterojunction mechanism and the introduction of O and Zn vacancies reduces the surface reaction barrier.This work provides an innovative strategy of vacancy engineering in S-scheme heterojunction for solar-to-fuel energy conversion.

先秦两汉空间观与权力的空间化——从“空”、“宇”、“天”的语义演变到“天下”观念的构建

考察"空"、"宇"、"天"等与传统中国空间观念密切相关的汉字在先秦时期的造字本义和语义演变以及先秦两汉关于"天"及"天下"的观念建构,可以发现,先秦两汉空间观的发生与发展经历了一个从具象实践到抽象理论再到权力表征的发展转换过程。在这一过程中,秩序逐渐被纳入空间认知中,空间秩序、空间关系逐渐成为权力的表征,尤其自秦汉始,权力的空间化不仅体现为帝制中国的疆域扩张,亦表现为日常生活实践中的空间秩序,并深刻影响了艺术创作尤其是传统文学、绘画艺术的基本内容、表现方式乃至审美批评。

架空输电线路应用摄影测量技术分析

随着摄影测量技术的成熟和发展,在架空输电线路工程中的应用摄影测量技术得到广泛重视。本文对摄影测量在架空输电线路中的应用现状进行分析和总结,并对其发展趋势提出一点看法。

Hollow tubes constructed by carbon nanotubes self-assembly for CO_(2) capture

Carbon nanotubes(CNTs)have garnered significant attention in the fields of science,engineering,and medicine due to their numerous advantages.The initial step towards harnessing the potential of CNTs involves their macroscopic assembly.The present study employed a gentle and direct self-assembly technique,wherein controlled growth of CNT sheaths occurred on the metal wire’s surface,followed by etching of the remaining metal to obtain the hollow tubes composed of CNTs.By controlling the growth time and temperature,it is possible to alter the thickness of the CNTs sheath.After immersing in a solution containing 1 g/L of CNTs at 60℃ for 24 h,the resulting CNTs layer achieved a thickness of up to 60μm.These hollow CNTs tubes with varying inner diameters were prepared through surface reinforcement using polymers and sacrificing metal wires,thereby exhibiting exceptional attributes such as robustness,flexibility,air tightness,and high adsorption capacity that effectively capture CO_(2) from the gas mixture.

《论语》“屡空”新考

《论语》中的"屡空"的"屡"不能解释为"每、数",而当解释为"贫",与"窭、娄"同源。"空"当训诂为"穷"。"屡空"的意思是生活极度贫穷,难以遵守正常的礼节。

Co_(3)O_(4)/TiO_(2) composite photocatalyst:Preparation and synergistic degradation performance of toluene

TiO_(2) nanobelts and Co_(3)O_(4)/TiO_(2) catalytic materials were prepared using the hydrothermal method.The cat-alyst was characterized by X-ray diffraction,scanning electron microscopy,transmission electron microscopy,X-ray electron spectroscopy,and fluorescence spectroscopy.At room temperature,with a relative humidity of 50.0%,the total gas flow rate of 1.0 L·min-1,the space velocity of 1.05×10^(4) h^(-1),and toluene volume concentration of 25.0µL·L^(-1),two 6 W vacuum ultraviolet lamps were used as light sources to catalyze,degrade,and mineralize toluene.The results show that the prepared catalyst is in the shape of nano-ribbons.The loading of Co_(3)O_(4) inhibits the recombina-tion of photogenerated electrons and holes and can effectively improve the catalytic performance.The Co_(3)O_(4)/TiO_(2) with a load of 6.0%Co_(3)O_(4) has the best catalytic effect.When N2 was used as a carrier gas,the degradation rate of tol-uene was only 34.7%.The toluene degradation is mainly due to the photolysis of vacuum ultraviolet light.When air was used as a carrier gas,O_(3) was produced.The Co_(3)O_(4)/TiO_(2) with a load of 6.0%and vacuum ultraviolet synergistical-ly promote toluene degradation.The highest degradation rate of toluene was 91.7%and the mineralization rate was 74.6%.The degradation rate of toluene was 2.6 times that of nitrogen as a carrier gas.

Experimental and numerical investigations on acoustic damping of monoclinic crystalline wideband sound absorbing structures

In order to overcome the limitations of traditional microperforated plate with narrow sound absorption bandwidth and a single structure,two multi-cavity composite sound-absorbing materials were designed based on the shape of monoclinic crystals:uniaxial oblique structure(UOS)and biaxial oblique structure(BOS).Through finite element simulation and experimental research,the theoretical models of UOS and BOS were verified,and their sound absorption mechanisms were revealed.At the same time,the influence of multi-cavity composites on sound absorption performance was analyzed based on the theoretical model,and the influence of structural parameters on sound absorption performance was discussed.The research results show that,in the range of 100-2000 Hz,UOS has three sound absorption peaks and BOS has five sound absorption peaks.The frequency range of the half-absorption bandwidth(α>0.5)of UOS and BOS increases by 242% and 229%,respectively.Compared with traditional microperforated sound-absorbing structures,the series and parallel hybrid methods significantly increase the sound-absorbing bandwidth of the sound-absorbing structure.This research has guiding significance for noise control and has broad application prospects in the fields of transportation,construction,and mechanical design.

Highly selective electrosynthesis of imines via electroreduction coupling of nitroarenes with aryl aldehydes on Co_(9)S_(8)with positively charged sulfur vacancies

The electrocatalytic synthesis of imines through the reductive imination of nitroarenes with aldehydes is a facile,environmentally friendly,and valuable process.In this study,high selectivity electrosynthesis of imines was realized through the electrocatalytic C-N coupling reaction between nitroarenes and aryl aldehydes on Co_(9)S_(8)nanoflowers with rich sulfur vacancies(Co_(9)S_(8)-Vs).Comparative experiments revealed that positively charged sulfur vacancies play a pivotal role in boosting catalytic selectivity towards imines.Electron-deficient sulfur vacancies intensified the adsorption of negatively charged Ph-NO_(2),thereby enhancing the conversion rate of the electrochemical nitrobenzene-reduction reaction(eNB-RR).Simultaneously,sulfur vacancies augmented the adsorption capability of negatively charged Ph-CHO,enriching Ph-CHO species at the electrode interface and expediting the Schiff base condensation reaction rate.The experimental results show that the reaction conditions can satisfy the different nitroarenes and aryl aldehydes in the electrocatalytic aqueous-phase system under mild conditions to obtain the corresponding imine products in high selectivity.This study provides a facile and environmentally friendly pathway for future electrocatalytic synthesis of imine.

Heat and mass transfer of a circular porous moist object located in a triangular shaped vented cavity

Heat and mass transfer of a circular-shaped porous moist object inside a two-dimensional triangle cavity is investigated by using finite element method.The porous object is considered to be a moist food sample,located in the middle of the cavity with inlet and outlet ports with different configurations of inlet/outlet ports.Convective drying performance is numerically assessed for different values of Reynolds numbers(between 50 and 250),dry air inlet temperature(between 40 and 80℃)and different locations of the port.It is observed that changing the port locations has significant impacts on the flow recirculaitons inside the triangular chamber while convective drying performance is highly affected.The moisture content reduces with longer time and for higher Reynolds number(Re)values.Case P4 where inlet and outlet ports are in the middle of the walls provides the most effective configuration in terms of convective drying performance while the worst case is seen for P1 case where inlet and outlet are closer to the corners of the chamber.There is a 192% difference between the moisture reduction of these two cases at Re=250,T=80℃ and t=120 min.

Seismic identification and characterization of complex storage space oil and gas reservoirs

To predict complex reservoir spaces(with developed caves,pores,and fractures),based on the results of full-azimuth depth migration processing,we adopted reverse weighted nonlinear inversion to improve the accuracy of porous reservoir prediction.Scattering imaging three-parameter wavelet transform technology was used to accurately predict small-scale cave bodies.The joint inversion method of velocity and amplitude anisotropy was developed to improve the accuracy of small and medium-sized fracture prediction.The results of multiscale fracture modeling and characterization,interwell connectivity analysis,and connection path prediction are consistent with the production condition.Finally,based on the above prediction findings,favorable reservoir development areas were predicted.The above ideas and strategies have great application value for the efficient exploration and development of complex storage space reservoirs and the optimization of high-yield well locations.

Boosting CO_(2) photoreduction by synergistic optimization of multiple processes through metal vacancy engineering

The photoreduction of greenhouse gas CO_(2) using photocatalytic technologies not only benefits en-vironmental remediation but also facilitates the production of raw materials for chemicals.Howev-er,the efficiency of CO_(2) photoreduction remains generally low due to the challenging activation of CO_(2) and the limited light absorption and separation of charge.Defect engineering of catalysts rep-resents a pivotal strategy to enhance the photocatalytic activity for CO_(2),with most research on met-al oxide catalysts focusing on the creation of anionic vacancies.The exploration of metal vacancies and their effects,however,is still underexplored.In this study,we prepared an In2O3 catalyst with indium vacancies(VIn)through defect engineering for CO_(2) photoreduction.Experimental and theo-retical calculations results demonstrate that VIn not only facilitate light absorption and charge sepa-ration in the catalyst but also enhance CO_(2) adsorption and reduce the energy barrier for the for-mation of the key intermediate*COOH during CO_(2) reduction.Through metal vacancy engineering,the activity of the catalyst was 7.4 times,reaching an outstanding rate of 841.32μmol g(-1)h^(-1).This work unveils the mechanism of metal vacancies in CO_(2) photoreduction and provides theoretical guidance for the development of novel CO_(2) photoreduction catalysts.

Ablation behaviour and mechanical performance of ZrB_(2)-ZrC-SiC modified carbon/carbon composites prepared by vacuum infiltration combined with reactive melt infiltration

The development of advanced aircraft relies on high performance thermal-structural materials,and carbon/carbon com-posites(C/C)composited with ultrahigh-temperature ceramics are ideal candidates.However,the traditional routes of compositing are either inefficient and expensive or lead to a non-uniform distribution of ceramics in the matrix.Compared with the traditional C/C-ZrC-SiC composites prepared by the reactive melt infiltration of ZrSi_(2),C/C-ZrB_(2)-ZrC-SiC composites prepared by the vacuum infiltration of ZrB_(2) combined with reactive melt infiltration have the higher content and more uniform distribution of the introduced ceramic phases.The mass and linear ablation rates of the C/C-ZrB_(2)-ZrC-SiC composites were respectively 68.9%and 29.7%lower than those of C/C-ZrC-SiC composites prepared by reactive melt infiltration.The ablation performance was improved because the volatilization of B_(2)O_(3),removes some of the heat,and the more uniformly distributed ZrO_(2),that helps produce a ZrO2-SiO2 continu-ous protective layer,hinders oxygen infiltration and decreases ablation.

论广东山区地名用字“崆”——从广东最高峰“石坑崆”说起

“崆”类地名常见于粤北和粤东山区,如广东最高峰“石坑崆”。作为地名的“崆”在各地也写作“埪”“硿”,都属于方言用字。其本字为“空”,在客家方言中用以表示山间凹陷、坑谷,后来也转指山岳名称。此类地名主要分布于广东客家地区,可视为客家方言特征词。

浅谈图书馆管理服务空间的变化

进入到21世纪以来,数字化革命更深入到社会各个方面,图书馆也应由自动化管理向数字化的空间拓展,以最终为读者服务为综旨的图书馆,将会面向自身的深刻的空间拓展:从数字化、典藏、管理和服务方式的巨大变化。分析图书馆在信息服务空间中的功能和定位、开展创新型服务的方式方法,并提出图书馆工作创新的建议。

Evaluation of development potential of pumped hydroelectric storage and geothermal utilization system in abandoned coal mine

Every year in China,a significant number of mines are closed or abandoned.The pumped hydroelectric storage(PHS)and geothermal utilization are vital means to efficiently repurpose resources in abandoned mine.In this work,the development potentials of the PHS and geothermal utilization systems were evaluated.Considering the geological conditions and meteorological data available of Jiahe abandoned mine,a simple evaluation model for PHS and geothermal utilization was established.The average efficiency of the PHS system exceeds 70%and the regulatable energy of a unit volume is over 1.53 kW·h/m^(3).The PHS system achieves optimal performance when the wind/solar power ratio reaches 0.6 and 0.3 in daily and year scale,respectively.In the geothermal utilization system,the outlet temperature and heat production are significantly affected by the injection flow rate.The heat production performance is more stable at lower rate flow,and the proportion of heat production is higher in the initial stage at greater flow rate.As the operating time increases,the proportion of heat production gradually decreases.The cyclic heat storage status has obvious advantages in heat generation and cooling.Furthermore,the energy-saving and emission reduction benefits of PHS and geothermal utilization systems were calculated.

Sensitivity Analysis of Injection Characteristic to Structural Parameters of GDI Injector Nozzle Hole

The nozzle inner-flow characteristic of the“spray G”injector was studied by the computational fluid dynamics(CFD)simulation,and the sensitivity of cycle fuel mass to the conicity and entrance radius of the nozzle hole were analyzed.Results show that the inner conicity of nozzle hole inhibits the development of cavitation phenomena,and increases the injection rate.While the outer conicity of nozzle hole promotes the diffusion of cavita-tion,leading to reductions of the liquid volume fraction of the nozzle outlet and the local flow resistance of the nozzle hole.The sensitivity of cycle fuel mass to inner-cone nozzle hole is stronger than that of the outer-cone noz-zle,especially at the smaller hole conicity.The increase of injection pressure enhances the sensitivity of the injection characteristics to the nozzle hole structure,in which inner-cone nozzle has higher sensitivity coefficient than the outer-cone nozzle hole.However,the increase of injection pressure aggravates the offset of liquid jet to the nozzle axis of the outer-cone nozzle hole.With the increase of the inner conicity of nozzle,the sensitivity of the injection characteristics to the entrance radius of the hole decreases.With the increase of the outer conicity of nozzle hole,the sensitivity of the injection characteristics to the entrance radius of the hole increases.

The Late Miocene‘ovibovin’bovids in Eurasia

During the Late Miocene,numerous medium to large-sized herbivores,that resemble the living Ovibos in skeletal morphology,dispersed throughout the Holarctic realm and comprised eleven genera:Lantiantragus,Shaanxispira,Tsaidamotherium,Criotherium,Mesembriacerus,Hezhengia,Urmiatherium,Parurmiatherium,Plesiaddax,Sinotragus,and Prosinotragus.These genera are primarily found in eastern Asia,in which nine genera are found in northern China,as well as in countries in eastern Europe and western Asia.They are distinguished by unique characteristics,including a perpendicular braincase,specialized horn cores,and a robust basioccipital.Previous studies have often classified these‘ovibovin’bovids as part of the conventional subfamily/tribe Ovibovinae/Ovibovini,along with extant Ovibos.Nevertheless,an increasing number of studies do not support the monophyly of the subfamily/tribe Ovibovinae/Ovibovini,nor is a close relationship likely between these Late Miocene‘ovibovin’bovids and extant Ovibos.Among the eleven genera of‘ovibovin’bovids,Plesiaddax,Hezhengia,and Urmiatherium are often considered to have a very close relationship and conventionally form the tribe Urmiatheriini.However,previous phylogenetic analyses do not support the monophyly of Urmiatheriini.This paper presents a summary of the transmutation of the terms Ovibovidae/Ovibovinae/Ovibovini/Ovibovina,the temporal and spatial distribution of the Late Miocene‘ovibovin’bovids in Eurasia,the principal characteristics of these taxa,and the previous phylogenetic analyses.

Research and development on mechanism of removal of indoor volatile organic compounds by plants

Background,aim,and scope Owing to the rapid development of modernisation and urbanisation,living standards have gradually improved.However,the widespread use of high-energy-consuming indoor appliances and furniture has made indoor environments a primary environmental problem affecting human health.Sick building syndrome(SBS)and building-related illness(BRI)have occurred,and indoor air conditions have been extensively studied.Common indoor pollutants include CO,CO_(2),volatile organic compounds(VOCs)(such as the formaldehyde and benzene series),NOx(NO and NO_(2)),and polycyclic aromatic hydrocarbons(PAHs).VOCs have replaced SO_(2)as the“The Fourteenth Five-Year Plan”urban air quality assessment new indicators.Indoor VOCs can cause diseases such as cataract,asthma,and lung cancer.To protect human health,researchers have proposed several indoor air purification technologies,including adsorption,filtration,electrostatic dust removal,ozonation,and plant purification.However,each technology has drawbacks,such as high operating costs,high energy consumption,and the generation of secondary waste or toxic substances.Plant degradation of VOCs as a bioremediation technology has the characteristics of low cost,high efficiency,and sustainability,thereby becoming a potential green solution for improving indoor air quality.This study introduces the research status and mechanism of plant removal of indoor VOCs and provides an experimental basis and scientific guidance for analysing the mechanism of plant degradation of pollutants.Materials and methods This study reviews studies on the harm caused by indoor pollutants to human health and related sources,mainly investigating the degradation of indoor formaldehyde,BTEX(benzene,toluene,ethylbenzene,and xylene)plant mechanisms,and research results.Results Plants can remove VOCs via stomatal and non-stomatal adsorption,interfoliar microbial,rhizosphere microbial,and growth media.Benzene,toluene,and xylene(BTX)are adsorbed by pores,hydroxylated into fumaric acid,and then removed into CO_(2) and H_(2)O by TCA.Formaldehyde enters plant leaves through the stomata and epidermal waxy substances and is adsorbed.After the two steps of enzymatic oxidation,formic acid and CO_(2) are generated.Finally,it enters the Calvin cycle and removes glucose and other nontoxic compounds.Discussion The non-stomatal degradation of VOCs can be divided into adsorption by cuticular wax and active adsorption by plant surface microorganisms.The leaf epidermal waxy matter content and the lipid composition of the epidermal membrane covering the plant surface play important roles in the non-stomatal adsorption of indoor air pollutants.The leaf margin of a plant is an ecological environment containing various microbial communities.The endophytic and inoculated microbiota in plant buds and leaves can remove VOCs(formaldehyde and BTEX).Formaldehyde can be directly absorbed by plant leaves and converted into organic acids,sugars,CO_(2) and H_(2)O by microbes.Bioremediation of indoor VOCs is usually inefficient,leading to plant toxicity or residual chemical substance volatilisation through leaves,followed by secondary pollution.Therefore,plants must be inoculated with microorganisms to improve the efficiency of plant degradation of VOCs.However,the effectiveness of interfoliar microbial removal remains largely unknown and several microorganisms are not culturable.Therefore,methods for collecting,identifying,and culturing microorganisms must be developed.As the leaf space is a relatively unstable environment,the degradation of VOCs by rhizosphere microorganisms is equally important,and formaldehyde is absorbed more by rhizosphere microorganisms at night.The inoculation of bacteria into the rhizosphere improves the efficiency of plants in degrading VOCs.However,most of these studies were conducted in simulation chambers.To ensure the authenticity of these conclusions,the ability of plants to remove indoor air pollutants must be further verified in real situations.Conclusions Plant purification is an economical,environment-friendly,and sustainable remediation technology.This review summarises the mechanisms of VOC plant degradation and presents its limitations.Simultaneously,it briefly puts forward a plant selection scheme according to different temperatures,light,and specific VOCs that can be absorbed to choose the appropriate plant species.However,some studies have denied the purification effect of plants and proposed that numerous plants are required to achieve indoor ventilation effects.Therefore,determining the ability of plants to remove indoor VOCs requires a combination of realistic and simulated scenarios.Recommendations and perspectives Plants and related microorganisms play an important role in improving indoor air quality,therefore,the effect of plants and the related microorganisms on improving indoor air quality must be studied further and the effect of plants on indoor VOCs will be the focus of future research.