Electrocatalytic hydrogen production from seawater holds enormous promise for clean energy generation.Nevertheless,the direct electrolysis of seawater encounters significant challenges due to poor anodic stability cau...Electrocatalytic hydrogen production from seawater holds enormous promise for clean energy generation.Nevertheless,the direct electrolysis of seawater encounters significant challenges due to poor anodic stability caused by detrimental chlorine chemistry.Herein,we present our recent discovery that the incorporation of Ce into Ni Fe layered double hydroxide nanosheet array on Ni foam(Ce-Ni Fe LDH/NF)emerges as a robust electrocatalyst for seawater oxidation.During the seawater oxidation process,CeO_(2)is generated,effectively repelling Cl^(-)and inhibiting the formation of Cl O-,resulting in a notable enhancement in the oxidation activity and stability of alkaline seawater.The prepared Ce-Ni Fe LDH/NF requires only overpotential of 390 m V to achieve the current density of 1 A cm^(-2),while maintaining long-term stability for 500 h,outperforming the performance of Ni Fe LDH/NF(430 m V,150 h)by a significant margin.This study highlights the effectiveness of a Ce-doping strategy in augmenting the activity and stability of materials based on Ni Fe LDH in seawater electrolysis for oxygen evolution.展开更多
The double perovskite oxides Sr2Mg1-xF exMoO6-δ were investigated as catalysts for the methane oxidation.The structural properties of catalysts were characterized in detail by X-ray diffraction,X-ray photoelectron sp...The double perovskite oxides Sr2Mg1-xF exMoO6-δ were investigated as catalysts for the methane oxidation.The structural properties of catalysts were characterized in detail by X-ray diffraction,X-ray photoelectron spectroscopy and X-ray absorption spectroscopy.The catalytic property was strongly influenced by the Fe substitution.The relation between catalytic performance and the degree of Fe substitution was examined with regard to the structure and surface characteristics of the mixed oxides.The Fe-containing catalysts exhibited higher activity attributable to the possible（Fe2＋,Mo6＋） and （Fe3＋,Mo5＋）valency pairs,and the highest activity was observed for Sr2Mg0.2Fe0.8MoO6-δ.The enhancement of the catalytic activity may be correlated with the Fe-relating surface lattice oxygen species and was discussed in view of the presence of oxygen vacancies.展开更多
The aim of this paper is to investigate the effect of nitrite intercalated Mg-Al layered double hydroxides(Mg-Al LDH-NO_(2))on mortar durability under the coexisting environment of Cl−and SO_(4)^(2-).Cl−and SO_(4)^(2-...The aim of this paper is to investigate the effect of nitrite intercalated Mg-Al layered double hydroxides(Mg-Al LDH-NO_(2))on mortar durability under the coexisting environment of Cl−and SO_(4)^(2-).Cl−and SO_(4)^(2-) binding properties of Mg-Al LDH-NO_(2) in simulated concrete pore solutions,Cl−and SO_(4)^(2-) diffusion properties of mortars with Mg-Al LDHNO 2 were examined.The steel corrosion and resistance of mortar against SO_(4)^(2-) attack were also evaluated.The results indicate that Mg-Al LDH-NO_(2) can effectively adsorb the Cl−and SO_(4)^(2-) in simulated concrete pore solution,and inhibit the diffusion of Cl−and SO_(4)^(2-) into cement mortars.The presence of SO_(4)^(2-) can greatly affect the uptake amount of Cl−,and there is a coupled effect of Cl−and SO_(4)^(2-) on their penetration into mortar specimens.In addition,Mg-Al LDH-NO_(2) can greatly upgrade the resistance of mortars against SO_(4)^(2-) attack and well prevent the steel from corrosion.However,Cl−will aggravate the SO_(4)^(2-) attack and SO_(4)^(2-) can initially decrease and then increase the steel corrosion.展开更多
With the continuous development of China's social economy,it has correspondingly promoted the development of the railway engineering experimental career,and has made tremendous progress in the cultivation of railw...With the continuous development of China's social economy,it has correspondingly promoted the development of the railway engineering experimental career,and has made tremendous progress in the cultivation of railway engineering experimental talents.At the same time,there are still many problems in the development of rail transit in the construction of"double first-class".Only by solving the existing problems can we further promote the smooth development of the training of railway engineering experimental talents.Therefore,the article mainly analyzes the problems and countermeasures of railway engineering experimental training,combined with the status and role of laboratories in the training of talents under the background of"double first-class",according to the society's demand for first-class engineering talents,we reformed and explored laboratory resource integration and optimization.展开更多
Mg-Al layered double hydroxide intercalated with CO_(3)^(2-)(CO_(3)·Mg-Al LDH) is effective for treating HCl exhaust gas.HCl reacts with CO_(3)^(2-) in CO_(3)·Mg-Al LDH, resulting in the formation of Cl·...Mg-Al layered double hydroxide intercalated with CO_(3)^(2-)(CO_(3)·Mg-Al LDH) is effective for treating HCl exhaust gas.HCl reacts with CO_(3)^(2-) in CO_(3)·Mg-Al LDH, resulting in the formation of Cl·Mg-Al LDH.We propose that CO_(2) can be used for the desorption of Cl^(-)from Cl·Mg-Al LDH to regenerate CO_(3)·Mg-Al LDH.Herein,we studied the desorption of a from CI-Mg-Al LDH by adding water to Cl·Mg-Al LDH and blowing CO_(2) into it.We also analyzed the effects of temperature and water addition speed on the desorption of CI^(-)from Cl·Mg-Al LDH.Our results show that the added water adhered to CI·Mg-Al LDH and that CO_(2) in the gaseous phase was dissolved in this adhered water,thus generating CO_(3)^(2-).Therefore,anion exchange occurred between CO_(3)^(2-) and Cl^(-)in the Cl·Mg-Al LDH,thus desorbing Cl^(-).展开更多
Rationally manipulating surface reconstruction of catalysts for water oxidation,inducing formation and dynamic accumulation of catalytically active centers still face numerous challenges.Herein,the introduction of[Cr(...Rationally manipulating surface reconstruction of catalysts for water oxidation,inducing formation and dynamic accumulation of catalytically active centers still face numerous challenges.Herein,the introduction of[Cr(C_(2)O_(4))_(3)]^(3-)into NiFe LDHs by intercalation engineering to promote surface reconstruction achieves an advanced oxygen evolution reaction(OER)activity.In view of the weak electronegativity of Cr^(3+) in[Cr(C_(2)O_(4))_(3)]^(3-),the intercalation of[Cr(C_(2)O_(4))_(3)]^(3-)is expected to result in an electron-rich structure of Fe sites in NiFe LDHs,and higher valence state of Ni can be formed with the charge transfer between Fe and Ni.The optimized electronic structure of NiFe-[Cr(C_(2)O_(4))_(3)]^(3-)-LDHs with more active Ni^(3+) species and the expedited dynamic generation of Ni^(3+) (Fe)OOH phase during the OER process contributed to its excellent catalytic property,revealed by in situ X-ray absorption spectroscopy,Raman spectroscopy,and quasi-in situ X-ray photoelectron spectroscopy.With the modulated electronic structure of metal sites,NiFe-[Cr(C_(2)O_(4))_(3)]^(3-)-LDHs exhibited promoted OER property with a lower overpotential of 236 mV at the current density of 10 mA cm^(-2).This work illustrates the intercalation of conjugated anion to dynamically construct desired Ni^(3+) sites with the optimal electronic environment for improved OER electrocatalysis.展开更多
This paper analyzes the characteristics of the output gradient histogram and shortages of several traditional automatic threshold methods in order to segment the gradient image better. Then an improved double-threshol...This paper analyzes the characteristics of the output gradient histogram and shortages of several traditional automatic threshold methods in order to segment the gradient image better. Then an improved double-threshold method is proposed, which is combined with the method of maximum classes variance, estimating-area method and double-threshold method. This method can automatically select two different thresholds to segment gradient images. The computer simulation is performed on the traditional methods and this algorithm and proves that this method can get satisfying result. Key words gradient histogram image - threshold selection - double-threshold method - maximum classes variance method CLC number TP 391. 41 Foundation item: Supported by the National Nature Science Foundation of China (50099620) and the Project of Chenguang Plan in Wuhan (985003062)Biography: YANG Shen (1977-), female, Ph. D. candidate, research direction: multimedia information processing and network technology.展开更多
We consider complex-valued functions f ∈ L^1 （R^2＋）, where R＋ ：= [0,∞）, and prove sufficient conditions under which the double sine Fourier transform fss and the double cosine Fourier transform fcc belong to o...We consider complex-valued functions f ∈ L^1 （R^2＋）, where R＋ ：= [0,∞）, and prove sufficient conditions under which the double sine Fourier transform fss and the double cosine Fourier transform fcc belong to one of the two-dimensional Lipschitz classes Lip（a,β） for some 0 〈 α,β ≤ 1; or to one of the Zygmund classes Zyg（α,β） for some 0 〈 α,β ≤ 2. These sufficient conditions are best possible in the sense that they are also necessary for nonnegative-valued functions f ∈ L^1 （R^2＋）.展开更多
Double - faced iso - object embroidery is carried out byusing the uneven intercalated stitch crafts of the parallel- lines stitch as a main body, being accompanied by oth-er stitch crafts and miscellaneous stitches, d...Double - faced iso - object embroidery is carried out byusing the uneven intercalated stitch crafts of the parallel- lines stitch as a main body, being accompanied by oth-er stitch crafts and miscellaneous stitches, done on thesame textile material. This paper deals with the flower -bird double - faced embroidery fan of the Qing Dynasty,from pattern design, stitching formation and techniqueof color arrangement, describes the possible way of mak-ing double - faced embroidery with iso - object effectboth in the front and in the back.展开更多
Abstract: A new pyrometer, which can solve the affection of emissivity change in temperature measuring, has been developed by double Y - type optical fibers. The mathematical model of the new pyrometer is presented an...Abstract: A new pyrometer, which can solve the affection of emissivity change in temperature measuring, has been developed by double Y - type optical fibers. The mathematical model of the new pyrometer is presented and the errors of the new pyrometer are analyzed.展开更多
The aspect of formation and evolution of the recycled pulsar（PSR J0737-3039 A/B） is investigated, taking into account the contributions of accretion rate, radius and spin-evolution diagram（- diagram） in the double...The aspect of formation and evolution of the recycled pulsar（PSR J0737-3039 A/B） is investigated, taking into account the contributions of accretion rate, radius and spin-evolution diagram（- diagram） in the double pulsar system. Accepting the spin-down age as a rough estimate（or often an upper limit） of the true age of the neutron star, we also impose the restrictions on the radius of this system. We calculate the radius of the recycled pulsar PSR J0737-3039 A ranges approximately from 8.14 to 25.74 km, and the composition of its neutron star nuclear matters is discussed in the mass-radius diagram.展开更多
基金support from the Free Exploration Project of Frontier Technology for Laoshan Laboratory(No.16-02)the National Natural Science Foundation of China(Nos.22072015 and 21927811)。
文摘Electrocatalytic hydrogen production from seawater holds enormous promise for clean energy generation.Nevertheless,the direct electrolysis of seawater encounters significant challenges due to poor anodic stability caused by detrimental chlorine chemistry.Herein,we present our recent discovery that the incorporation of Ce into Ni Fe layered double hydroxide nanosheet array on Ni foam(Ce-Ni Fe LDH/NF)emerges as a robust electrocatalyst for seawater oxidation.During the seawater oxidation process,CeO_(2)is generated,effectively repelling Cl^(-)and inhibiting the formation of Cl O-,resulting in a notable enhancement in the oxidation activity and stability of alkaline seawater.The prepared Ce-Ni Fe LDH/NF requires only overpotential of 390 m V to achieve the current density of 1 A cm^(-2),while maintaining long-term stability for 500 h,outperforming the performance of Ni Fe LDH/NF(430 m V,150 h)by a significant margin.This study highlights the effectiveness of a Ce-doping strategy in augmenting the activity and stability of materials based on Ni Fe LDH in seawater electrolysis for oxygen evolution.
基金the financial supports from the National Natural Science Foundation of China(No.20703042)National Basic Research Program of China(No.2010CB923300)+1 种基金USTC-NSRL Association Funding(No.KY2060030009)the Fundamental Research Funds for the Central Universities
文摘The double perovskite oxides Sr2Mg1-xF exMoO6-δ were investigated as catalysts for the methane oxidation.The structural properties of catalysts were characterized in detail by X-ray diffraction,X-ray photoelectron spectroscopy and X-ray absorption spectroscopy.The catalytic property was strongly influenced by the Fe substitution.The relation between catalytic performance and the degree of Fe substitution was examined with regard to the structure and surface characteristics of the mixed oxides.The Fe-containing catalysts exhibited higher activity attributable to the possible（Fe2＋,Mo6＋） and （Fe3＋,Mo5＋）valency pairs,and the highest activity was observed for Sr2Mg0.2Fe0.8MoO6-δ.The enhancement of the catalytic activity may be correlated with the Fe-relating surface lattice oxygen species and was discussed in view of the presence of oxygen vacancies.
基金Project(51478164)supported by the National Natural Science Foundation of ChinaProject(BK20181306)supported by Natural Science Foundation of Jiangsu Province,China。
文摘The aim of this paper is to investigate the effect of nitrite intercalated Mg-Al layered double hydroxides(Mg-Al LDH-NO_(2))on mortar durability under the coexisting environment of Cl−and SO_(4)^(2-).Cl−and SO_(4)^(2-) binding properties of Mg-Al LDH-NO_(2) in simulated concrete pore solutions,Cl−and SO_(4)^(2-) diffusion properties of mortars with Mg-Al LDHNO 2 were examined.The steel corrosion and resistance of mortar against SO_(4)^(2-) attack were also evaluated.The results indicate that Mg-Al LDH-NO_(2) can effectively adsorb the Cl−and SO_(4)^(2-) in simulated concrete pore solution,and inhibit the diffusion of Cl−and SO_(4)^(2-) into cement mortars.The presence of SO_(4)^(2-) can greatly affect the uptake amount of Cl−,and there is a coupled effect of Cl−and SO_(4)^(2-) on their penetration into mortar specimens.In addition,Mg-Al LDH-NO_(2) can greatly upgrade the resistance of mortars against SO_(4)^(2-) attack and well prevent the steel from corrosion.However,Cl−will aggravate the SO_(4)^(2-) attack and SO_(4)^(2-) can initially decrease and then increase the steel corrosion.
基金The research is financially supported by the Education and Teaching Reform Project of Central South University(Project No.:2019jy097)。
文摘With the continuous development of China's social economy,it has correspondingly promoted the development of the railway engineering experimental career,and has made tremendous progress in the cultivation of railway engineering experimental talents.At the same time,there are still many problems in the development of rail transit in the construction of"double first-class".Only by solving the existing problems can we further promote the smooth development of the training of railway engineering experimental talents.Therefore,the article mainly analyzes the problems and countermeasures of railway engineering experimental training,combined with the status and role of laboratories in the training of talents under the background of"double first-class",according to the society's demand for first-class engineering talents,we reformed and explored laboratory resource integration and optimization.
文摘Mg-Al layered double hydroxide intercalated with CO_(3)^(2-)(CO_(3)·Mg-Al LDH) is effective for treating HCl exhaust gas.HCl reacts with CO_(3)^(2-) in CO_(3)·Mg-Al LDH, resulting in the formation of Cl·Mg-Al LDH.We propose that CO_(2) can be used for the desorption of Cl^(-)from Cl·Mg-Al LDH to regenerate CO_(3)·Mg-Al LDH.Herein,we studied the desorption of a from CI-Mg-Al LDH by adding water to Cl·Mg-Al LDH and blowing CO_(2) into it.We also analyzed the effects of temperature and water addition speed on the desorption of CI^(-)from Cl·Mg-Al LDH.Our results show that the added water adhered to CI·Mg-Al LDH and that CO_(2) in the gaseous phase was dissolved in this adhered water,thus generating CO_(3)^(2-).Therefore,anion exchange occurred between CO_(3)^(2-) and Cl^(-)in the Cl·Mg-Al LDH,thus desorbing Cl^(-).
基金support from the National Natural Science Foundation of China(51402100,21905088,21573066 and U19A2017)the Provincial Natural Science Foundation of Hunan(2020JJ5044,2022JJ10006)。
文摘Rationally manipulating surface reconstruction of catalysts for water oxidation,inducing formation and dynamic accumulation of catalytically active centers still face numerous challenges.Herein,the introduction of[Cr(C_(2)O_(4))_(3)]^(3-)into NiFe LDHs by intercalation engineering to promote surface reconstruction achieves an advanced oxygen evolution reaction(OER)activity.In view of the weak electronegativity of Cr^(3+) in[Cr(C_(2)O_(4))_(3)]^(3-),the intercalation of[Cr(C_(2)O_(4))_(3)]^(3-)is expected to result in an electron-rich structure of Fe sites in NiFe LDHs,and higher valence state of Ni can be formed with the charge transfer between Fe and Ni.The optimized electronic structure of NiFe-[Cr(C_(2)O_(4))_(3)]^(3-)-LDHs with more active Ni^(3+) species and the expedited dynamic generation of Ni^(3+) (Fe)OOH phase during the OER process contributed to its excellent catalytic property,revealed by in situ X-ray absorption spectroscopy,Raman spectroscopy,and quasi-in situ X-ray photoelectron spectroscopy.With the modulated electronic structure of metal sites,NiFe-[Cr(C_(2)O_(4))_(3)]^(3-)-LDHs exhibited promoted OER property with a lower overpotential of 236 mV at the current density of 10 mA cm^(-2).This work illustrates the intercalation of conjugated anion to dynamically construct desired Ni^(3+) sites with the optimal electronic environment for improved OER electrocatalysis.
文摘This paper analyzes the characteristics of the output gradient histogram and shortages of several traditional automatic threshold methods in order to segment the gradient image better. Then an improved double-threshold method is proposed, which is combined with the method of maximum classes variance, estimating-area method and double-threshold method. This method can automatically select two different thresholds to segment gradient images. The computer simulation is performed on the traditional methods and this algorithm and proves that this method can get satisfying result. Key words gradient histogram image - threshold selection - double-threshold method - maximum classes variance method CLC number TP 391. 41 Foundation item: Supported by the National Nature Science Foundation of China (50099620) and the Project of Chenguang Plan in Wuhan (985003062)Biography: YANG Shen (1977-), female, Ph. D. candidate, research direction: multimedia information processing and network technology.
基金Supported partially by the Program TMOP-4.2.2/08/1/2008-0008 of the Hungarian National Development Agency
文摘We consider complex-valued functions f ∈ L^1 （R^2＋）, where R＋ ：= [0,∞）, and prove sufficient conditions under which the double sine Fourier transform fss and the double cosine Fourier transform fcc belong to one of the two-dimensional Lipschitz classes Lip（a,β） for some 0 〈 α,β ≤ 1; or to one of the Zygmund classes Zyg（α,β） for some 0 〈 α,β ≤ 2. These sufficient conditions are best possible in the sense that they are also necessary for nonnegative-valued functions f ∈ L^1 （R^2＋）.
文摘Double - faced iso - object embroidery is carried out byusing the uneven intercalated stitch crafts of the parallel- lines stitch as a main body, being accompanied by oth-er stitch crafts and miscellaneous stitches, done on thesame textile material. This paper deals with the flower -bird double - faced embroidery fan of the Qing Dynasty,from pattern design, stitching formation and techniqueof color arrangement, describes the possible way of mak-ing double - faced embroidery with iso - object effectboth in the front and in the back.
文摘Abstract: A new pyrometer, which can solve the affection of emissivity change in temperature measuring, has been developed by double Y - type optical fibers. The mathematical model of the new pyrometer is presented and the errors of the new pyrometer are analyzed.
基金Supported by the National Program on Key Research and Development Project under Grant No 2016YFA0400801the National Natural Science Foundation of China under Grant Nos 11173034,11673023 and 11364007+2 种基金the Fundamental Research Funds for the Central Universitythe Key Support Disciplines of Theoretical Physics of Guizhou Province Education Bureau under Grant No ZDXK[2015]38the Youth Talents Project of Science and Technology in Education Bureau of Guizhou Province under Grant No KY[2017]204
文摘The aspect of formation and evolution of the recycled pulsar（PSR J0737-3039 A/B） is investigated, taking into account the contributions of accretion rate, radius and spin-evolution diagram（- diagram） in the double pulsar system. Accepting the spin-down age as a rough estimate（or often an upper limit） of the true age of the neutron star, we also impose the restrictions on the radius of this system. We calculate the radius of the recycled pulsar PSR J0737-3039 A ranges approximately from 8.14 to 25.74 km, and the composition of its neutron star nuclear matters is discussed in the mass-radius diagram.
