A Calculation Method of Double Strength Reduction for Layered Slope Based on the Reduction of Water Content Intensity

The calculation of the factor of safety(FOS)is an important means of slope evaluation.This paper proposed an improved double strength reductionmethod(DRM)to analyze the safety of layered slopes.The physical properties of different soil layers of the slopes are different,so the single coefficient strength reduction method(SRM)is not enough to reflect the actual critical state of the slopes.Considering that the water content of the soil in the natural state is the main factor for the strength of the soil,the attenuation law of shear strength of clayey soil changing with water content is fitted.This paper also establishes the functional relationship between different reduction coefficients.Then,a USDFLD subroutine is programmed using the secondary development function of finite element software.Controlling the relationship between field variables and calculation time realizes double strength reduction applicable to the layered slope.Finally,by comparing the calculation results of different examples,it is proved that the stress and displacement distribution of the critical slope state obtained by the improved method is more realistic,and the calculated safety factor is more reliable.The newly proposedmethod considers the difference of intensity attenuation between different soil layers under natural conditions and avoids the disadvantage of the strength reduction method with uniform parameters,which provides a new idea and method for stability analysis of layered and complex slopes.

Numerical Modelling of Double Slit Caisson Breakwater Integrated Oscillating Water Column Wave Energy Converter with Modal Superposition Method

Oscillating water column wave energy converter is a power generation device in which ocean waves excite the oscillation of the water surface in an air chamber, which generates fluctuations in air pressure and rotate air turbine generator(s). The oscillation of the fluid in the air chamber is a fluid oscillation phenomenon with a natural period, similar to fluid oscillation in a container such as sloshing. Previous research has shown that for an oscillating water column with a single air chamber submerged in water, the oscillation characteristics can be modeled as a one-degree-of-freedom oscillation system that takes only a single oscillation mode into account. However, a double-slit breakwater integrated oscillating water column wave energy converter using two water columns of the breakwater separated by slit walls, has been verified to have two resonance periods. In this study, the free oscillating motion of the oscillating water column wave energy converter using the double-slit breakwater is modeled by modal superposition method including the first-order and second-order modes of vertical motion of the two water surfaces. The result from the simulation is similar to the result of the free vibration experiment.

Recent advances in flat sheet mixed matrix membrane modified by Mg-based layered double hydroxides(LDHs)for salt and organic compound separations

Magnesium(Mg)is a widely used and attractive metal,known for its unique physical and chemical properties,and it has been employed in the manufacture of many practical materials.Layered Double Hydroxides(LDHs),particularly Mg-based LDHs,rank among the most prevalent two-dimensional materials utilized in separation processes,which include adsorption,extraction,and membrane technology.The high popularity of Mg-based LDHs in separation applications can be attributed to their properties,such as excellent hydrophilicity,high surface area,ion exchangeability,and adjustable interlayer space.Currently,polymer membranes play a pivotal role in semi-industrial and industrial separation processes.Consequently,the development of polymer membranes and the mitigation of their limitations have emerged as compelling topics for researchers.Several methods exist to enhance the separation performance and anti-fouling properties of polymer membranes.Among these,incorporating additives into the membrane polymer matrix stands out as a cost-effective,straightforward,readily available,and efficient approach.The use of Mg-based LDHs,either in combination with other materials or as a standalone additive in the polymer membrane matrix,represents a promising strategy to bolster the separation and anti-fouling efficacy of flat sheet mixed matrix polymer membranes.This review highlights Mg-based LDHs as high-potential additives designed to refine flat sheet mixed matrix polymer membranes for applications in wastewater treatment and brackish water desalination.

The superhydrophobic sponge decorated with Ni-Co double layered oxides with thiol modification for continuous oil/water separation

In this paper, the superhydrophobic polyurethane sponge(SS-PU) was facilely fabricated by etching with Jones reagent to bind the nanoparticles of Ni-Co double layered oxides(LDOs) on the surface, and following modification with n-dodecyl mercaptan(DDT). This method provides a new strategy to fabricate superhydrophobic PU sponge with a water contact angle of 157° for absorbing oil with low cost and in large scale. It exhibits the strong absorption capacity and highly selective characteristic for various kinds of oils which can be recycled by simple squeezing. Besides, the as-prepared sponge can deal with the floating and underwater oils, indicating its application value in handling oil spills and domestic oily wastewater. The good self-cleaning ability shows the potential to clear the pollutants due to the ultralow adhesion to water. Especially, the most important point is that the superhydrophobic sponge can continuously and effectively separate the oil/water mixture against the condition of turbulent disturbance by using our designed device system, which exhibit its good superhydrophobicity, strong stability.Furthermore, the SS-PU still maintained stable absorption performance after 150 cycle tests without losing capacity obviously, showing excellent durability in long-term operation and significant potential as an efficient absorbent in large-scale dispose of oily water.

Reinforced temperature control of a reactive double dividing-wall distillation column

The mass and thermal coupling makes the control of the reactive double dividing-wall distillation column(R-DDWDC) an especially challenging issue with a highly interactive nature. With reference to the separation of an ideal endothermic quaternary reversible reaction with the most unfavorable ranking of relative volatilities(A + B ■ C + D with α_(A)>α_(C)>α_(D)>α_(B)), the operation rationality of the R-DDWDC is studied in this contribution. The four-point single temperature control system leads to great steady-state discrepancies in the compositions of products C and D and the reason stems essentially from the failure in keeping strictly the stoichiometric ratio between reactants A and B. A temperature plus temperature cascade control scheme is then employed to reinforce the stoichiometric ratio control and helps to secure a substantial abatement in the steady-state discrepancies. A temperature difference plus temperature cascade control scheme is finally synthesized and leads even to better performance than the most effective double temperature difference control scheme. These outcomes reveal not only the operation feasibility of the R-DDWDC but also the general significance of the proposed temperature difference plus temperature cascade control scheme to the inferential control of any other complicated distillation columns.

Accurate design of spatially separated double active site in Bi_(4)NbO_(8)Cl single crystal to promote Z-Scheme photocatalytic overall water splitting

The efficiency of photocatalytic overall water splitting was mainly limited by the slow reaction kinetics of water oxidation.How to design effective surface active site to overcome the slow water oxidation reaction was a major challenge.Here,we propose a strategy to accelerate surface water oxidation through the fabrication spatially separated double active sites.FeCoPi/Bi_(4)NbO_(8)Cl-OVs photocatalyst with spatially separated double active site was prepared by hydrogen reduction photoanode deposition method.Due to the high matching of the spatial loading positions of FeCoPi and OVs with the photogenerated charge distribution of Bi_(4)NbO_(8)Cl and corresponding reaction mechanisms of substrate,the FeCoPi and OVs on the(001)and(010)crystal planes of Bi_(4)NbO_(8)Cl photocatalyst provided surface active site for water oxidation reaction and electron shuttle reaction(Fe^(3+)/Fe^(2+)),respectively.Under visible light irradiation,the evolution O_(2)rate of FeCoPi/Bi_(4)NbO_(8)Cl OVs was 16.8μmol h^(-1),as 32.9 times as Bi_(4)NbO_(8)Cl.Furthermore,a hydrogen evolution co-catalyst PtRu@Cr_(2)O_(3)was prepared by sequential photodeposition method.Due to the introduction of Ru,the Schottky barrier between PbTiO_(3)and Pt was effectively reduced,which promoted the transfer of photogenerated electrons to PtRu@Cr_(2)O_(3)thermodynamically,the evolution H_(2)rate on PtRu@Cr_(2)O_(3)/PbTiO_(3)increased to 664.8 times.On based of the synchronous enhancement of the water oxidation performance on FeCoPi/Bi_(4)NbO_(8)Cl-OVs and water reduction performance on PtRu@Cr_(2)O_(3)/PbTiO_(3),a novel Z-Scheme photocatalytic overall water splitting system(FeCoPi/Bi_(4)NbO_(8)Cl-OVs)mediated by Fe^(3+)/Fe^(2+)had successfully constructed.Under visible light irradiation,the evolution rates of H_(2)and O_(2)were 2.5 and 1.3μmol h^(-1),respectively.This work can provide some reference for the design of active site and the controllable synthesis of OVs spatial position.On the other hand,the hydrogen evolution co catalyst(PtRu@Cr_(2)O_(3))and the co catalyst FeCoPi for oxygen evolution contributed to the construction of an overall water splitting system.

Recent progress in functionalized layered double hydroxides and their application in efficient electrocatalytic water oxidation

Layered double hydroxides (LDHs), a class of anionic clays consisting of brucite-like host layers and interlayer anions, have been widely investigated in the last decade due to their promising applications in many areas such as catalysis, ion separation and adsorption. Owing to the highly tunable compositi on and uniform distribution of metal cations in the brucite-like layers, as well as the facile exchangeability of intercalated anions, LDHs can be modified and functionalized to form various nanostructures/composites through versatile processes such as anion intercalation and exfoliation, decoration of nanoparticles, selfassembly with other two-dimensional (2D) materials, and controlled growth on conductive supports (e.g., nanowire arrays, nano tubes, 3D foams). In this article, we briefly review the recent advances on both the LDH nano structures and functionalized composites toward the applications in energy conversion, especially for water oxidation.

An Incursion of Off-Equatorial Subsurface Cold Water and Its Role in Triggering the “Double Dip” La Nia Event of 2011

Based on Global Ocean Data Assimilation System （GODAS） and NCEP reanalysis data, atmospheric and oceanic pro- cesses possibly responsible for the onset of the 2011/12 La Nifia event, which followed the 2010/11 La Nifia even--referred to as a ＂double dip＂ La Nifia--are investigated. The key mechanisms involved in activating the 2011/12 La Nifia are illus- trated by these datasets. Results show that neutral conditions were already evident in the equatorial eastern Pacific during the decaying phase of the 2010/11 La Nifia. However, isothermal analyses show obviously cold water still persisting at the surface and at subsurface depths in off-equatorial regions throughout early 2011, being most pronounced in the tropical South Pacific. The negative SST anomalies in the tropical South Pacific acted to strengthen a southern wind across the equator. The subsurface cold water in the tropical South Pacific then spread northward and broke into the equatorial region at the thermo- cline depth. This incursion process of off-equatorial subsurface cold water successfully interrupted the eastern propagation of warm water along the equator, which had previously accumulated at subsurface depths in the warm pool during the 2010/11 La Nifia event. Furthermore, the incursion process strengthened as a result of the off-equatorial effects, mostly in the tropical South Pacific. The negative SST anomalies then reappeared in the central basin in summer 2011, and acted to trigger local coupled air-sea interactions to produce atmospheric-oceanic anomalies that developed and evolved with the second cooling in the fall of 2011.

Model for water pollution remote sensing based on double scattering and its application in the Zhujiang River outfall

It is a valid route for quantitatively remote sensing on water pollution to build a model according to the physical mechanisms of scattering and absorbing of suspended substance, pollutant, and molecules of water. Remote sensing model for water pollution based on single scattering is simple and easy to be used, but the precision is affected by turbidity of water. The characteristics of the energy composition of multiple scattering, are analyzed and it is proposed that, based on the model of single scattering, if the flux of the second scattering is considered additionally, the precision of the model will be remarkably improved and the calculation is still very simple. The factor of the second scattering is deduced to build a double scattering model, and the practical arithmetic for the calculation of the model is put forward. The result of applying this model in the water area around the Zhujiang(Pearl) River outfall shows that the precision is obviously improved. The result also shows that the seriously polluted water area is distributed in the northeast of Lingding Sea, the Victoria Bay of Hong Kong, and the Shengzhen Bay.

Layered double hydroxide(LDH)-based materials:A mini-review on strategies to improve the performance for photocatalytic water splitting

The high energy demand we currently face in society and the subsequent large consumption of fossil fuels cause its depletion and increase the pollution levels.The quest for the production of clean energy from renewable and sustainable sources remains open.The conversion of solar energy into hydrogen via the water-splitting process,assisted by pho tores pons ive semiconductor catalysts,is one of the most promising technologies.Significant progress has been made on water splitting in the past few years and a variety of photocatalysts active not only under ultra-violet(UV) light but especially with the visible part of the electromagnetic spectrum have been developed.Layered double hydroxides(LDH)-based materials have emerged as a promising class of nanomaterials for solar energy applications owing to their unique layered structure,compositional flexibility,tunable bandgaps,ease of synthesis and low manufacturing costs.This review covers the most recent research dedicated to LDH materials for photocatalytic water-splitting applications and encompasses a range of synthetic strategies and post-modifications used to enhance their performance.Moreover,we provide a thorough discussion of the experimental conditions crucial to obtaining improved photoactivity and highlight the impact of some specific parameters,namely,catalysts loading,cocatalysts,sacrificial agents,and irradiation sources.This review provides the necessary tools to select the election technique for adequately enhancing the photoactivity of LDH and modified LDH-based materials and concludes with a critical summary that outlines further research directions.

2D materials modulating layered double hydroxides for electrocatalytic water splitting

Exploring highly efficient electrochemical water splitting catalysts has recently attracted extensive research interest from both fundamental researches and practical applications.Transition metal‐based layered double hydroxides(LDHs)have been proved to be one of the most efficient materials for oxygen evolution reaction(OER),however,still suffered from low conductivity and sluggish kinetics for hydrogen evolution reaction(HER),which largely inhibited the overall water splitting efficiency.To address this dilemma,enormous approaches including doping regulation,intercalation tuning and defect engineering are therefore rationally designed and developed.Herein,we focus on the recent exciting progress of LDHs hybridization with other two‐dimensional(2D)materials for water splitting reactions,not barely for enhancing OER efficiency but also for boosting HER activity.Particularly,the structural features,morphologies,charge transfer and synergistic effects for the heterostructure/heterointerface that influence the electrocatalytic performance are discussed in details.The hybrid 2D building blocks not only serve as additional conductivity and structural supported but also promote electron transfer at the interfaces and further enhance the electrocatalytic performance.The construction and application of the nanohybrid materials will guide a new direction in developing multifunctional materials based on LDHs,which will contribute to energy conversion and storage.

Automatic segmentation of gas plumes from multibeam water column images using a U-shape network

Cold seeps are widely developed on the seabed of continental margins and can form gas plumes due to the upward migration of methane-rich fluids.The detection and automatic segmentation of gas plumes are of great significance in locating and studying the cold seep system that is usually accompanied by hydrate layers in the subsurface.A multibeam echo-sounder system(MBES)can record the complete backscatter intensity of the water column,and it is one of the most effective means for detecting cold seeps.However,the gas plumes recorded in multibeam water column images(WCI)are usually blurred due to the interference of the complicated water environment and the sidelobes of the MBES,making it difficult to obtain the effective segmentation.Therefore,based on the existing UNet semantic segmentation network,this paper proposes an AP-UNet network combining the convolutional block attention module and the pyramid pooling module for the automatic segmentation and extraction of gas plumes.Comparative experiments are conducted among three traditional segmentation methods and two deep learning methods.The results show that the AP-UNet segmentation model can effectively suppress complicated water column noise interference.The segmentation precision,the Dice coefficient,and the recall rate of this model are 92.09%,92.00%,and 92.49%,respectively,which are 1.17%,2.10%,and 2.07%higher than the results of the UNet.

Liquid holdup measurement with double helix capacitance sensor in horizontal oil-water two-phase flow pipes

This paper presents the characteristics of a double helix capacitance sensor for measurement of the liquid holdup in horizontal oil–water two-phase flow. The finite element method is used to calculate the sensitivity field of the sensor in a pipe with 20 mm inner diameter and the effect of sensor geometry on the distribution of sensitivity field is presented. Then, a horizontal oil–water two-phase flow experiment is carried out to measure the response of the double helix capacitance sensor, in which a novel method is proposed to calibrate the liquid holdup based on three pairs of parallel-wire capacitance probes. The performance of the sensor is analyzed in terms of the flow structures detected by mini-conductance array probes.

NiFe layered double-hydroxide nanoparticles for efficiently enhancing performance of BiVO_4 photoanode in photoelectrochemical water splitting

A bismuth vanadate(BiVO4)photoanode with a cocatalyst consisting of NiFe layered double‐hydroxide(NiFe‐LDH)nanoparticles was fabricated for photoelectrochemical(PEC)water splitting.NiFe‐LDH nanoparticles,which can improve light‐absorption capacities and facilitate efficient hole transfer to the surface,were deposited on the surface of the BiVO4 photoanode by a hydrothermal method.All the samples were characterized using X‐ray diffraction,scanning electron microscopy,and diffuse‐reflectance spectroscopy.Linear sweep voltammetry and current‐time plots were used to investigate the PEC activity.The photocurrent response of NiFe‐LDH/BiVO4 at 1.23 V vs the reversible hydrogen electrode was higher than those of Ni(OH)2/BiVO4,Fe(OH)2/BiVO4 and pure BiVO4 electrodes under visible‐light illumination.NiFe‐LDH/BiVO4 also gave a superior PEC hydrogen evolution performance.Furthermore,the stability of the NiFe‐LDH/BiVO4 photoanode was excellent compared with that of the bare BiVO4 photoanode,and offers a novel method for solar‐assisted water splitting.

Heating of heavy oil by circulating hot water in closed double casing in ultra-deep wells

In heavy oil production,the loss of energy to ambient surroundings decreases the temperature of the heavy oil flowing upwards in a vertical wellbore,which increases the oil viscosity and the oil may not flow normally in the wellbore.Therefore,it is necessary to lower the heavy oil viscosity by heating methods to allow it to be lifted easily.Heating of heavy oil in an oil well is achieved by circulating hot water in annuli in the well（tubing-casing annulus,casing-casing annulus）.In this paper,based on heat transfer principles and fluid flow theory,a model is developed for produced fluids and hot water flowing in a vertical wellbore.The temperature and pressure of produced fluids and hot water in the wellbore are calculated and the effect of hot water on heavy oil temperature is analyzed.Calculated results show that the hot water circulating in the annuli may effectively heat the heavy oil in the tubing,so as to significantly reduce both oil viscosity and resistance to oil flow.

An accurate detection algorithm for time backtracked projectile-induced water columns based on the improved YOLO network

During a sea firing training,the intelligent detection of projectile-induced water column targets in a firing video is the prerequisite for and critical to the automatic calculation of miss distance,while the correct and precise calculation of miss distance is directly affected by the accuracy,false alarm rate and time delay of detection.After analyzing the characteristics of projectile-induced water columns,an accurate detection algorithm for time backtracked projectile-induced water columns based on the improved you only look once(YOLO)network is put forward.The capability and accuracy of detecting projectileinduced water column targets with the conventional YOLO network are improved by optimizing the anchor box through K-means clustering and embedding the squeeze and excitation(SE)attention module.The detection area is limited by adopting a sea-sky line detection algorithm based on gray level co-occurrence matrix(GLCM),so as to effectively eliminate such disturbances as ocean waves and ship wakes,and lower the false alarm rate of projectile-induced water column detection.The improved algorithm increases the mAP50 of water column detection by 30.3%.On the basis of correct detection,a time backtracking algorithm is designed with mean shift to track images containing projectile-induced water column in reverse time sequence.It accurately detects a projectile-induced water column at the time of its initial appearance as well as its pixel position in images,and considerably reduces detection delay,so as to provide the support for the automatic,accurate,and real-time calculation of miss distance.

On the sampling strategies and models for measuring diffusion exchange with a double diffusion encoding sequence

Water exchange between the different compartments of a heterogeneous specimen can be characterized via diffusion magnetic resonance imaging(dMRI).Many analysis frameworks using dMRI data have been proposed to describe exchange,often using a double diffusion encoding(DDE)stimulated echo sequence.Techniques such as diffusion exchange weighted imaging(DEWI)and the filter exchange and rapid exchange models,use a specific subset of the full space DDE signal.In this work,a general representation of the DDE signal was employed with different sampling schemes(namely constant b1,diagonal and anti-diagonal)from the data reduction models to estimate exchange.A near-uniform sampling scheme was proposed and compared with the other sampling schemes.The filter exchange and rapid exchange models were also applied to estimate exchange with their own subsampling schemes.These subsampling schemes and models were compared on both simulated data and experimental data acquired with a benchtop MR scanner.In synthetic data,the diagonal and near-uniform sampling schemes performed the best due to the consistency of their estimates with the ground truth.In experimental data,the shifted diagonal and near-uniform sampling schemes outperformed the others,yielding the most consistent estimates with the full space estimation.The results suggest the feasibility of measuring exchange using a general representation of the DDE signal along with variable sampling schemes.In future studies,algorithms could be further developed for the optimization of sampling schemes,as well as incorporating additional properties,such as geometry and diffusion anisotropy,into exchange frameworks.

Recent progress in water splitting and hybrid supercapacitors based on nickel-vanadium layered double hydroxides

Environmentally friendly energy sources alternatives to fossil fuels such as solar and wind are strategic for meeting the needs of an increasingly energy demanding society,despite their periodic/intermittent nature.Thus,urge the development of clean and renewable energy sources such as based on solar energy and water in a cyclic way,by photoinduced water-splitting and regeneration in fuel cells.In this context,energy storage devices such as hybrid supercapacitors become fundamental for realization of a sustainable society.In this review,the early discovery and recent advances concerning synthetic strategies,hierarchical structures,and oxygen evolution reaction(OER)/hydrogen evolution reactions(HER) catalytic performances of nickel-vanadium double hydroxides(NiV-LDHs) based nanomaterials are summarized.A discussion about the role of vanadium ions in HER/OER was also included,highlighting the recent progress in theoretical calculations in this field.Finally,some hybrid supercapacitor electrode materials based on NiV-LDHs are described,including the strategies to circumvent the parasitic oxygen evolution reaction during charge-discharge of those energy storage devices.In short,catalysts for HER/OER and hybrid supercapacitor electrode materials based on NiV-LDHs were reviewed considering their key multifunctional role in the way to a more sustainable society.

Middle or low water pressure direct spiral double helix converging nozzle structure optimization and flow field analysis

In order to solve the problem of using new nozzle is proposed in fire rescue robot. middle or low water pressure to form fine water mist, a Existing water mist nozzles are basically used for high pressure and in large size, complex structure and poor low pressure atomization effect in comparison with requirement of snake-like fire rescue robots. On the basis of comprehensive typical spray noz- zles, a direct spiral double helix converging nozzle （DSDHCN） is proposed, which has the advanta- ges of small volume, light weight, simple structure, and convenient installation. To make the spray nozzle have good performance, and meet the requirements of more efficient fire extinguishing, a nu- merical study is carried out to analyze the internal and external full flow field of nozzle. A gas-liquid two-phase flow is applied to simulate the external full flow field of nozzle with VOF model in fluent software. The simulation results show the real situation of water flow out of the atomization nozzle and the water jet trajectory. Some simulations about middle or low water pressure direct spiral double he- lix converging optimized nozzle have been done in 30bar pressure. The simulation results show that the optimized nozzle structure not only makes the spray droplets have a good cone angle, but also have a sufficient axial velocity,which proves the structure rationality of the proposed optimized nozzle.

Hydrodynamic Performance of An Integrated System of Breakwater and A Multi-Chamber OWC Wave Energy Converter

A multi-chamber oscillating water column wave energy converter(OWC-WEC)integrated to a breakwater is investigated.The hydrodynamic characteristics of the device are analyzed using an analytical model based on the linear potential flow theory.A pneumatic model is employed to investigate the relationship between the air mass flux in the chamber and the turbine characteristics.The effects of chamber width,wall draft and wall thickness on the hydrodynamic performance of a dual-chamber OWC-WEC are investigated.The results demonstrate that the device,with a smaller front wall draft and a wider rear chamber exhibits a broader effective frequency bandwidth.The device with a chamber-width-ratio of 1:3 performs better in terms of power absorption.Additionally,results from the analysis of a triplechamber OWC-WEC demonstrate that reducing the front chamber width and increasing the rearward chamber width can improve the total performance of the device.Increasing the number of chambers from 1 to 2 or 3 can widen the effective frequency bandwidth.