采用CALPHAD(calculation of phase diagram)方法对Fe-V和Ni-V二元系进行了热力学优化,并结合第一性原理计算,利用(A,B)_(10)(A,B)_(4)(A,B)_(16)三亚点阵模型描述σ相,首次成功地描述了σ相的占位分数。使用优化的模型参数不仅可以描述...采用CALPHAD(calculation of phase diagram)方法对Fe-V和Ni-V二元系进行了热力学优化,并结合第一性原理计算,利用(A,B)_(10)(A,B)_(4)(A,B)_(16)三亚点阵模型描述σ相,首次成功地描述了σ相的占位分数。使用优化的模型参数不仅可以描述Fe-V和Ni-V系热化学性质,而且可以很好地重现Fe-V和Ni-V系的相平衡关系,为高熵合金多组元热力学数据库的建立奠定基础。展开更多
在不预热情况下 ,通过调整熔敷金属Cu和Ni的含量 ,改变铸铁激光熔敷层内奥氏体相与渗碳体相体积分数 ,分析了奥氏体相体积分数对熔敷层抗裂性的影响。在最佳激光熔敷工艺参数基础上 ,研究了Cu和Ni对熔敷层奥氏体体积分数、表面裂纹率及...在不预热情况下 ,通过调整熔敷金属Cu和Ni的含量 ,改变铸铁激光熔敷层内奥氏体相与渗碳体相体积分数 ,分析了奥氏体相体积分数对熔敷层抗裂性的影响。在最佳激光熔敷工艺参数基础上 ,研究了Cu和Ni对熔敷层奥氏体体积分数、表面裂纹率及表面耐磨性的影响。获得的未裂临界熔敷层面积为 5 5 .1cm2 ,其对应熔敷材料为Cu Ni C Si Fe。以此熔敷材料为基础 ,改变V含量 ,在熔敷层得到原位自生V2 C。研究了V2 C对熔敷层耐磨性的影响 ,分析了V2 C对熔敷层硬度及磨损质量损失的影响规律 ,最终获得了可显著提高熔敷层抗裂性及耐磨性的Cu Ni V C Si展开更多
To modify the thermodynamics and kinetic performance of magnesium hydride(MgH_(2))for solid-state hydrogen storage,Ni_(3)V_(2)O_(8)-rGO(rGO represents reduced graphene oxide)and Ni_(3)V_(2)O_(8)nanocomposites were pre...To modify the thermodynamics and kinetic performance of magnesium hydride(MgH_(2))for solid-state hydrogen storage,Ni_(3)V_(2)O_(8)-rGO(rGO represents reduced graphene oxide)and Ni_(3)V_(2)O_(8)nanocomposites were prepared by hydrothermal and subsequent heat treatment.The beginning hydrogen desorption temperature of 7 wt.%Ni_(3)V_(2)O_(8)-rGO modified MgH_(2)was reduced to 208℃,while the additive-free MgH_(2)and 7 wt.%Ni_(3)V_(2)O_(8)doped MgH_(2)appeared to discharge hydrogen at 340 and 226℃,respectively.A charging capacity of about 4.7 wt.%H_(2)for MgH_(2)+7 wt.%Ni_(3)V_(2)O_(8)-rGO was achieved at 125℃ in 10 min,while the dehydrogenated MgH_(2)took 60 min to absorb only 4.6 wt.%H_(2)at 215℃.The microstructure analysis confirmed that the in-situ generated Mg_(2)Ni/Mg_(2)N_(i)H_(4) and metallic V contributed significantly to the enhanced performance of MgH_(2).In addition,the presence of rGO in the MgH_(2)+7 wt.%Ni_(3)V_(2)O_(8)-rGO composite reduced particle aggregation tendency of Mg/MgH_(2),leading to improving the cyclic stability of MgH_(2)during 20 cycles.展开更多
文摘采用CALPHAD(calculation of phase diagram)方法对Fe-V和Ni-V二元系进行了热力学优化,并结合第一性原理计算,利用(A,B)_(10)(A,B)_(4)(A,B)_(16)三亚点阵模型描述σ相,首次成功地描述了σ相的占位分数。使用优化的模型参数不仅可以描述Fe-V和Ni-V系热化学性质,而且可以很好地重现Fe-V和Ni-V系的相平衡关系,为高熵合金多组元热力学数据库的建立奠定基础。
文摘在不预热情况下 ,通过调整熔敷金属Cu和Ni的含量 ,改变铸铁激光熔敷层内奥氏体相与渗碳体相体积分数 ,分析了奥氏体相体积分数对熔敷层抗裂性的影响。在最佳激光熔敷工艺参数基础上 ,研究了Cu和Ni对熔敷层奥氏体体积分数、表面裂纹率及表面耐磨性的影响。获得的未裂临界熔敷层面积为 5 5 .1cm2 ,其对应熔敷材料为Cu Ni C Si Fe。以此熔敷材料为基础 ,改变V含量 ,在熔敷层得到原位自生V2 C。研究了V2 C对熔敷层耐磨性的影响 ,分析了V2 C对熔敷层硬度及磨损质量损失的影响规律 ,最终获得了可显著提高熔敷层抗裂性及耐磨性的Cu Ni V C Si
基金the financial support from the National Natural Science Foundation of China(No.51801078).
文摘To modify the thermodynamics and kinetic performance of magnesium hydride(MgH_(2))for solid-state hydrogen storage,Ni_(3)V_(2)O_(8)-rGO(rGO represents reduced graphene oxide)and Ni_(3)V_(2)O_(8)nanocomposites were prepared by hydrothermal and subsequent heat treatment.The beginning hydrogen desorption temperature of 7 wt.%Ni_(3)V_(2)O_(8)-rGO modified MgH_(2)was reduced to 208℃,while the additive-free MgH_(2)and 7 wt.%Ni_(3)V_(2)O_(8)doped MgH_(2)appeared to discharge hydrogen at 340 and 226℃,respectively.A charging capacity of about 4.7 wt.%H_(2)for MgH_(2)+7 wt.%Ni_(3)V_(2)O_(8)-rGO was achieved at 125℃ in 10 min,while the dehydrogenated MgH_(2)took 60 min to absorb only 4.6 wt.%H_(2)at 215℃.The microstructure analysis confirmed that the in-situ generated Mg_(2)Ni/Mg_(2)N_(i)H_(4) and metallic V contributed significantly to the enhanced performance of MgH_(2).In addition,the presence of rGO in the MgH_(2)+7 wt.%Ni_(3)V_(2)O_(8)-rGO composite reduced particle aggregation tendency of Mg/MgH_(2),leading to improving the cyclic stability of MgH_(2)during 20 cycles.
