The effects of dwell time on the phase structure, microstructure, and electrical properties were investigated for the 0.98（K0.sNa0.5）NbO3-0.02LaFeO3 ceramics （abbreviated as 0.98KNN-0.02LF）. All the ceramics sinte...The effects of dwell time on the phase structure, microstructure, and electrical properties were investigated for the 0.98（K0.sNa0.5）NbO3-0.02LaFeO3 ceramics （abbreviated as 0.98KNN-0.02LF）. All the ceramics sintered for different dwell time are of pure phase and the peak intensity of the 0.98KNN-0.02LF ceramics becomes stronger with a longer dwell time. Denser microstructures with larger grain size are developed for the sample with a longer dwell time. The maximum dielectric permittivity decreases with increasing the dwell time, and the deteriorative dielectric properties are due to the increasing grain size and the domain wall motion. Ferroelectric properties results indicate that 2Pr value slightly decreases with increasing the dwell time, while the 2Ec value increases. Consequently, the 0.98KNN-0.02LF ceramic sintered at 1150 ℃ for 2 h shows optimum dielectric properties （er=2253 and tan fi〈5%） and ferroelectric properties （2Pr=34.51 gC/cm2 and 2Ec=5.07 kV/mm）.展开更多
The lead-free piezoelectric ceramics (1-x)(K0.5Na0.5)NbO3-xLiNbO3(abbreviated as KNLN) were synthesized by a traditional solid state reaction. The effects of Li+ on the sintering characteristic, the phase structure an...The lead-free piezoelectric ceramics (1-x)(K0.5Na0.5)NbO3-xLiNbO3(abbreviated as KNLN) were synthesized by a traditional solid state reaction. The effects of Li+ on the sintering characteristic, the phase structure and piezoelectric properties of KNLN ceramics were investigated. The sintering temperature of KNN-based ceramics is decreased by doping Li+ and the range of the sintering temperature is narrow. The KNLN ceramics exhibit an enhanced piezoelectric properties with the piezoelectric constant d33 value of 180-200 pC/N, The electromechanical coupling coefficients kp is 35%-40%. The results show that (1-x)(K0.5Na0.5)-NbO3-xLiNbO3 (x=0.05, 0.06) is a promising high-temperature lead free piezoelectric ceramic.展开更多
基金Project(CX201108)supported by the Doctorate Foundation of Northwestern Polytechnical University,ChinaProject(51072165)supported by the National Natural Science Foundation of ChinaProjects(KP200901,SKLSP201104)supported by the Fund of State Key Laboratory of Solidification Processing in NWPU,China
文摘The effects of dwell time on the phase structure, microstructure, and electrical properties were investigated for the 0.98（K0.sNa0.5）NbO3-0.02LaFeO3 ceramics （abbreviated as 0.98KNN-0.02LF）. All the ceramics sintered for different dwell time are of pure phase and the peak intensity of the 0.98KNN-0.02LF ceramics becomes stronger with a longer dwell time. Denser microstructures with larger grain size are developed for the sample with a longer dwell time. The maximum dielectric permittivity decreases with increasing the dwell time, and the deteriorative dielectric properties are due to the increasing grain size and the domain wall motion. Ferroelectric properties results indicate that 2Pr value slightly decreases with increasing the dwell time, while the 2Ec value increases. Consequently, the 0.98KNN-0.02LF ceramic sintered at 1150 ℃ for 2 h shows optimum dielectric properties （er=2253 and tan fi〈5%） and ferroelectric properties （2Pr=34.51 gC/cm2 and 2Ec=5.07 kV/mm）.
基金Project( 10474077) supported by the National Natural Science Foundation of China Project(2002CB613304) supported by the National Basic Research Program of China
文摘The lead-free piezoelectric ceramics (1-x)(K0.5Na0.5)NbO3-xLiNbO3(abbreviated as KNLN) were synthesized by a traditional solid state reaction. The effects of Li+ on the sintering characteristic, the phase structure and piezoelectric properties of KNLN ceramics were investigated. The sintering temperature of KNN-based ceramics is decreased by doping Li+ and the range of the sintering temperature is narrow. The KNLN ceramics exhibit an enhanced piezoelectric properties with the piezoelectric constant d33 value of 180-200 pC/N, The electromechanical coupling coefficients kp is 35%-40%. The results show that (1-x)(K0.5Na0.5)-NbO3-xLiNbO3 (x=0.05, 0.06) is a promising high-temperature lead free piezoelectric ceramic.
