Reaction of laser ablated zinc and cadmium atoms with SO2 molecules was studied by low temperature matrix isolation infrared spectroscopy. Cyclic M（SO2） and anion M（SO2）-（M=Zn, Cd） were produced in excess argon ...Reaction of laser ablated zinc and cadmium atoms with SO2 molecules was studied by low temperature matrix isolation infrared spectroscopy. Cyclic M（SO2） and anion M（SO2）-（M=Zn, Cd） were produced in excess argon and neon, which were identified by 34SO2 and S18O2 isotopic substitutions. The observed infrared spectra and molecular structures were confirmed by density functional theoretical calculations. Natural charge distributions indicated significant electron transfer from s orbitals of zinc or cadmium metal atom to S02 ligand and cyclic M（SO2） complexes favored ＂ion pair＂ M＋（SO2）-formation, which were trapped in low temperature matrices. In addition Zn-O or Cd-O bond in M（SO2） exhibited strong polarized covalent character. Reaction of Hg atom with SO2 was also investigated, but no reaction product was observed, due to the relativistic effect that resulted in the contraction of 6s valence shell and high ionization potential of Hg atom.展开更多
We first obtained by impregnating the zeolite with salts U, W and V and examined the X-ray uranium catalyst SAPO-U, W, V based on natural zeolite Chankanayskogoe deposits for the oxidation of SO2 to SO3.
对菊花在长期低浓度SO2情况下光合色素含量和叶绿素荧光特性进行了研究.结果表明:用0.3 m g.L-1的SO2处理1周,引起菊花叶片光合色素含量显著增加,叶绿素荧光动力学曲线明显下降,表观电子传递速率(E)、非环式电子传递的量子效率(Y)和光...对菊花在长期低浓度SO2情况下光合色素含量和叶绿素荧光特性进行了研究.结果表明:用0.3 m g.L-1的SO2处理1周,引起菊花叶片光合色素含量显著增加,叶绿素荧光动力学曲线明显下降,表观电子传递速率(E)、非环式电子传递的量子效率(Y)和光化学淬灭系数(qp)有所增加;熏气至6周,叶绿素荧光动力学曲线和非光化学淬灭系数(qN)显著升高,光合色素含量显著下降,PS II反应中心潜在活性(FV/F0)、E和Y明显降低,而对PS II原初光能转换效率(FV/Fm)和qp的影响较小.展开更多
文摘Reaction of laser ablated zinc and cadmium atoms with SO2 molecules was studied by low temperature matrix isolation infrared spectroscopy. Cyclic M（SO2） and anion M（SO2）-（M=Zn, Cd） were produced in excess argon and neon, which were identified by 34SO2 and S18O2 isotopic substitutions. The observed infrared spectra and molecular structures were confirmed by density functional theoretical calculations. Natural charge distributions indicated significant electron transfer from s orbitals of zinc or cadmium metal atom to S02 ligand and cyclic M（SO2） complexes favored ＂ion pair＂ M＋（SO2）-formation, which were trapped in low temperature matrices. In addition Zn-O or Cd-O bond in M（SO2） exhibited strong polarized covalent character. Reaction of Hg atom with SO2 was also investigated, but no reaction product was observed, due to the relativistic effect that resulted in the contraction of 6s valence shell and high ionization potential of Hg atom.
文摘We first obtained by impregnating the zeolite with salts U, W and V and examined the X-ray uranium catalyst SAPO-U, W, V based on natural zeolite Chankanayskogoe deposits for the oxidation of SO2 to SO3.
文摘对菊花在长期低浓度SO2情况下光合色素含量和叶绿素荧光特性进行了研究.结果表明:用0.3 m g.L-1的SO2处理1周,引起菊花叶片光合色素含量显著增加,叶绿素荧光动力学曲线明显下降,表观电子传递速率(E)、非环式电子传递的量子效率(Y)和光化学淬灭系数(qp)有所增加;熏气至6周,叶绿素荧光动力学曲线和非光化学淬灭系数(qN)显著升高,光合色素含量显著下降,PS II反应中心潜在活性(FV/F0)、E和Y明显降低,而对PS II原初光能转换效率(FV/Fm)和qp的影响较小.
