A thermoelectric generation Stirling engine (TEG-Stirling engine) is discussed by employing a low temperature Stirling engine and the dissipative equation of motion derived from the method of thermomechanical dynamics...A thermoelectric generation Stirling engine (TEG-Stirling engine) is discussed by employing a low temperature Stirling engine and the dissipative equation of motion derived from the method of thermomechanical dynamics (TMD). The results and mechanism of axial flux electromagnetic induction (AF-EMI) are applied to a low temperature Stirling engine, resulting in a TEG-Stirling engine. The method of TMD produced thermodynamically consistent and time-dependent physical quantities for the first time, such as internal energy ℰ(t), thermodynamic work Wth(t), the total entropy (heat dissipation) Qd(t)and measure or temperature of a nonequilibrium state T˜(t). The TMD analysis produced a lightweight mechanical system of TEG-Stirling engine which derives electric power from waste heat of temperature (40˚CT100˚C) by a thermoelectric conversion method. An optimal low rotational speed about 30θ′(t)/(2π)60(rpm) is found, applicable to devices for sustainable, clean energy technologies. The stability of a thermal state and angular rotations of TEG-Stirling engine are specifically shown by employing properties of nonequilibrium temperature T˜(t), which is also applied to study optimal fuel-injection and combustion timings of heat engines.展开更多
The thermoelectric energy conversion technique by employing the Disk-Magnet Electromagnetic Induction (DM-EMI) is examined in detail, and possible applications to heat engines as one of the energy-harvesting technolog...The thermoelectric energy conversion technique by employing the Disk-Magnet Electromagnetic Induction (DM-EMI) is examined in detail, and possible applications to heat engines as one of the energy-harvesting technologies are discussed. The idea is induced by the analysis of thermomechanical dynamics (TMD) for a nonequilibrium irreversible thermodynamic system of heat engines, such as a drinking bird and a low temperature Stirling engine, resulting in thermoelectric energy generation different from conventional heat engines. The current thermoelectric energy conversion with DM-EMI can be applied to wide ranges of machines and temperature differences. The mechanism of DM-EMI energy converter is categorized as the axial flux generator (AFG), which is the reason why the technology is applicable to sensitive thermoelectric conversions. On the other hand, almost all the conventional turbines use the radius flux generator to extract huge electric power, which uses the radial flux generator (RFG). The axial flux generator is helpful for a low mechanoelectric energy conversion and activations of waste heat from macroscopic energy generators such as wind, geothermal, thermal, nuclear power plants and heat-dissipation lines. The technique of DM-EMI will contribute to solving environmental problems to maintain clean and sustainable energy as one of the energy harvesting technologies.展开更多
Zinc oxide(ZnO)serves as a crucial functional semiconductor with a wide direct bandgap of approximately 3.37 eV.Solvothermal reaction is commonly used in the synthesis of ZnO micro/nanostructures,given its low cost,si...Zinc oxide(ZnO)serves as a crucial functional semiconductor with a wide direct bandgap of approximately 3.37 eV.Solvothermal reaction is commonly used in the synthesis of ZnO micro/nanostructures,given its low cost,simplicity,and easy implementation.Moreover,ZnO morphology engineering has become desirable through the alteration of minor conditions in the reaction process,particularly at room temperature.In this work,ZnO micro/nanostructures were synthesized in a solution by varying the amounts of the ammonia added at low temperatures(including room temperature).The formation of Zn^(2+)complexes by ammonia in the precursor regulated the reaction rate of the morphology engineering of ZnO,which resulted in various structures,such as nanoparticles,nanosheets,microflowers,and single crystals.Finally,the obtained ZnO was used in the optoelectronic application of ultraviolet detectors.展开更多
To accurately diagnosemisfire faults in automotive engines,we propose a Channel Attention Convolutional Model,specifically the Squeeze-and-Excitation Networks(SENET),for classifying engine vibration signals and precis...To accurately diagnosemisfire faults in automotive engines,we propose a Channel Attention Convolutional Model,specifically the Squeeze-and-Excitation Networks(SENET),for classifying engine vibration signals and precisely pinpointing misfire faults.In the experiment,we established a total of 11 distinct states,encompassing the engine’s normal state,single-cylinder misfire faults,and dual-cylinder misfire faults for different cylinders.Data collection was facilitated by a highly sensitive acceleration signal collector with a high sampling rate of 20,840Hz.The collected data were methodically divided into training and testing sets based on different experimental groups to ensure generalization and prevent overlap between the two sets.The results revealed that,with a vibration acceleration sequence of 1000 time steps(approximately 50 ms)as input,the SENET model achieved a misfire fault detection accuracy of 99.8%.For comparison,we also trained and tested several commonly used models,including Long Short-Term Memory(LSTM),Transformer,and Multi-Scale Residual Networks(MSRESNET),yielding accuracy rates of 84%,79%,and 95%,respectively.This underscores the superior accuracy of the SENET model in detecting engine misfire faults compared to other models.Furthermore,the F1 scores for each type of recognition in the SENET model surpassed 0.98,outperforming the baseline models.Our analysis indicated that the misclassified samples in the LSTM and Transformer models’predictions were primarily due to intra-class misidentifications between single-cylinder and dual-cylinder misfire scenarios.To delve deeper,we conducted a visual analysis of the features extracted by the LSTM and SENET models using T-distributed Stochastic Neighbor Embedding(T-SNE)technology.The findings revealed that,in the LSTMmodel,data points of the same type tended to cluster together with significant overlap.Conversely,in the SENET model,data points of various types were more widely and evenly dispersed,demonstrating its effectiveness in distinguishing between different fault types.展开更多
Rechargeable magnesium batteries(RMBs)have been considered a promising“post lithium-ion battery”system to meet the rapidly increasing demand of the emerging electric vehicle and grid energy storage market.However,th...Rechargeable magnesium batteries(RMBs)have been considered a promising“post lithium-ion battery”system to meet the rapidly increasing demand of the emerging electric vehicle and grid energy storage market.However,the sluggish diffusion kinetics of bivalent Mg^(2+)in the host material,related to the strong Coulomb effect between Mg^(2+)and host anion lattices,hinders their further development toward practical applications.Defect engineering,regarded as an effective strategy to break through the slow migration puzzle,has been validated in various cathode materials for RMBs.In this review,we first thoroughly understand the intrinsic mechanism of Mg^(2+)diffusion in cathode materials,from which the key factors affecting ion diffusion are further presented.Then,the positive effects of purposely introduced defects,including vacancy and doping,and the corresponding strategies for introducing various defects are discussed.The applications of defect engineering in cathode materials for RMBs with advanced electrochemical properties are also summarized.Finally,the existing challenges and future perspectives of defect engineering in cathode materials for the overall high-performance RMBs are described.展开更多
Ischemic stroke is a secondary cause of mortality worldwide,imposing considerable medical and economic burdens on society.Extracellular vesicles,serving as natural nanocarriers for drug delivery,exhibit excellent bioc...Ischemic stroke is a secondary cause of mortality worldwide,imposing considerable medical and economic burdens on society.Extracellular vesicles,serving as natural nanocarriers for drug delivery,exhibit excellent biocompatibility in vivo and have significant advantages in the management of ischemic stroke.However,the uncertain distribution and rapid clearance of extracellular vesicles impede their delivery efficiency.By utilizing membrane decoration or by encapsulating therapeutic cargo within extracellular vesicles,their delivery efficacy may be greatly improved.Furthermore,previous studies have indicated that microvesicles,a subset of large-sized extracellular vesicles,can transport mitochondria to neighboring cells,thereby aiding in the restoration of mitochondrial function post-ischemic stroke.Small extracellular vesicles have also demonstrated the capability to transfer mitochondrial components,such as proteins or deoxyribonucleic acid,or their sub-components,for extracellular vesicle-based ischemic stroke therapy.In this review,we undertake a comparative analysis of the isolation techniques employed for extracellular vesicles and present an overview of the current dominant extracellular vesicle modification methodologies.Given the complex facets of treating ischemic stroke,we also delineate various extracellular vesicle modification approaches which are suited to different facets of the treatment process.Moreover,given the burgeoning interest in mitochondrial delivery,we delved into the feasibility and existing research findings on the transportation of mitochondrial fractions or intact mitochondria through small extracellular vesicles and microvesicles to offer a fresh perspective on ischemic stroke therapy.展开更多
Throughout the contemporary Chinese history of geography,geographical engineering has consistently played a pivotal role as a fundamental scientific activity.It possesses its distinct ontological basis and value orien...Throughout the contemporary Chinese history of geography,geographical engineering has consistently played a pivotal role as a fundamental scientific activity.It possesses its distinct ontological basis and value orientation,rendering it inseparable from being merely a derivative of geographical science or technology.This paper defines geographical engineering and introduces its development history through the lens of Chinese geographical engineering praxises.Furthermore,it is highlighted the logical and functional consistency between the theory of human-earth system and the praxis of geographical engineering.Six modern cases of geographical engineering projects are presented in detail to demonstrate the points and characteristics of different types of modern geographical engineering.Geographical engineering serves as an engine for promoting integrated geography research,and in response to the challenge posed by fragmented geographies,this paper advocates for an urgent revitalization of geographical engineering.The feasibility of revitalizing geographical engineering is guaranteed because it aligns with China’s national strategies.展开更多
Recent advances in research on extracellular vesicles have significantly enhanced their potential as therapeutic agents for neurological diseases.Owing to their therapeutic properties and ability to cross the blood–b...Recent advances in research on extracellular vesicles have significantly enhanced their potential as therapeutic agents for neurological diseases.Owing to their therapeutic properties and ability to cross the blood–brain barrier,extracellular vesicles are recognized as promising drug delivery vehicles for various neurological conditions,including ischemic stroke,traumatic brain injury,neurodegenerative diseases,glioma,and psychosis.However,the clinical application of natural extracellular vesicles is hindered by their limited targeting ability and short clearance from the body.To address these limitations,multiple engineering strategies have been developed to enhance the targeting capabilities of extracellular vesicles,thereby enabling the delivery of therapeutic contents to specific tissues or cells.Therefore,this review aims to highlight the latest advancements in natural and targeting-engineered extracellular vesicles,exploring their applications in treating traumatic brain injury,ischemic stroke,Parkinson's disease,Alzheimer's disease,amyotrophic lateral sclerosis,glioma,and psychosis.Additionally,we summarized recent clinical trials involving extracellular vesicles and discussed the challenges and future prospects of using targeting-engineered extracellular vesicles for drug delivery in treating neurological diseases.This review offers new insights for developing highly targeted therapies in this field.展开更多
Transverse-flux with high efficiency has been applied in Stirling engine and permanent magnet synchronous linear generator system,however it is restricted for large application because of low and complex process.A nov...Transverse-flux with high efficiency has been applied in Stirling engine and permanent magnet synchronous linear generator system,however it is restricted for large application because of low and complex process.A novel type of cylindrical,non-overlapping,transverse-flux,and permanent-magnet linear motor(TFPLM) is investigated,furthermore,a high power factor and less process complexity structure research is developed.The impact of magnetic leakage factor on power factor is discussed,by using the Finite Element Analysis(FEA) model of stirling engine and TFPLM,an optimization method for electro-magnetic design of TFPLM is proposed based on magnetic leakage factor.The relation between power factor and structure parameter is investigated,and a structure parameter optimization method is proposed taking power factor maximum as a goal.At last,the test bench is founded,starting experimental and generating experimental are performed,and a good agreement of simulation and experimental is achieved.The power factor is improved and the process complexity is decreased.This research provides the instruction to design high-power factor permanent-magnet linear generator.展开更多
In this Letter we outline a dielectric multilayer spectrally selective filter designed for solar energy applications.The optical performance of this 78-layer interference filter constructed by TiOx and SiO_(2) is pres...In this Letter we outline a dielectric multilayer spectrally selective filter designed for solar energy applications.The optical performance of this 78-layer interference filter constructed by TiOx and SiO_(2) is presented.A hybrid system combining photovoltaic cells with a solar-powered Stirling engine using the designed filter is analyzed.The calculated results show the advantages of this spectrally selective method for solar power generation.展开更多
Based on the state equation of an ideal quantum gas, the regenerative loss of a Stirling engine cycle working with an ideal quantum gas is calculated. Thermal efficiency of the cycle is derived. Furthermore, under the...Based on the state equation of an ideal quantum gas, the regenerative loss of a Stirling engine cycle working with an ideal quantum gas is calculated. Thermal efficiency of the cycle is derived. Furthermore, under the condition of quantum degeneracy, several special thermal efficiencies are discussed. Ratios of thermal efficiencies versus the temperature ratio and volume ratio of the cycle are made. It is found that the thermal efficiency of the cycle not only depends on high and low temperatures but also on maximum and minimum volumes. In a classical gas state the thermal efficiency of the cycle is equal to that of the Carnot cycle. In an ideal quantum gas state the thermal efficiency of the cycle is smaller than that of the Carnot cycle. This will be significant for deeper understanding of the gas Stirling engine cycle.展开更多
The reported discrepancy between theory and experiment for external combustion Stirling engines is explained by the addition of thermal resistance of the combustion gasses to the standard Carnot model. In these cases,...The reported discrepancy between theory and experiment for external combustion Stirling engines is explained by the addition of thermal resistance of the combustion gasses to the standard Carnot model. In these cases, the Stirling engine ideal efficiency is not as is normally reported equal to the Carnot cycle efficiency but is significantly lower. A new equation for ideal Stirling engine efficiency when the heat is obtained through external combustion without pre-heating the air, is presented and results for various fuels tabulated. The results show that petrol and diesel, internal combustion engines (Otto cycle) have a higher ideal efficiency than the Stirling engine. When comparing thermoacoustic engines heated by wood, efficiency should not be quoted as a percentage of the Carnot efficiency, but against a figure 48% lower than Carnot. The effect is not seen with electrically heated rigs, solar or nuclear fission heated engines.展开更多
We applied the method of Thermomechanical Dynamics (TMD) to a low-temperature Stirling engine, and the dissipative equation of motion and time-evolving physical quantities are self-consistently calculated for the firs...We applied the method of Thermomechanical Dynamics (TMD) to a low-temperature Stirling engine, and the dissipative equation of motion and time-evolving physical quantities are self-consistently calculated for the first time in this field. The thermomechanical states of the heat engine are in Nonequilibrium Irreversible States (NISs), and time-dependent thermodynamic work W(t), internal energy E(t), energy dissipation or entropy Q<sub>d</sub>(t), and temperature T(t), are precisely studied and computed in TMD. We also introduced the new formalism, Q(t)-picture of thermodynamic heat-energy flows, for consistent analyses of NISs. Thermal flows in a long-time uniform heat flow and in a short-time heat flow are numerically studied as examples. In addition to the analysis of time-dependent physical quantities, the TMD analysis suggests that the concept of force and acceleration in Newtonian mechanics should be modified. The acceleration is defined as a continuously differentiable function of Class C<sup>2</sup> in Newtonian mechanics, but the thermomechanical dynamics demands piecewise continuity for acceleration and thermal force, required from physical reasons caused by frictional variations and thermal fluctuations. The acceleration has no direct physical meaning associated with force in TMD. The physical implications are fundamental for the concept of the macroscopic phenomena in NISs composed of systems in thermal and mechanical motion.展开更多
The purpose of carrying out present work is to design, build and test a rhombic drive Stirling engine with a β-type configuration consisting of two dynamic pistons (displacer and power) reciprocates in the in-line co...The purpose of carrying out present work is to design, build and test a rhombic drive Stirling engine with a β-type configuration consisting of two dynamic pistons (displacer and power) reciprocates in the in-line concentric cylinder arrangement. The displacement rod is assembled concentrically inside the power piston rod. The rhombic drive mechanism is proposed in such a way that, by using a pair of gear wheels the sliding motion of both piston rods is controlled and thus, an engine is balanced. The developed prototype has a swept volume of 75 cm<sup>3</sup> with the displacer piston and power piston cylinder hot ends heated by liquefied petroleum gas (LPG) burner and cooled water, respectively. It uses air as the working gas at atmospheric pressure for initial charging of the engine. Several designs were studied before settling on a β-type configuration. The LPG gas burner was considered as a potential heat source. The various elements of an engine (heater, cooler, re-generator, flywheel and piping systems) were designed, constructed and analyzed. The testing results revealed that the engine at initial atmospheric air filling started working in only about 120 seconds at an LPG heater temperature of 400℃ (824<sup>°</sup>F) with 280 rpm. At a heater temperature of 550℃ (1022<sup>°</sup>F), the engine speed was 630 rpm. At the engine speed of 245 rpm, the maximum torque was 0.215 Nm, while the maximum power was 8 Watts at 355 rpm. Engine speed increased with the increase of flame temperature. Several tests were performed on the engine to improve its running efficiency and critical problem areas were isolated and addressed. Moreover, results revealed that Stirling engines working with relatively low-temperature air are potentially attractive engines of the future, especially LPG powered low temperature differential Stirling engines. The Stirling engine was capable of generating between 50 to 100 Watts of electricity.展开更多
This paper analyzes the viability of a new microcogeneration system with a Stirling engine micro-CHP(combined heat and power)and renewable solar energy:thermal and photovoltaic system,using accumulation system for hot...This paper analyzes the viability of a new microcogeneration system with a Stirling engine micro-CHP(combined heat and power)and renewable solar energy:thermal and photovoltaic system,using accumulation system for hot water and ion lithium batteries for electricity.A weather station gives real meteorological parameters for Mediterranean climate(Málaga,Spain).A control unit permits to have a full automated system,which works according to a flowchart.This controller also allows theorizing a demand profile curve of daily consumption,typical for this or other climates.Many studies analyse different kinds of combined systems by simulating or making the real installation to obtain results for either microcogeneration or solar power,but not together,e.g.central heating applications to obtain a constant consumption of hot water.This new system shows a new combination of resources(natural gas in Stirling and solar energy systems),and the implementation allows doing experiments with different profiles of consumption to have real,non-theoretical,results.The control system is self-governing:it connects the different supplies of energy(solar thermal,photovoltaic,Stirling or batteries)depending on the demand,this demand can be changed by simulating any profile:domestic(heat and power),business,low thermal demand,low electricity demand,etc.展开更多
We analyze the performance of a quantum Stirling heat engine(QSHE), using a two-level system and a harmonic oscillator as the working medium, that is in contact with a squeezed thermal reservoir and a cold reservoir. ...We analyze the performance of a quantum Stirling heat engine(QSHE), using a two-level system and a harmonic oscillator as the working medium, that is in contact with a squeezed thermal reservoir and a cold reservoir. First, we derive closed-form expressions for the produced work and efficiency, which strongly depend on the squeezing parameter rh. Then, we prove that the effect of squeezing heats the working medium to a higher effective temperature, which leads to better overall performance. In particular, the efficiency increases with the degree of squeezing, surpassing the standard Carnot limit when the ratio of the temperatures of the hot and cold reservoirs is small. Furthermore, we derive the analytical expressions for the efficiency at maximum work and the maximum produced work in the high and low temperature regimes,and we find that at extreme temperatures the squeezing parameter rhdoes not affect the performance of the QSHE. Finally,the performance of the QSHE depends on the nature of the working medium.展开更多
A mathematical model that describes the relationship between structural parameters and operating parameters was established based on the structure of Stirling reversible heat engine by Schmidt analyses. The calculatio...A mathematical model that describes the relationship between structural parameters and operating parameters was established based on the structure of Stirling reversible heat engine by Schmidt analyses. The calculation formulas of output power and average temperature of Stirling reversible heat engine were deduced, which disclosed the relationship between average temperature and ultimate pressure. A set of theoretical calculation formula of Stirling reversible heat engine was explored by combining definition of efficiency of heat engine. Research results provide theoretical references to design of parts and control system of Stirling reversible heat eneine.展开更多
文摘A thermoelectric generation Stirling engine (TEG-Stirling engine) is discussed by employing a low temperature Stirling engine and the dissipative equation of motion derived from the method of thermomechanical dynamics (TMD). The results and mechanism of axial flux electromagnetic induction (AF-EMI) are applied to a low temperature Stirling engine, resulting in a TEG-Stirling engine. The method of TMD produced thermodynamically consistent and time-dependent physical quantities for the first time, such as internal energy ℰ(t), thermodynamic work Wth(t), the total entropy (heat dissipation) Qd(t)and measure or temperature of a nonequilibrium state T˜(t). The TMD analysis produced a lightweight mechanical system of TEG-Stirling engine which derives electric power from waste heat of temperature (40˚CT100˚C) by a thermoelectric conversion method. An optimal low rotational speed about 30θ′(t)/(2π)60(rpm) is found, applicable to devices for sustainable, clean energy technologies. The stability of a thermal state and angular rotations of TEG-Stirling engine are specifically shown by employing properties of nonequilibrium temperature T˜(t), which is also applied to study optimal fuel-injection and combustion timings of heat engines.
文摘The thermoelectric energy conversion technique by employing the Disk-Magnet Electromagnetic Induction (DM-EMI) is examined in detail, and possible applications to heat engines as one of the energy-harvesting technologies are discussed. The idea is induced by the analysis of thermomechanical dynamics (TMD) for a nonequilibrium irreversible thermodynamic system of heat engines, such as a drinking bird and a low temperature Stirling engine, resulting in thermoelectric energy generation different from conventional heat engines. The current thermoelectric energy conversion with DM-EMI can be applied to wide ranges of machines and temperature differences. The mechanism of DM-EMI energy converter is categorized as the axial flux generator (AFG), which is the reason why the technology is applicable to sensitive thermoelectric conversions. On the other hand, almost all the conventional turbines use the radius flux generator to extract huge electric power, which uses the radial flux generator (RFG). The axial flux generator is helpful for a low mechanoelectric energy conversion and activations of waste heat from macroscopic energy generators such as wind, geothermal, thermal, nuclear power plants and heat-dissipation lines. The technique of DM-EMI will contribute to solving environmental problems to maintain clean and sustainable energy as one of the energy harvesting technologies.
基金funded by the National Natural Science F oundation of China(No.52172205)。
文摘Zinc oxide(ZnO)serves as a crucial functional semiconductor with a wide direct bandgap of approximately 3.37 eV.Solvothermal reaction is commonly used in the synthesis of ZnO micro/nanostructures,given its low cost,simplicity,and easy implementation.Moreover,ZnO morphology engineering has become desirable through the alteration of minor conditions in the reaction process,particularly at room temperature.In this work,ZnO micro/nanostructures were synthesized in a solution by varying the amounts of the ammonia added at low temperatures(including room temperature).The formation of Zn^(2+)complexes by ammonia in the precursor regulated the reaction rate of the morphology engineering of ZnO,which resulted in various structures,such as nanoparticles,nanosheets,microflowers,and single crystals.Finally,the obtained ZnO was used in the optoelectronic application of ultraviolet detectors.
基金Yongxian Huang supported by Projects of Guangzhou Science and Technology Plan(2023A04J0409)。
文摘To accurately diagnosemisfire faults in automotive engines,we propose a Channel Attention Convolutional Model,specifically the Squeeze-and-Excitation Networks(SENET),for classifying engine vibration signals and precisely pinpointing misfire faults.In the experiment,we established a total of 11 distinct states,encompassing the engine’s normal state,single-cylinder misfire faults,and dual-cylinder misfire faults for different cylinders.Data collection was facilitated by a highly sensitive acceleration signal collector with a high sampling rate of 20,840Hz.The collected data were methodically divided into training and testing sets based on different experimental groups to ensure generalization and prevent overlap between the two sets.The results revealed that,with a vibration acceleration sequence of 1000 time steps(approximately 50 ms)as input,the SENET model achieved a misfire fault detection accuracy of 99.8%.For comparison,we also trained and tested several commonly used models,including Long Short-Term Memory(LSTM),Transformer,and Multi-Scale Residual Networks(MSRESNET),yielding accuracy rates of 84%,79%,and 95%,respectively.This underscores the superior accuracy of the SENET model in detecting engine misfire faults compared to other models.Furthermore,the F1 scores for each type of recognition in the SENET model surpassed 0.98,outperforming the baseline models.Our analysis indicated that the misclassified samples in the LSTM and Transformer models’predictions were primarily due to intra-class misidentifications between single-cylinder and dual-cylinder misfire scenarios.To delve deeper,we conducted a visual analysis of the features extracted by the LSTM and SENET models using T-distributed Stochastic Neighbor Embedding(T-SNE)technology.The findings revealed that,in the LSTMmodel,data points of the same type tended to cluster together with significant overlap.Conversely,in the SENET model,data points of various types were more widely and evenly dispersed,demonstrating its effectiveness in distinguishing between different fault types.
基金support of the National Natural Science Foundation of China(Grant No.22225801,22178217 and 22308216)supported by the Fundamental Research Funds for the Central Universities,conducted at Tongji University.
文摘Rechargeable magnesium batteries(RMBs)have been considered a promising“post lithium-ion battery”system to meet the rapidly increasing demand of the emerging electric vehicle and grid energy storage market.However,the sluggish diffusion kinetics of bivalent Mg^(2+)in the host material,related to the strong Coulomb effect between Mg^(2+)and host anion lattices,hinders their further development toward practical applications.Defect engineering,regarded as an effective strategy to break through the slow migration puzzle,has been validated in various cathode materials for RMBs.In this review,we first thoroughly understand the intrinsic mechanism of Mg^(2+)diffusion in cathode materials,from which the key factors affecting ion diffusion are further presented.Then,the positive effects of purposely introduced defects,including vacancy and doping,and the corresponding strategies for introducing various defects are discussed.The applications of defect engineering in cathode materials for RMBs with advanced electrochemical properties are also summarized.Finally,the existing challenges and future perspectives of defect engineering in cathode materials for the overall high-performance RMBs are described.
基金supported by the grants from University of Macao,China,Nos.MYRG2022-00221-ICMS(to YZ)and MYRG-CRG2022-00011-ICMS(to RW)the Natural Science Foundation of Guangdong Province,No.2023A1515010034(to YZ)。
文摘Ischemic stroke is a secondary cause of mortality worldwide,imposing considerable medical and economic burdens on society.Extracellular vesicles,serving as natural nanocarriers for drug delivery,exhibit excellent biocompatibility in vivo and have significant advantages in the management of ischemic stroke.However,the uncertain distribution and rapid clearance of extracellular vesicles impede their delivery efficiency.By utilizing membrane decoration or by encapsulating therapeutic cargo within extracellular vesicles,their delivery efficacy may be greatly improved.Furthermore,previous studies have indicated that microvesicles,a subset of large-sized extracellular vesicles,can transport mitochondria to neighboring cells,thereby aiding in the restoration of mitochondrial function post-ischemic stroke.Small extracellular vesicles have also demonstrated the capability to transfer mitochondrial components,such as proteins or deoxyribonucleic acid,or their sub-components,for extracellular vesicle-based ischemic stroke therapy.In this review,we undertake a comparative analysis of the isolation techniques employed for extracellular vesicles and present an overview of the current dominant extracellular vesicle modification methodologies.Given the complex facets of treating ischemic stroke,we also delineate various extracellular vesicle modification approaches which are suited to different facets of the treatment process.Moreover,given the burgeoning interest in mitochondrial delivery,we delved into the feasibility and existing research findings on the transportation of mitochondrial fractions or intact mitochondria through small extracellular vesicles and microvesicles to offer a fresh perspective on ischemic stroke therapy.
基金Under the auspices of National Natural Science Foundation of China(No.42293270)。
文摘Throughout the contemporary Chinese history of geography,geographical engineering has consistently played a pivotal role as a fundamental scientific activity.It possesses its distinct ontological basis and value orientation,rendering it inseparable from being merely a derivative of geographical science or technology.This paper defines geographical engineering and introduces its development history through the lens of Chinese geographical engineering praxises.Furthermore,it is highlighted the logical and functional consistency between the theory of human-earth system and the praxis of geographical engineering.Six modern cases of geographical engineering projects are presented in detail to demonstrate the points and characteristics of different types of modern geographical engineering.Geographical engineering serves as an engine for promoting integrated geography research,and in response to the challenge posed by fragmented geographies,this paper advocates for an urgent revitalization of geographical engineering.The feasibility of revitalizing geographical engineering is guaranteed because it aligns with China’s national strategies.
基金supported by the National Natural Science Foundation of China,Nos.82171363,82371381(to PL),82171458(to XJ)Key Research and Development Project of Shaa nxi Province,Nos.2024SF-YBXM-404(to KY)。
文摘Recent advances in research on extracellular vesicles have significantly enhanced their potential as therapeutic agents for neurological diseases.Owing to their therapeutic properties and ability to cross the blood–brain barrier,extracellular vesicles are recognized as promising drug delivery vehicles for various neurological conditions,including ischemic stroke,traumatic brain injury,neurodegenerative diseases,glioma,and psychosis.However,the clinical application of natural extracellular vesicles is hindered by their limited targeting ability and short clearance from the body.To address these limitations,multiple engineering strategies have been developed to enhance the targeting capabilities of extracellular vesicles,thereby enabling the delivery of therapeutic contents to specific tissues or cells.Therefore,this review aims to highlight the latest advancements in natural and targeting-engineered extracellular vesicles,exploring their applications in treating traumatic brain injury,ischemic stroke,Parkinson's disease,Alzheimer's disease,amyotrophic lateral sclerosis,glioma,and psychosis.Additionally,we summarized recent clinical trials involving extracellular vesicles and discussed the challenges and future prospects of using targeting-engineered extracellular vesicles for drug delivery in treating neurological diseases.This review offers new insights for developing highly targeted therapies in this field.
基金Supported by National Natural Science Foundation of China(Grant No.50877013)
文摘Transverse-flux with high efficiency has been applied in Stirling engine and permanent magnet synchronous linear generator system,however it is restricted for large application because of low and complex process.A novel type of cylindrical,non-overlapping,transverse-flux,and permanent-magnet linear motor(TFPLM) is investigated,furthermore,a high power factor and less process complexity structure research is developed.The impact of magnetic leakage factor on power factor is discussed,by using the Finite Element Analysis(FEA) model of stirling engine and TFPLM,an optimization method for electro-magnetic design of TFPLM is proposed based on magnetic leakage factor.The relation between power factor and structure parameter is investigated,and a structure parameter optimization method is proposed taking power factor maximum as a goal.At last,the test bench is founded,starting experimental and generating experimental are performed,and a good agreement of simulation and experimental is achieved.The power factor is improved and the process complexity is decreased.This research provides the instruction to design high-power factor permanent-magnet linear generator.
基金Supported by the Research Foundation of Science and Technology Department of Zhejiang Province(2009C21023).
文摘In this Letter we outline a dielectric multilayer spectrally selective filter designed for solar energy applications.The optical performance of this 78-layer interference filter constructed by TiOx and SiO_(2) is presented.A hybrid system combining photovoltaic cells with a solar-powered Stirling engine using the designed filter is analyzed.The calculated results show the advantages of this spectrally selective method for solar power generation.
基金Project supported by the National Natural Science Foundation of China (Grant No 10465003), the Natural bcience Poundation of Jiangxi Province, China. (Grant No 0412011) and Science Foundation of Jiangxi Education Bureau, China.
文摘Based on the state equation of an ideal quantum gas, the regenerative loss of a Stirling engine cycle working with an ideal quantum gas is calculated. Thermal efficiency of the cycle is derived. Furthermore, under the condition of quantum degeneracy, several special thermal efficiencies are discussed. Ratios of thermal efficiencies versus the temperature ratio and volume ratio of the cycle are made. It is found that the thermal efficiency of the cycle not only depends on high and low temperatures but also on maximum and minimum volumes. In a classical gas state the thermal efficiency of the cycle is equal to that of the Carnot cycle. In an ideal quantum gas state the thermal efficiency of the cycle is smaller than that of the Carnot cycle. This will be significant for deeper understanding of the gas Stirling engine cycle.
文摘The reported discrepancy between theory and experiment for external combustion Stirling engines is explained by the addition of thermal resistance of the combustion gasses to the standard Carnot model. In these cases, the Stirling engine ideal efficiency is not as is normally reported equal to the Carnot cycle efficiency but is significantly lower. A new equation for ideal Stirling engine efficiency when the heat is obtained through external combustion without pre-heating the air, is presented and results for various fuels tabulated. The results show that petrol and diesel, internal combustion engines (Otto cycle) have a higher ideal efficiency than the Stirling engine. When comparing thermoacoustic engines heated by wood, efficiency should not be quoted as a percentage of the Carnot efficiency, but against a figure 48% lower than Carnot. The effect is not seen with electrically heated rigs, solar or nuclear fission heated engines.
文摘We applied the method of Thermomechanical Dynamics (TMD) to a low-temperature Stirling engine, and the dissipative equation of motion and time-evolving physical quantities are self-consistently calculated for the first time in this field. The thermomechanical states of the heat engine are in Nonequilibrium Irreversible States (NISs), and time-dependent thermodynamic work W(t), internal energy E(t), energy dissipation or entropy Q<sub>d</sub>(t), and temperature T(t), are precisely studied and computed in TMD. We also introduced the new formalism, Q(t)-picture of thermodynamic heat-energy flows, for consistent analyses of NISs. Thermal flows in a long-time uniform heat flow and in a short-time heat flow are numerically studied as examples. In addition to the analysis of time-dependent physical quantities, the TMD analysis suggests that the concept of force and acceleration in Newtonian mechanics should be modified. The acceleration is defined as a continuously differentiable function of Class C<sup>2</sup> in Newtonian mechanics, but the thermomechanical dynamics demands piecewise continuity for acceleration and thermal force, required from physical reasons caused by frictional variations and thermal fluctuations. The acceleration has no direct physical meaning associated with force in TMD. The physical implications are fundamental for the concept of the macroscopic phenomena in NISs composed of systems in thermal and mechanical motion.
文摘The purpose of carrying out present work is to design, build and test a rhombic drive Stirling engine with a β-type configuration consisting of two dynamic pistons (displacer and power) reciprocates in the in-line concentric cylinder arrangement. The displacement rod is assembled concentrically inside the power piston rod. The rhombic drive mechanism is proposed in such a way that, by using a pair of gear wheels the sliding motion of both piston rods is controlled and thus, an engine is balanced. The developed prototype has a swept volume of 75 cm<sup>3</sup> with the displacer piston and power piston cylinder hot ends heated by liquefied petroleum gas (LPG) burner and cooled water, respectively. It uses air as the working gas at atmospheric pressure for initial charging of the engine. Several designs were studied before settling on a β-type configuration. The LPG gas burner was considered as a potential heat source. The various elements of an engine (heater, cooler, re-generator, flywheel and piping systems) were designed, constructed and analyzed. The testing results revealed that the engine at initial atmospheric air filling started working in only about 120 seconds at an LPG heater temperature of 400℃ (824<sup>°</sup>F) with 280 rpm. At a heater temperature of 550℃ (1022<sup>°</sup>F), the engine speed was 630 rpm. At the engine speed of 245 rpm, the maximum torque was 0.215 Nm, while the maximum power was 8 Watts at 355 rpm. Engine speed increased with the increase of flame temperature. Several tests were performed on the engine to improve its running efficiency and critical problem areas were isolated and addressed. Moreover, results revealed that Stirling engines working with relatively low-temperature air are potentially attractive engines of the future, especially LPG powered low temperature differential Stirling engines. The Stirling engine was capable of generating between 50 to 100 Watts of electricity.
文摘This paper analyzes the viability of a new microcogeneration system with a Stirling engine micro-CHP(combined heat and power)and renewable solar energy:thermal and photovoltaic system,using accumulation system for hot water and ion lithium batteries for electricity.A weather station gives real meteorological parameters for Mediterranean climate(Málaga,Spain).A control unit permits to have a full automated system,which works according to a flowchart.This controller also allows theorizing a demand profile curve of daily consumption,typical for this or other climates.Many studies analyse different kinds of combined systems by simulating or making the real installation to obtain results for either microcogeneration or solar power,but not together,e.g.central heating applications to obtain a constant consumption of hot water.This new system shows a new combination of resources(natural gas in Stirling and solar energy systems),and the implementation allows doing experiments with different profiles of consumption to have real,non-theoretical,results.The control system is self-governing:it connects the different supplies of energy(solar thermal,photovoltaic,Stirling or batteries)depending on the demand,this demand can be changed by simulating any profile:domestic(heat and power),business,low thermal demand,low electricity demand,etc.
文摘We analyze the performance of a quantum Stirling heat engine(QSHE), using a two-level system and a harmonic oscillator as the working medium, that is in contact with a squeezed thermal reservoir and a cold reservoir. First, we derive closed-form expressions for the produced work and efficiency, which strongly depend on the squeezing parameter rh. Then, we prove that the effect of squeezing heats the working medium to a higher effective temperature, which leads to better overall performance. In particular, the efficiency increases with the degree of squeezing, surpassing the standard Carnot limit when the ratio of the temperatures of the hot and cold reservoirs is small. Furthermore, we derive the analytical expressions for the efficiency at maximum work and the maximum produced work in the high and low temperature regimes,and we find that at extreme temperatures the squeezing parameter rhdoes not affect the performance of the QSHE. Finally,the performance of the QSHE depends on the nature of the working medium.
文摘A mathematical model that describes the relationship between structural parameters and operating parameters was established based on the structure of Stirling reversible heat engine by Schmidt analyses. The calculation formulas of output power and average temperature of Stirling reversible heat engine were deduced, which disclosed the relationship between average temperature and ultimate pressure. A set of theoretical calculation formula of Stirling reversible heat engine was explored by combining definition of efficiency of heat engine. Research results provide theoretical references to design of parts and control system of Stirling reversible heat eneine.