The rotating circular plate is widely used in mechanical engineering, meanwhile the plates are often in the electromagnetic field in modern industry with complex loads. In order to study the resonance of a rotating ci...The rotating circular plate is widely used in mechanical engineering, meanwhile the plates are often in the electromagnetic field in modern industry with complex loads. In order to study the resonance of a rotating circular plate under static loads in magnetic field, the nonlinear vibration equation about the spinning circular plate is derived according to Hamilton principle. The algebraic expression of the initial deflection and the magneto elastic forced disturbance differential equation are obtained through the application of Galerkin integral method. By mean of modified Multiple scale method, the strongly nonlinear amplitude-frequency response equation in steady state is established. The amplitude frequency characteristic curve and the relationship curve of amplitude changing with the static loads and the excitation force of the plate are obtained according to the numerical calculation. The influence of magnetic induction intensity, the speed of rotation and the static loads on the amplitude and the nonlinear characteristics of the spinning plate are analyzed. The proposed research provides the theory reference for the research of nonlinear resonance of rotating plates in engineering.展开更多
The nonlinear combined resonance problem of a ferromagnetic circular plate in a transverse alternating magnetic field is investigated. On the basis of the deformation potential energy, the strain potential energy, and...The nonlinear combined resonance problem of a ferromagnetic circular plate in a transverse alternating magnetic field is investigated. On the basis of the deformation potential energy, the strain potential energy, and the kinetic energy of the circular plate, the Hamilton principle is used to induce the magnetoelastic coupling transverse vibration dynamical equation of the ferromagnetic circular plate. Based on the basic electromagnetic theory, the expressions of the magnet force and the Lorenz force of the circular plate are presented. A displacement function satisfying clamped-edge combined with the Galerkin method is used to derive the Duffing vibration differential equation of the circular plate. The amplitude-frequency response equations of the system under various combined resonance forms are obtained by means of the multi-scale method, and the stability of the steady-state solutions is analyzed according to the Lyapunov theory. Through examples, the amplitude-frequency characteristic curves with different parameters, the amplitude of resonance varying with magnetic field intensity and excitation force, and the time-course response diagram, phase diagram, Poincar′e diagram of the system vibration are plotted, respectively. The effects of different parameters on the amplitude and stability of the system are discussed. The results show that the electromagnetic parameters have a significant effect on the multi-valued attribute and stability of the resonance solutions, and the system may exhibit complex nonlinear dynamical behavior including multi-period and quasi-periodic motion.展开更多
In this study,circular dichroism(CD)and molecular dynamics(MD)simulation were used to investigate the thermal unfolding pathway of staphylococcal enterotoxin B(SEB)at temperatures of 298–371 and 298–500 K,and the re...In this study,circular dichroism(CD)and molecular dynamics(MD)simulation were used to investigate the thermal unfolding pathway of staphylococcal enterotoxin B(SEB)at temperatures of 298–371 and 298–500 K,and the relationship between the experimental and simulation results were explored.Our computational findings on the secondary structure of SEB showed that at room temperature,the CD spectroscopic results were highly consistent with the MD results.Moreover,under heating conditions,the changing trends of helix,sheet and random coil obtained by CD spectral fitting were highly consistent with those obtained by MD.In order to gain a deeper understanding of the thermal stability mechanism of SEB,the MD trajectories were analyzed in terms of root mean square deviation(RMSD),secondary structure assignment(SSA),radius of gyration(R_(g)),free energy surfaces(FES),solvent-accessible surface area(SASA),hydrogen bonds and salt bridges.The results showed that at low heating temperature,domain Ⅰ without loops(omitting the mobile loop region)mainly relied on hydrophobic interaction to maintain its thermal stability,whereas the thermal stability of domain Ⅱ was mainly controlled by salt bridges and hydrogen bonds.Under high heating temperature conditions,the hydrophobic interactions in domain Ⅰ without loops were destroyed and the secondary structure was almost completely lost,while domain Ⅱ could still rely on salt bridges as molecular staples to barely maintain the stability of the secondary structure.These results help us to understand the thermodynamic and kinetic mechanisms that maintain the thermal stability of SEB at the molecular level,and provide a direction for establishing safer and more effective food sterilization processes.展开更多
The relativistic interaction of charged particle beams with a circularly polarized electromagnetic wave propagating along a uniform guiding magnetic field in the tunneling of a dielectric medium is analyzed. The accel...The relativistic interaction of charged particle beams with a circularly polarized electromagnetic wave propagating along a uniform guiding magnetic field in the tunneling of a dielectric medium is analyzed. The acceleration mechanism and a self-consistent nonlinear theory are presented for the interaction of relativistic charged particle beams with electromagnetic waves. Numerical results show that the beam particle can be efficiently accelerated in the interaction process.展开更多
Using the method of Picus and Beer invariants, general expressions are obtained for the total intensity I and the degree of circular polarization Рcirc.of the luminescence of GaAs-type semiconductors with the partici...Using the method of Picus and Beer invariants, general expressions are obtained for the total intensity I and the degree of circular polarization Рcirc.of the luminescence of GaAs-type semiconductors with the participation of shallow acceptor levels in a longitudinal magnetic field H. Special cases are analyzed depending on the value and direction of the magnetic field strength, as well as on the constants of the g-factor of the acceptor g1,g2and the conduction band electron ge. In the case of a strong magnetic field H// [100], [111], [110], a numerical calculation of the angular dependence of the quantities I and Рcirc.was performed for some critical values of g2/g1, at which Рcirc.exhibits a sharp anisotropy in the range from −100% to +100%, and the intensity of the crystal radiation along the magnetic field tends to a minimum value.展开更多
Electron magnetic circular dichroism opens a new door to explore magnetic properties by transmitted electrons in the transmission electron microscope. However, obtaining quantitative magnetic parameters, such as spin ...Electron magnetic circular dichroism opens a new door to explore magnetic properties by transmitted electrons in the transmission electron microscope. However, obtaining quantitative magnetic parameters, such as spin and orbital magnetic moment with element-specificity, goes a long way along with the development and improvement of this technique both in theoretical and experimental aspects. In this review, we will give a detailed description of the quantitative electron magnetic circular dichroism(EMCD) technique to measure magnetic parameters with spin-specificity, element-specificity,site-specificity, and orbital-spin-specificity. The discussion completely contains the procedures from raw experimental data acquisition to final magnetic parameters, together with the related custom code we have developed.展开更多
The configuration, magnetic field calculation and field distribution of the birdcage RF coil is pre-sented. This type of coil can produce a circular Polarized magnetic field. It has been widely used in the MRIsystem f...The configuration, magnetic field calculation and field distribution of the birdcage RF coil is pre-sented. This type of coil can produce a circular Polarized magnetic field. It has been widely used in the MRIsystem for head and whole-body imaging which can achive nearly optimal RF field uniformity and signal-to-noise ratio(SNR). The rnagnetic field is evenly distributed over the coil. The features of the birdcage coil areanalyzed on the basis of numerical simulation and experimental studies.展开更多
We report a theoretical scheme using a B-spline basis set to improve the poor computational accuracy of circular Rydberg states of hydrogen atoms in the intermediate magnetic field. This scheme can produce high accura...We report a theoretical scheme using a B-spline basis set to improve the poor computational accuracy of circular Rydberg states of hydrogen atoms in the intermediate magnetic field. This scheme can produce high accuracy energy levels and valid for an arbitrary magnetic field. Energy levels of hydrogen are presented for circular Rydberg states with azimuthal quantum numbers |m| =10-70 as a function of magnetic field strengths ranging from zero to 2.35 × 10^9 T. The variation of spatial distributions of electron probability densities with magnetic field strengths is discussed and competition between Coulomb and magnetic interactions is illustrated.展开更多
The application of Genetic Algorithm (GA) to the optimization of important parameters (Directivity, Radiated Power, Impedance etc.) of magnetically biased microstrip antenna, fabricated on ferrite substrate, is report...The application of Genetic Algorithm (GA) to the optimization of important parameters (Directivity, Radiated Power, Impedance etc.) of magnetically biased microstrip antenna, fabricated on ferrite substrate, is reported. The fitness functions for the GA program have been developed using cavity method for the analysis of microstrip antenna. The effect of external magnetic biasing has also been incorporated in the fitness function formulation as effective propagation constant. Using stochastic based search method of GA the common characteristics of electro-magnetic were entertained which cannot be handled by other optimization techniques. The genetic algorithm was run for 500 generations. The computed results are in good agreement with the results obtained experimentally.展开更多
The obvious circular dichroism(CD) and optical activity can be obtained based on the chiral metamaterial due to the plasmon-enhanced effect, which is very attractive for future compact devices with enhanced capabili...The obvious circular dichroism(CD) and optical activity can be obtained based on the chiral metamaterial due to the plasmon-enhanced effect, which is very attractive for future compact devices with enhanced capabilities of light manipulation. In this paper, we propose a dual-chiral metamaterial composed of bilayer asymmetric split ring resonators(ASRR)that are in mirror-symmetry shape. It is demonstrated that the CD can get enhancement in the terahertz regime. Moreover,the CD can be further improved by modulating the asymmetry of ASRR. The enhanced CD effect in the terahertz regime has great potential applications in sensing, biomedical imaging, and molecular recognition.展开更多
The interconnection of polarization and phase in electromagnetic scattering process has attracted both fundamental and practical interest.Here we propose the principle and experimental demonstration of a scatteringcon...The interconnection of polarization and phase in electromagnetic scattering process has attracted both fundamental and practical interest.Here we propose the principle and experimental demonstration of a scatteringcontrol mechanism based on the simultaneous control of polarization and phase via a continuously shaped planar metasurface.Under circularly polarized illumination,the scattering is redirected to off-specular direction,leading to significant reduction of the scattering cross section.Theoretical investigation shows that the underlying physical mechanism is the spin-dependent phase modulation in the anisotropic scattering process.Our approach would provide valuable guidance for the full control of electromagnetic wave for diverse applications.展开更多
A spacecraft loses all forms of communication, including global positioning system signals, data telemetry, voice communication and so on, when it enters the communication blackout phase. This becomes more and more cr...A spacecraft loses all forms of communication, including global positioning system signals, data telemetry, voice communication and so on, when it enters the communication blackout phase. This becomes more and more critical with the development of reentry vehicle missions since radio blackout brings about many serious issues related to vehicle safety. This paper studies the influence of magnetic field on antenna performance in plasma. The results indicate that the effect of plasma on the antenna performance can be negligible when the magnetic field reaches a certain strength. This provides another way to solve the reentry blackout problem.展开更多
Circular dichroism(CD)has shown very interesting possibilities as a means to characterize the chiral signal of a chiral structure.Here,we theoretically demonstrated enhanced and tunable CD in the visible light regime ...Circular dichroism(CD)has shown very interesting possibilities as a means to characterize the chiral signal of a chiral structure.Here,we theoretically demonstrated enhanced and tunable CD in the visible light regime using a composite structure consisting of a double-layer metal grating gaped by a dielectric waveguide layer.Based on the coupling of the waveguide modes and the localized plasmonic resonances,the CD could reach a maximum value as high as 0.52 at635 nm,which is four times higher than the CD value obtained in a conventional double-layer grating without the waveguide coupling effect.Furthermore,the spectral positions of the enhanced CD bands could be easily tuned by controlling the structural parameters.The proposed hybrid double-grating and waveguide structures could have potential applications in chiral selective imaging,sensing and spectroscopy,especially where the transmission measurement is required.展开更多
Researchers have long studied circular dichroism(CD) for its enormous prospects in life sciences. Many biomolecules have vibration modes in the terahertz region, and terahertz CD spectra are robust to detect biomolecu...Researchers have long studied circular dichroism(CD) for its enormous prospects in life sciences. Many biomolecules have vibration modes in the terahertz region, and terahertz CD spectra are robust to detect biomolecular structures. However,few studies explore the terahertz CD spectra on even natural materials due to technical challenges in both fields. Here, we report a setup of home-built terahertz time-domain spectroscopy to measure the polarization states of terahertz waves.By carefully measuring the transmission Jones matrix, we obtain terahertz CD spectra of α-lactose tablets and D-glucose tablets. Our results show that the terahertz CD spectra are sensitive to vibrational motions in biochemical compounds,which will find wide applications in biosensing and biomedical diagnostics.展开更多
Based on the starch hydrolysis reaction accelerated by microwave irradiation with α-amylase, the circular dichroism (CD) and secondary structure changes of α-amylase under the condition of microwave irradiation an...Based on the starch hydrolysis reaction accelerated by microwave irradiation with α-amylase, the circular dichroism (CD) and secondary structure changes of α-amylase under the condition of microwave irradiation and water bath were studied by circular dichroism spectra. The results showed that, both the peak heights (at 2=193 nm) of the CD spectra of the samples treated by microwave irradiation and water bath reduced. The reduced rate by microwave irradiation ranged from 140% to 220%, while the reduced rate by water bath ranged from 60% to 140%. The peak of the sample treated by microwave irradiation for 60 min disappeared at λ=193 nm, while the sample showed a wake peak by water bath. The peak position by microwave irradiation emerged a blue shift in the range of 5-8 nm at λ=204 nm and λ=220 nm, while it emerged in the range of 3-5 nm by water bath. With time going on, the microwave irradiation and water bath have prompted the secondary structure of α-helix, β-sheet, β-turn and the mutual transformations of random coil, but the trends were different.展开更多
Interaction of procainamide hydrochloride(PAH) with human serum albumin(HSA) is of great significance in understanding the pharmacokinetic and pharmacodynamic mechanisms of the drug. Multi-spectroscopic techniques...Interaction of procainamide hydrochloride(PAH) with human serum albumin(HSA) is of great significance in understanding the pharmacokinetic and pharmacodynamic mechanisms of the drug. Multi-spectroscopic techniques were used to investigate the binding mode of PAH to HSA and results revealed the presence of static type of quenching mechanism. The number of binding sites, binding constants and thermodynamic parameters were calculated. The results showed a spontaneous binding of PAH to HSA and hydrophobic interactions played a major role. In addition, the distance between PAH and the Trp–214 was estimated employing the F?rster's theory. Site marker competitive experiments indicated that the binding of PAH to HSA primarily took place in subdomain IIA(Sudlow's site I). The influence of interference of some common metal ions on the binding of PAH to HSA was studied. Synchronous fluorescence spectra(SFS), 3D fluorescence spectra and circular dichroism(CD) results indicated the conformational changes in the structure of HSA.展开更多
The effects of temperature,pH and long-term storage on the secondary structure and conformation changes of bovine haemoglobin(bHb) were studied using circular dichroism(CD) and ultraviolet-visible(UV-vis) spectr...The effects of temperature,pH and long-term storage on the secondary structure and conformation changes of bovine haemoglobin(bHb) were studied using circular dichroism(CD) and ultraviolet-visible(UV-vis) spectroscopies.Neural network software was used to deconvolute the CD data to obtain the fractional content of the five secondary structures.The storage stability of bHb solutions in pH 6,7 and8 buffers was significantly higher at 4 ℃ than at 23 ℃ for the first 3 days.A complete denaturation of bHb was observed after 40 days irrespective of storage temperature or pH.The bHb solutions were also exposed to heating and cooling cycles between 25 and 65 ℃ and structural changes were followed by UVvis and CD spectroscopies.These experiments demonstrated that α-helix content of bHb decreased steadily with the increasing temperature above 35 ℃ at all pH values.The loss in a-helicity and gain in random coil conformations was pH-dependent and the greatest under alkaline conditions.Furthermore,there was minimal recovery of the secondary structure content upon cooling to 25 ℃.The use of bHb as a model drug is very common and this study elucidates the significance of storage and processing conditions on its stability.展开更多
In human cells, the heterogeneous nuclear ribonucleoproteins (hnRNP) are represented by a group of polypeptides, with various molecular properties, comprizing the most abundant constituents of the cell nucleus. Autoan...In human cells, the heterogeneous nuclear ribonucleoproteins (hnRNP) are represented by a group of polypeptides, with various molecular properties, comprizing the most abundant constituents of the cell nucleus. Autoantibodies to hnRNPs have been reported in patients suffering from different rheumatic dieseases since 1980s. Experimental evidence indicates that hnRNP complexes undergo substantial structural changes during mRNA formation and export. However, how this contributes to disease development still has to be elucidated. Here some preliminary physicochemical features of RNA-protein folding and stability patterns of newly characterized hnRNP A3 with further functional implications in development of systemic human autoimmune states are reported.展开更多
The second-harmonic generation (SHG) circular dichroism in the light of reflection from chiral films of tripod-like chiral molecules is investigated. The expressions of the second-harmonic generation circular dichro...The second-harmonic generation (SHG) circular dichroism in the light of reflection from chiral films of tripod-like chiral molecules is investigated. The expressions of the second-harmonic generation circular dichroism are derived from our presented three-coupled-oscillator model for the tripod-like chiral molecules. Spectral dependence of the circular dichroism of SHG from film surface composed of tripod-like chiral molecules is simulated numerically and analysed. Influence of ehiral parameters on the second-harmonic generation circular dichroism spectrum in chiral films is studied. The result shows that the second-harmonic generation circular dichroism is a sensitive method of detecting chirality compared with the ordinary circular dichroism in linear optics. All of our work indicates that the classical molecular models are very effective to explain the second-harmonic generation circular dichroism of chiral molecular system. The classical molecular model theory can give us a clear physical picture and brings us very instructive information about the link between the molecular configuration and the nonlinear processes.展开更多
The circular dichroism(CD) signal of a molecule is usually weak,however,a strong CD signal in optical spectrum is desirable because of its wide range of applications in biosensing,chiral photo detection,and chiral cat...The circular dichroism(CD) signal of a molecule is usually weak,however,a strong CD signal in optical spectrum is desirable because of its wide range of applications in biosensing,chiral photo detection,and chiral catalysis.In this work,we show that a strong chiral response can be obtained in a hybridized system consisting of an artificial chiral molecule and a nanorod in the strong coupling regime.The artificial chiral molecule is composed of six quantum dots in a helix assembly,and its CD signal arises from internal Coulomb interactions between quantum dots.The CD signal of the hybridized system is highly dependent on the Coulomb interactions and the strong coupling progress through the electromagnetic interactions.We use the coupled oscillator model to analyze strong coupling phenomenon and address that the strong coupling progress can amplify the CD signal.This work provides a scenario for designing new plasmonic nanostructures with a strong chiral optical response.展开更多
基金Supported by National Natural Science Foundation of China(Grant No11472239)Hebei Provincial Natural Science Foundation of China(Grant No.A2015203023)Key Project of Science and Technology Research of Higher Education of Hebei Province of China(Grant No.ZD20131055)
文摘The rotating circular plate is widely used in mechanical engineering, meanwhile the plates are often in the electromagnetic field in modern industry with complex loads. In order to study the resonance of a rotating circular plate under static loads in magnetic field, the nonlinear vibration equation about the spinning circular plate is derived according to Hamilton principle. The algebraic expression of the initial deflection and the magneto elastic forced disturbance differential equation are obtained through the application of Galerkin integral method. By mean of modified Multiple scale method, the strongly nonlinear amplitude-frequency response equation in steady state is established. The amplitude frequency characteristic curve and the relationship curve of amplitude changing with the static loads and the excitation force of the plate are obtained according to the numerical calculation. The influence of magnetic induction intensity, the speed of rotation and the static loads on the amplitude and the nonlinear characteristics of the spinning plate are analyzed. The proposed research provides the theory reference for the research of nonlinear resonance of rotating plates in engineering.
基金Project supported by the National Natural Science Foundation of China(No.11472239)
文摘The nonlinear combined resonance problem of a ferromagnetic circular plate in a transverse alternating magnetic field is investigated. On the basis of the deformation potential energy, the strain potential energy, and the kinetic energy of the circular plate, the Hamilton principle is used to induce the magnetoelastic coupling transverse vibration dynamical equation of the ferromagnetic circular plate. Based on the basic electromagnetic theory, the expressions of the magnet force and the Lorenz force of the circular plate are presented. A displacement function satisfying clamped-edge combined with the Galerkin method is used to derive the Duffing vibration differential equation of the circular plate. The amplitude-frequency response equations of the system under various combined resonance forms are obtained by means of the multi-scale method, and the stability of the steady-state solutions is analyzed according to the Lyapunov theory. Through examples, the amplitude-frequency characteristic curves with different parameters, the amplitude of resonance varying with magnetic field intensity and excitation force, and the time-course response diagram, phase diagram, Poincar′e diagram of the system vibration are plotted, respectively. The effects of different parameters on the amplitude and stability of the system are discussed. The results show that the electromagnetic parameters have a significant effect on the multi-valued attribute and stability of the resonance solutions, and the system may exhibit complex nonlinear dynamical behavior including multi-period and quasi-periodic motion.
文摘In this study,circular dichroism(CD)and molecular dynamics(MD)simulation were used to investigate the thermal unfolding pathway of staphylococcal enterotoxin B(SEB)at temperatures of 298–371 and 298–500 K,and the relationship between the experimental and simulation results were explored.Our computational findings on the secondary structure of SEB showed that at room temperature,the CD spectroscopic results were highly consistent with the MD results.Moreover,under heating conditions,the changing trends of helix,sheet and random coil obtained by CD spectral fitting were highly consistent with those obtained by MD.In order to gain a deeper understanding of the thermal stability mechanism of SEB,the MD trajectories were analyzed in terms of root mean square deviation(RMSD),secondary structure assignment(SSA),radius of gyration(R_(g)),free energy surfaces(FES),solvent-accessible surface area(SASA),hydrogen bonds and salt bridges.The results showed that at low heating temperature,domain Ⅰ without loops(omitting the mobile loop region)mainly relied on hydrophobic interaction to maintain its thermal stability,whereas the thermal stability of domain Ⅱ was mainly controlled by salt bridges and hydrogen bonds.Under high heating temperature conditions,the hydrophobic interactions in domain Ⅰ without loops were destroyed and the secondary structure was almost completely lost,while domain Ⅱ could still rely on salt bridges as molecular staples to barely maintain the stability of the secondary structure.These results help us to understand the thermodynamic and kinetic mechanisms that maintain the thermal stability of SEB at the molecular level,and provide a direction for establishing safer and more effective food sterilization processes.
基金supported by National Natural Science Foundation of China(Nos.51275029,51102007 and 11275007)
文摘The relativistic interaction of charged particle beams with a circularly polarized electromagnetic wave propagating along a uniform guiding magnetic field in the tunneling of a dielectric medium is analyzed. The acceleration mechanism and a self-consistent nonlinear theory are presented for the interaction of relativistic charged particle beams with electromagnetic waves. Numerical results show that the beam particle can be efficiently accelerated in the interaction process.
文摘Using the method of Picus and Beer invariants, general expressions are obtained for the total intensity I and the degree of circular polarization Рcirc.of the luminescence of GaAs-type semiconductors with the participation of shallow acceptor levels in a longitudinal magnetic field H. Special cases are analyzed depending on the value and direction of the magnetic field strength, as well as on the constants of the g-factor of the acceptor g1,g2and the conduction band electron ge. In the case of a strong magnetic field H// [100], [111], [110], a numerical calculation of the angular dependence of the quantities I and Рcirc.was performed for some critical values of g2/g1, at which Рcirc.exhibits a sharp anisotropy in the range from −100% to +100%, and the intensity of the crystal radiation along the magnetic field tends to a minimum value.
文摘Electron magnetic circular dichroism opens a new door to explore magnetic properties by transmitted electrons in the transmission electron microscope. However, obtaining quantitative magnetic parameters, such as spin and orbital magnetic moment with element-specificity, goes a long way along with the development and improvement of this technique both in theoretical and experimental aspects. In this review, we will give a detailed description of the quantitative electron magnetic circular dichroism(EMCD) technique to measure magnetic parameters with spin-specificity, element-specificity,site-specificity, and orbital-spin-specificity. The discussion completely contains the procedures from raw experimental data acquisition to final magnetic parameters, together with the related custom code we have developed.
文摘The configuration, magnetic field calculation and field distribution of the birdcage RF coil is pre-sented. This type of coil can produce a circular Polarized magnetic field. It has been widely used in the MRIsystem for head and whole-body imaging which can achive nearly optimal RF field uniformity and signal-to-noise ratio(SNR). The rnagnetic field is evenly distributed over the coil. The features of the birdcage coil areanalyzed on the basis of numerical simulation and experimental studies.
基金Support from National Science Foundation of USA under Grant No. 0630370National Natural Science Foundation of China under Grant Nos. 90403028 and 11074260
文摘We report a theoretical scheme using a B-spline basis set to improve the poor computational accuracy of circular Rydberg states of hydrogen atoms in the intermediate magnetic field. This scheme can produce high accuracy energy levels and valid for an arbitrary magnetic field. Energy levels of hydrogen are presented for circular Rydberg states with azimuthal quantum numbers |m| =10-70 as a function of magnetic field strengths ranging from zero to 2.35 × 10^9 T. The variation of spatial distributions of electron probability densities with magnetic field strengths is discussed and competition between Coulomb and magnetic interactions is illustrated.
文摘The application of Genetic Algorithm (GA) to the optimization of important parameters (Directivity, Radiated Power, Impedance etc.) of magnetically biased microstrip antenna, fabricated on ferrite substrate, is reported. The fitness functions for the GA program have been developed using cavity method for the analysis of microstrip antenna. The effect of external magnetic biasing has also been incorporated in the fitness function formulation as effective propagation constant. Using stochastic based search method of GA the common characteristics of electro-magnetic were entertained which cannot be handled by other optimization techniques. The genetic algorithm was run for 500 generations. The computed results are in good agreement with the results obtained experimentally.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11174051,11374049,and 11204139)the Natural Science Foundation of Jiangsu Province of China(Grant No.BK20131283)the Fundamental Research Funds for the Central Universities,China
文摘The obvious circular dichroism(CD) and optical activity can be obtained based on the chiral metamaterial due to the plasmon-enhanced effect, which is very attractive for future compact devices with enhanced capabilities of light manipulation. In this paper, we propose a dual-chiral metamaterial composed of bilayer asymmetric split ring resonators(ASRR)that are in mirror-symmetry shape. It is demonstrated that the CD can get enhancement in the terahertz regime. Moreover,the CD can be further improved by modulating the asymmetry of ASRR. The enhanced CD effect in the terahertz regime has great potential applications in sensing, biomedical imaging, and molecular recognition.
基金the China Triumph International Engineering Co. Ltd.(CTIEC),Shanghai,China,which offers generous financial support for this work
文摘The interconnection of polarization and phase in electromagnetic scattering process has attracted both fundamental and practical interest.Here we propose the principle and experimental demonstration of a scatteringcontrol mechanism based on the simultaneous control of polarization and phase via a continuously shaped planar metasurface.Under circularly polarized illumination,the scattering is redirected to off-specular direction,leading to significant reduction of the scattering cross section.Theoretical investigation shows that the underlying physical mechanism is the spin-dependent phase modulation in the anisotropic scattering process.Our approach would provide valuable guidance for the full control of electromagnetic wave for diverse applications.
基金supported by National High Technology Research and Development Program of China(No.2011AA7022016)National Natural Science Foundation of China(No.11275045)the Sichuan Province Science and Technology Support Program of China(No.13ZC2317)
文摘A spacecraft loses all forms of communication, including global positioning system signals, data telemetry, voice communication and so on, when it enters the communication blackout phase. This becomes more and more critical with the development of reentry vehicle missions since radio blackout brings about many serious issues related to vehicle safety. This paper studies the influence of magnetic field on antenna performance in plasma. The results indicate that the effect of plasma on the antenna performance can be negligible when the magnetic field reaches a certain strength. This provides another way to solve the reentry blackout problem.
基金Project supported by the National Natural Science Foundation of China(Grant No.11474215)。
文摘Circular dichroism(CD)has shown very interesting possibilities as a means to characterize the chiral signal of a chiral structure.Here,we theoretically demonstrated enhanced and tunable CD in the visible light regime using a composite structure consisting of a double-layer metal grating gaped by a dielectric waveguide layer.Based on the coupling of the waveguide modes and the localized plasmonic resonances,the CD could reach a maximum value as high as 0.52 at635 nm,which is four times higher than the CD value obtained in a conventional double-layer grating without the waveguide coupling effect.Furthermore,the spectral positions of the enhanced CD bands could be easily tuned by controlling the structural parameters.The proposed hybrid double-grating and waveguide structures could have potential applications in chiral selective imaging,sensing and spectroscopy,especially where the transmission measurement is required.
基金Project supported by the National Natural Science Foundation of China (Grant No. 61775233)。
文摘Researchers have long studied circular dichroism(CD) for its enormous prospects in life sciences. Many biomolecules have vibration modes in the terahertz region, and terahertz CD spectra are robust to detect biomolecular structures. However,few studies explore the terahertz CD spectra on even natural materials due to technical challenges in both fields. Here, we report a setup of home-built terahertz time-domain spectroscopy to measure the polarization states of terahertz waves.By carefully measuring the transmission Jones matrix, we obtain terahertz CD spectra of α-lactose tablets and D-glucose tablets. Our results show that the terahertz CD spectra are sensitive to vibrational motions in biochemical compounds,which will find wide applications in biosensing and biomedical diagnostics.
基金Project(08A080) supported by the Scientific Research Fund of Hunan Provincial Education Department,China
文摘Based on the starch hydrolysis reaction accelerated by microwave irradiation with α-amylase, the circular dichroism (CD) and secondary structure changes of α-amylase under the condition of microwave irradiation and water bath were studied by circular dichroism spectra. The results showed that, both the peak heights (at 2=193 nm) of the CD spectra of the samples treated by microwave irradiation and water bath reduced. The reduced rate by microwave irradiation ranged from 140% to 220%, while the reduced rate by water bath ranged from 60% to 140%. The peak of the sample treated by microwave irradiation for 60 min disappeared at λ=193 nm, while the sample showed a wake peak by water bath. The peak position by microwave irradiation emerged a blue shift in the range of 5-8 nm at λ=204 nm and λ=220 nm, while it emerged in the range of 3-5 nm by water bath. With time going on, the microwave irradiation and water bath have prompted the secondary structure of α-helix, β-sheet, β-turn and the mutual transformations of random coil, but the trends were different.
文摘Interaction of procainamide hydrochloride(PAH) with human serum albumin(HSA) is of great significance in understanding the pharmacokinetic and pharmacodynamic mechanisms of the drug. Multi-spectroscopic techniques were used to investigate the binding mode of PAH to HSA and results revealed the presence of static type of quenching mechanism. The number of binding sites, binding constants and thermodynamic parameters were calculated. The results showed a spontaneous binding of PAH to HSA and hydrophobic interactions played a major role. In addition, the distance between PAH and the Trp–214 was estimated employing the F?rster's theory. Site marker competitive experiments indicated that the binding of PAH to HSA primarily took place in subdomain IIA(Sudlow's site I). The influence of interference of some common metal ions on the binding of PAH to HSA was studied. Synchronous fluorescence spectra(SFS), 3D fluorescence spectra and circular dichroism(CD) results indicated the conformational changes in the structure of HSA.
基金the University of Greenwich for financial support
文摘The effects of temperature,pH and long-term storage on the secondary structure and conformation changes of bovine haemoglobin(bHb) were studied using circular dichroism(CD) and ultraviolet-visible(UV-vis) spectroscopies.Neural network software was used to deconvolute the CD data to obtain the fractional content of the five secondary structures.The storage stability of bHb solutions in pH 6,7 and8 buffers was significantly higher at 4 ℃ than at 23 ℃ for the first 3 days.A complete denaturation of bHb was observed after 40 days irrespective of storage temperature or pH.The bHb solutions were also exposed to heating and cooling cycles between 25 and 65 ℃ and structural changes were followed by UVvis and CD spectroscopies.These experiments demonstrated that α-helix content of bHb decreased steadily with the increasing temperature above 35 ℃ at all pH values.The loss in a-helicity and gain in random coil conformations was pH-dependent and the greatest under alkaline conditions.Furthermore,there was minimal recovery of the secondary structure content upon cooling to 25 ℃.The use of bHb as a model drug is very common and this study elucidates the significance of storage and processing conditions on its stability.
文摘In human cells, the heterogeneous nuclear ribonucleoproteins (hnRNP) are represented by a group of polypeptides, with various molecular properties, comprizing the most abundant constituents of the cell nucleus. Autoantibodies to hnRNPs have been reported in patients suffering from different rheumatic dieseases since 1980s. Experimental evidence indicates that hnRNP complexes undergo substantial structural changes during mRNA formation and export. However, how this contributes to disease development still has to be elucidated. Here some preliminary physicochemical features of RNA-protein folding and stability patterns of newly characterized hnRNP A3 with further functional implications in development of systemic human autoimmune states are reported.
基金Project supported by the excellent Team in Harbin Institute of Technology,Chinathe Natural Science Foundation of Heilongjiang Province,China (Grant No. A200406)
文摘The second-harmonic generation (SHG) circular dichroism in the light of reflection from chiral films of tripod-like chiral molecules is investigated. The expressions of the second-harmonic generation circular dichroism are derived from our presented three-coupled-oscillator model for the tripod-like chiral molecules. Spectral dependence of the circular dichroism of SHG from film surface composed of tripod-like chiral molecules is simulated numerically and analysed. Influence of ehiral parameters on the second-harmonic generation circular dichroism spectrum in chiral films is studied. The result shows that the second-harmonic generation circular dichroism is a sensitive method of detecting chirality compared with the ordinary circular dichroism in linear optics. All of our work indicates that the classical molecular models are very effective to explain the second-harmonic generation circular dichroism of chiral molecular system. The classical molecular model theory can give us a clear physical picture and brings us very instructive information about the link between the molecular configuration and the nonlinear processes.
基金Project supported by the National Key R&D Program of China(Grant No.2016YFA0301300)the Fundamental Research Funds for the Central Universities,China(Grant No.2019XD-A09)the National Natural Science Foundation of China(Grant No.11574035)。
文摘The circular dichroism(CD) signal of a molecule is usually weak,however,a strong CD signal in optical spectrum is desirable because of its wide range of applications in biosensing,chiral photo detection,and chiral catalysis.In this work,we show that a strong chiral response can be obtained in a hybridized system consisting of an artificial chiral molecule and a nanorod in the strong coupling regime.The artificial chiral molecule is composed of six quantum dots in a helix assembly,and its CD signal arises from internal Coulomb interactions between quantum dots.The CD signal of the hybridized system is highly dependent on the Coulomb interactions and the strong coupling progress through the electromagnetic interactions.We use the coupled oscillator model to analyze strong coupling phenomenon and address that the strong coupling progress can amplify the CD signal.This work provides a scenario for designing new plasmonic nanostructures with a strong chiral optical response.