该试验以玉米、花生2∶4间作模式为对象,采用开顶式气室法控制环境CO_(2)浓度,于2018-2019年设环境CO_(2)浓度(Ca,390μmol·mol-1)和升高CO_(2)浓度(Ce,700μmol·mol-1),以及不施磷(P0)和施磷(180 kg P2O5·hm-2,P180)处...该试验以玉米、花生2∶4间作模式为对象,采用开顶式气室法控制环境CO_(2)浓度,于2018-2019年设环境CO_(2)浓度(Ca,390μmol·mol-1)和升高CO_(2)浓度(Ce,700μmol·mol-1),以及不施磷(P0)和施磷(180 kg P2O5·hm-2,P180)处理下,分析CO_(2)浓度升高对间作玉米和间作花生功能叶光合碳同化关键酶活性、净光合速率以及籽粒产量的影响,以明确CO_(2)浓度升高影响玉米、花生间作体系光合作用的机理,为将来CO_(2)浓度升高环境下间作高产高效提供理论基础。结果表明:(1)Ce处理提高了间作玉米功能叶的PEPC、PPDK、NADP-MDH、Rubisco、GAPDH和Ru5PK等光合碳同化酶活性,其中PEPC和NADP-MDH在苗后43 d以及PPDK、Rubisco、GAPDH和Ru5PK在苗后59 d增幅均达到显著水平,此时施磷对其有正向调控作用。(2)Ce处理增强了间作花生功能叶的Rubisco、GAPDH、Ru5PK和FBPase等光合碳同化酶活性,在苗后43 d和59 d增幅均达到显著水平,此时施磷进一步显著提高了Rubisco与FBPase活性。(3)Ce处理下间作玉米、间作花生的净光合速率显著提高,间作玉米、间作花生和间作体系的籽粒产量分别显著提高了4.4%~52.0%、10.3%~24.0%和5.7%~47.0%;CO_(2)浓度升高和施磷对间作玉米、花生功能叶的净光合速率和间作体系产量具有正协同效应。研究表明,CO_(2)浓度升高可以通过提高间作玉米功能叶片的PEPC、PPDK、Rubisco、GAPDH和Ru5PK及间作花生功能叶片的Rubisco、GAPDH、Ru5PK和FBPase等光合碳同化酶活性,增强其对CO_(2)羧化固定能力,提高间作玉米、间作花生的光合速率,最终显著增加玉米、花生及间作体系的产量,并且增施磷肥对其具有正调控效应。展开更多
Easy and hard magnetization curves of Nd_2Co_(14)B compound have been measured with extracting-sample-magnetometer(μ_0H_(max)=6T)at 10～300 K.Magnetic anisotropy constants K_1 and K_2 have been determined by fitting ...Easy and hard magnetization curves of Nd_2Co_(14)B compound have been measured with extracting-sample-magnetometer(μ_0H_(max)=6T)at 10～300 K.Magnetic anisotropy constants K_1 and K_2 have been determined by fitting the hard magnetization curves,in which only K_1 ,K_2 and misalignment angle have been taken as fitting parameters.The values of K_1 and K_2 at 4.2 K were derived by extrapolation. Anisotropy coefficients,x_2~° and x_4~°were derived from the anisotropy constants.The anisotropy constant K_2 increases rapidly with increasing temperature when T<T_(sr)and slowly when T>T_(sr).The temperature depen- dence of the magnetic anisotropy coefficient x_2~° was fitted with the formula.The anisotropy coefficients x_2~° can be well described by the tenth-power law from 4.2 K to T_(sr)and by the sixth-power law from T_(sr_ to 300 K.展开更多
Chemical fixation of carbon dioxide(CO_(2))is an energy-saving method for alleviating the greenhouse gas emissions,whereas it persists a challenge posed by the demand for efficient catalysts.Herein,four unprecedented ...Chemical fixation of carbon dioxide(CO_(2))is an energy-saving method for alleviating the greenhouse gas emissions,whereas it persists a challenge posed by the demand for efficient catalysts.Herein,four unprecedented examples of tetradecanuclear vanadium clusters,namely,[(C_(2)H_(8)N_(2))6(CH_(3)O)8(CH_(3)OH)_(2)V_(10)^(Ⅳ)V_(4)ⅤO_(26)](V_(14)-1),[(C_(3)H_(10)N_(2))_(6)(CH_(3)O)_(8)(CH_(3)OH)_(2)V_(10)^(Ⅳ)V_(4)ⅤO_(26)](V14^(-2)),[(C_(6)H_(14)N_(2))6(CH_(3)O)8(CH_(3)OH)_(2)V_(10)^(Ⅳ)V_(4)ⅤO_(26)]·5H_(2)O(V14^(-3))and[(C_(4)H_(12)N_(2)O)_(4)(C_(4)H_(11)N_(2)O)_(2)(CH_(3)O)_(2)V_(10)^(Ⅳ)V_(4)ⅤO_(28)]·6H_(2)O(V_(14)-4),have been triumphantly designed and constructed under solvothermal conditions.Among them,compounds V_(14)-1–4 are the first cases of tetradecanuclear vanadium clusters without the introduction of inorganic acid radical ions.Two main units[V_(10)^(Ⅳ)V_(4)ⅤO_(26)]8+and[V10ⅣV4ⅤO28]4+represent brand-new configurations of tetradecanuclear vanadium clusters.Given the fact that the presence of V^(Ⅳ)/V^(Ⅴ)can potentially facilitate electron transfer and consequently expedite catalytic reactions,we explored the catalytic activities of these compounds.Remarkably,V_(14)-1 was further used as a heterogeneous catalyst in the CO_(2)fixation into cyclic carbonates under milder conditions(60℃,0.5 MPa)and exhibited higher catalytic activity.Also,the experimental results indicated that V_(14)-1 could efficiently catalyze the sulfoxidation,which could fully convert most sulfides within 40 min at room temperature.Moreover,as a stable heterogeneous catalyst employed in CO_(2)fixation with epoxides and oxidation of sulfides,V_(14)-1 could be consecutively used multiple cycles without losing its catalytic activity.展开更多
基金This work has been supported by the National Natural Science Foundation of P.R.China(5870025)Magnetism Laboratory of Institute of Physics,Beijing,P.R.China.
文摘Easy and hard magnetization curves of Nd_2Co_(14)B compound have been measured with extracting-sample-magnetometer(μ_0H_(max)=6T)at 10～300 K.Magnetic anisotropy constants K_1 and K_2 have been determined by fitting the hard magnetization curves,in which only K_1 ,K_2 and misalignment angle have been taken as fitting parameters.The values of K_1 and K_2 at 4.2 K were derived by extrapolation. Anisotropy coefficients,x_2~° and x_4~°were derived from the anisotropy constants.The anisotropy constant K_2 increases rapidly with increasing temperature when T<T_(sr)and slowly when T>T_(sr).The temperature depen- dence of the magnetic anisotropy coefficient x_2~° was fitted with the formula.The anisotropy coefficients x_2~° can be well described by the tenth-power law from 4.2 K to T_(sr)and by the sixth-power law from T_(sr_ to 300 K.
基金supported by the Natural Science Foundation of Jiangsu(BK20191359)the National Natural Science Foundation of China(92161109)+1 种基金the Postgraduate Research&Practice Innovation Program of Jiangsu Province(KYCX22_1343)the Social Science Foundation of Jiangsu(19TQB002)。
文摘Chemical fixation of carbon dioxide(CO_(2))is an energy-saving method for alleviating the greenhouse gas emissions,whereas it persists a challenge posed by the demand for efficient catalysts.Herein,four unprecedented examples of tetradecanuclear vanadium clusters,namely,[(C_(2)H_(8)N_(2))6(CH_(3)O)8(CH_(3)OH)_(2)V_(10)^(Ⅳ)V_(4)ⅤO_(26)](V_(14)-1),[(C_(3)H_(10)N_(2))_(6)(CH_(3)O)_(8)(CH_(3)OH)_(2)V_(10)^(Ⅳ)V_(4)ⅤO_(26)](V14^(-2)),[(C_(6)H_(14)N_(2))6(CH_(3)O)8(CH_(3)OH)_(2)V_(10)^(Ⅳ)V_(4)ⅤO_(26)]·5H_(2)O(V14^(-3))and[(C_(4)H_(12)N_(2)O)_(4)(C_(4)H_(11)N_(2)O)_(2)(CH_(3)O)_(2)V_(10)^(Ⅳ)V_(4)ⅤO_(28)]·6H_(2)O(V_(14)-4),have been triumphantly designed and constructed under solvothermal conditions.Among them,compounds V_(14)-1–4 are the first cases of tetradecanuclear vanadium clusters without the introduction of inorganic acid radical ions.Two main units[V_(10)^(Ⅳ)V_(4)ⅤO_(26)]8+and[V10ⅣV4ⅤO28]4+represent brand-new configurations of tetradecanuclear vanadium clusters.Given the fact that the presence of V^(Ⅳ)/V^(Ⅴ)can potentially facilitate electron transfer and consequently expedite catalytic reactions,we explored the catalytic activities of these compounds.Remarkably,V_(14)-1 was further used as a heterogeneous catalyst in the CO_(2)fixation into cyclic carbonates under milder conditions(60℃,0.5 MPa)and exhibited higher catalytic activity.Also,the experimental results indicated that V_(14)-1 could efficiently catalyze the sulfoxidation,which could fully convert most sulfides within 40 min at room temperature.Moreover,as a stable heterogeneous catalyst employed in CO_(2)fixation with epoxides and oxidation of sulfides,V_(14)-1 could be consecutively used multiple cycles without losing its catalytic activity.
