This paper aims to gain insight into Laoyemiao (LYM) tectonic features and utilizes the tectonic-hydrocarbon accumulation model by integrated analysis tectonic controls on suitable reservoirs, trap styles, and hydro...This paper aims to gain insight into Laoyemiao (LYM) tectonic features and utilizes the tectonic-hydrocarbon accumulation model by integrated analysis tectonic controls on suitable reservoirs, trap styles, and hydrocarbon migration. On the basis of 3-D seismic data interpretation and the Xi'nanzhuang (XNZ) Fault geometry analysis, it has been assessed that the LYM tectonics is essentially a transverse anticline produced by flexure of the XNZ Fault surface and superimposed by Neocene north-east-trending strike-slip faults. Transverse anticline is found to exert controls both on major sediment transportation pathways and sedimentary facies distribution. Fan-delta plains that accumulated on the anticline crest near the XNZ Fault scrap and fan-delta front on the anticline front and the upper part of both limbs slumps on synclines and the Linque subsag. In combination with the reservoir properties, suitable reservoirs are predicted in the subfacies of subaqueous distributary channel and mouth bar deposited on the anticline crest. The LYM-faulted anticline accounts for the following trap groups: faulted-block and anticline-dominated trap, fault-dominated traps, and combined and stratigraphic traps. Evidence from biomarkers of crude oil and hydrocarbon-filling period simultaneous, or a little later to the strike-slip fault activity, reveal that the strike.slip faults penetrating into the deep source rock, by connecting with shallow reservoirs, provide the major hydrocarbon migration pathways.展开更多
In order to shorten the evaluation cycle of cobalt catalyst before the optimized catalyst is fixed on, a mathematical method is proposed to calculate weight percentage of C5+ hydrocarbons. Based on the carbide polyme...In order to shorten the evaluation cycle of cobalt catalyst before the optimized catalyst is fixed on, a mathematical method is proposed to calculate weight percentage of C5+ hydrocarbons. Based on the carbide polymerization mechanism and the main hydrocarbons being linear alkanes and α-olefins, the correlation between hydrocarbon distribution and the molecular mass ratio of water to hydrocarbons is discussed. The result shows the ratio was within the range of 1.125-1.286 and the lower the ratio, the more gaseous hydrocarbons were obtained. Moreover, a linear equation between the weight percentage of C5+ hydrocarbons and the weight ratio of C5+ hydrocarbons to the total water is established. These results are validated by corresponding experiments. The weight percentage of C5+ hydrocarbons could be immediately calculated by this linear equation without detailed gas chromatography (GC) analysis of them.展开更多
Nanpu sag lies in the northwest part of the Bohai bay basin.Laoyemiao structural zone is located in the northwest part of the sag,to the north bound by basin-bounding master fault-Xi’nanzhuang fault (XNZF).This paper...Nanpu sag lies in the northwest part of the Bohai bay basin.Laoyemiao structural zone is located in the northwest part of the sag,to the north bound by basin-bounding master fault-Xi’nanzhuang fault (XNZF).This paper aims to gain insight into Laoyemiao tectonic features and set up its tectonic -hydrocarbon accumulation model by展开更多
Sulfate rocks and organic sulfur from sedimentary organic matter are conventionally assumed as the original sulfur sources for hydrogen sulfide (H2S) in oil and gas reservoirs. However, a few recent experiments prel...Sulfate rocks and organic sulfur from sedimentary organic matter are conventionally assumed as the original sulfur sources for hydrogen sulfide (H2S) in oil and gas reservoirs. However, a few recent experiments preliminarily indicate that the association of pyrite and hydrocarbons may also have implications for H2S generation, in which water effects and natural controls on the evolution of pyrite sulfur into OSCs and H2S have not been evaluated. In this study, laboratory experiments were conducted from 200 to 450°C to investigate chemical interactions between pyrite and hydrocarbons under hydrothermal conditions. Based on the experimental results, preliminary mechanism and geochemical implications were tentatively discussed. Results of the experiments showed that decomposition of pyrite produced H2S and thiophenes at as low as 330°C in the presence of water and n-pentane. High concentrations of H2S were generated above 450°C under closed pyrolysis conditions no matter whether there is water in the designed experiments. However, much more organic sulfur compounds (OSCs) were formed in the hydrous pyrolysis than in anhydrous pyrolysis. Generally, most of sulfur liberated from pyrite at elevated temperatures was converted to H2S. Water was beneficial to breakdown of pyrite and to decomposition of alkanes into olefins but not essential to formation of large amounts of H2S, given the main hydrogen source derived from hydrocarbons. In addition, cracking of pyrite in the presence of 1-octene under hydrous conditions was found to proceed at 200°C, producing thiols and alkyl sulfides. Unsaturated hydrocarbons would be more reactive intermediates involved in the breakdown of pyrite than alkanes. The geochemistry of OSCs is actually controlled by various geochemical factors such as thermal maturity and the carbon chain length of the alkanes. This study indicates that the scale of H2S gas generated in deep buried carbonate reservoirs via interactions between pyrite and natural gas should be much smaller than that of thermochemical sulfate reduction (TSR) due to the scarcity of pyrite in carbonate reservoirs and the limited amount of long-chained hydrocarbons in natural gas. Nevertheless, in some cases, OSCs and/or low contents of H2S found in deep buried reservoirs may be associated with the deposited pyrite-bearing rock and organic matters (hydrocarbons), which still needs further investigation.展开更多
The analyses of light hydrocarbons in oils from the Tarim Basin show that the Man-go’s parameter K is about unity except those oils trapped in the eastern part of the Tazhong (Central Tarim) Fault Uplift. The regular...The analyses of light hydrocarbons in oils from the Tarim Basin show that the Man-go’s parameter K is about unity except those oils trapped in the eastern part of the Tazhong (Central Tarim) Fault Uplift. The regular variance of K may indicates the accumulation and admixture of the oil populations in the eastern part of the Tazhong Fault Uplift.展开更多
The density and interfacial tension of nitrogen-hydrocarbon binary systems were measured at the temperature of40℃ over a wide range of pressures from 0.101 to 40 MPa.Measurements were made on the followinghydrocarbon...The density and interfacial tension of nitrogen-hydrocarbon binary systems were measured at the temperature of40℃ over a wide range of pressures from 0.101 to 40 MPa.Measurements were made on the followinghydrocarbons with nitrogen:n-pentane.n-hexane.n-heptane,n-octane,n-decane and toluene.Comparisons madebetween data obtained from these systems and those from the literature at 0.101 MPa and 40℃ show goodagreement and consistency.展开更多
When considering the usage of ionic liquids(ILs)for reactions and separations involving non-polar or weak-polar hydrocarbons,the knowledge of the mutual solubility behaviors of ILs and hydrocarbons is of the utmost im...When considering the usage of ionic liquids(ILs)for reactions and separations involving non-polar or weak-polar hydrocarbons,the knowledge of the mutual solubility behaviors of ILs and hydrocarbons is of the utmost importance.In this work,taking four typical C6-hydrocarbons namely benzene,cyclohexene,cyclohexane,and hexane as representatives,the mutual solubility of ILs and non-polar or weak-polar hydrocarbons are systematically studied based on the COSMO-RS model.The reliability of COSMO-RS for these systems is first evaluated by comparing experimental and predicted hydrocarbon-in-IL activity coefficient at infinite dilution and binary/ternary liquid-liquid equilibria of related systems.Then,the mutual solubility of the four hydrocarbons and13,650 ILs(composed by 210 cations and 65 anions)are predicted.The effect of different IL structural characteristics including alkyl chain length,cation family/symmetry/functional group,and anion on the IL-hydrocarbon mutual solubility behaviors are further analyzed by the analyses of interaction energy and screen charge distribution.The mutual solubility databases and the structural effects identified thereon could provide useful guidance for IL selection in related applications.展开更多
文摘This paper aims to gain insight into Laoyemiao (LYM) tectonic features and utilizes the tectonic-hydrocarbon accumulation model by integrated analysis tectonic controls on suitable reservoirs, trap styles, and hydrocarbon migration. On the basis of 3-D seismic data interpretation and the Xi'nanzhuang (XNZ) Fault geometry analysis, it has been assessed that the LYM tectonics is essentially a transverse anticline produced by flexure of the XNZ Fault surface and superimposed by Neocene north-east-trending strike-slip faults. Transverse anticline is found to exert controls both on major sediment transportation pathways and sedimentary facies distribution. Fan-delta plains that accumulated on the anticline crest near the XNZ Fault scrap and fan-delta front on the anticline front and the upper part of both limbs slumps on synclines and the Linque subsag. In combination with the reservoir properties, suitable reservoirs are predicted in the subfacies of subaqueous distributary channel and mouth bar deposited on the anticline crest. The LYM-faulted anticline accounts for the following trap groups: faulted-block and anticline-dominated trap, fault-dominated traps, and combined and stratigraphic traps. Evidence from biomarkers of crude oil and hydrocarbon-filling period simultaneous, or a little later to the strike-slip fault activity, reveal that the strike.slip faults penetrating into the deep source rock, by connecting with shallow reservoirs, provide the major hydrocarbon migration pathways.
基金supported by the Shanghai Research Institute of Petrochemical Technology,SINOPEC
文摘In order to shorten the evaluation cycle of cobalt catalyst before the optimized catalyst is fixed on, a mathematical method is proposed to calculate weight percentage of C5+ hydrocarbons. Based on the carbide polymerization mechanism and the main hydrocarbons being linear alkanes and α-olefins, the correlation between hydrocarbon distribution and the molecular mass ratio of water to hydrocarbons is discussed. The result shows the ratio was within the range of 1.125-1.286 and the lower the ratio, the more gaseous hydrocarbons were obtained. Moreover, a linear equation between the weight percentage of C5+ hydrocarbons and the weight ratio of C5+ hydrocarbons to the total water is established. These results are validated by corresponding experiments. The weight percentage of C5+ hydrocarbons could be immediately calculated by this linear equation without detailed gas chromatography (GC) analysis of them.
文摘Nanpu sag lies in the northwest part of the Bohai bay basin.Laoyemiao structural zone is located in the northwest part of the sag,to the north bound by basin-bounding master fault-Xi’nanzhuang fault (XNZF).This paper aims to gain insight into Laoyemiao tectonic features and set up its tectonic -hydrocarbon accumulation model by
基金the National Natural Science Foundations of China(No.41472095 and No.40902034)the Foundation of State Key Laboratory of Petroleum Resources and Prospecting,China University of Petroleum,Beijing(No.PRP/open-1508)PetroChina Innovation Foundation(No.2012D-5006-0104)
文摘Sulfate rocks and organic sulfur from sedimentary organic matter are conventionally assumed as the original sulfur sources for hydrogen sulfide (H2S) in oil and gas reservoirs. However, a few recent experiments preliminarily indicate that the association of pyrite and hydrocarbons may also have implications for H2S generation, in which water effects and natural controls on the evolution of pyrite sulfur into OSCs and H2S have not been evaluated. In this study, laboratory experiments were conducted from 200 to 450°C to investigate chemical interactions between pyrite and hydrocarbons under hydrothermal conditions. Based on the experimental results, preliminary mechanism and geochemical implications were tentatively discussed. Results of the experiments showed that decomposition of pyrite produced H2S and thiophenes at as low as 330°C in the presence of water and n-pentane. High concentrations of H2S were generated above 450°C under closed pyrolysis conditions no matter whether there is water in the designed experiments. However, much more organic sulfur compounds (OSCs) were formed in the hydrous pyrolysis than in anhydrous pyrolysis. Generally, most of sulfur liberated from pyrite at elevated temperatures was converted to H2S. Water was beneficial to breakdown of pyrite and to decomposition of alkanes into olefins but not essential to formation of large amounts of H2S, given the main hydrogen source derived from hydrocarbons. In addition, cracking of pyrite in the presence of 1-octene under hydrous conditions was found to proceed at 200°C, producing thiols and alkyl sulfides. Unsaturated hydrocarbons would be more reactive intermediates involved in the breakdown of pyrite than alkanes. The geochemistry of OSCs is actually controlled by various geochemical factors such as thermal maturity and the carbon chain length of the alkanes. This study indicates that the scale of H2S gas generated in deep buried carbonate reservoirs via interactions between pyrite and natural gas should be much smaller than that of thermochemical sulfate reduction (TSR) due to the scarcity of pyrite in carbonate reservoirs and the limited amount of long-chained hydrocarbons in natural gas. Nevertheless, in some cases, OSCs and/or low contents of H2S found in deep buried reservoirs may be associated with the deposited pyrite-bearing rock and organic matters (hydrocarbons), which still needs further investigation.
文摘The analyses of light hydrocarbons in oils from the Tarim Basin show that the Man-go’s parameter K is about unity except those oils trapped in the eastern part of the Tazhong (Central Tarim) Fault Uplift. The regular variance of K may indicates the accumulation and admixture of the oil populations in the eastern part of the Tazhong Fault Uplift.
文摘The density and interfacial tension of nitrogen-hydrocarbon binary systems were measured at the temperature of40℃ over a wide range of pressures from 0.101 to 40 MPa.Measurements were made on the followinghydrocarbons with nitrogen:n-pentane.n-hexane.n-heptane,n-octane,n-decane and toluene.Comparisons madebetween data obtained from these systems and those from the literature at 0.101 MPa and 40℃ show goodagreement and consistency.
基金The financial support from the National Natural Science Foundation of China(22278134)
文摘When considering the usage of ionic liquids(ILs)for reactions and separations involving non-polar or weak-polar hydrocarbons,the knowledge of the mutual solubility behaviors of ILs and hydrocarbons is of the utmost importance.In this work,taking four typical C6-hydrocarbons namely benzene,cyclohexene,cyclohexane,and hexane as representatives,the mutual solubility of ILs and non-polar or weak-polar hydrocarbons are systematically studied based on the COSMO-RS model.The reliability of COSMO-RS for these systems is first evaluated by comparing experimental and predicted hydrocarbon-in-IL activity coefficient at infinite dilution and binary/ternary liquid-liquid equilibria of related systems.Then,the mutual solubility of the four hydrocarbons and13,650 ILs(composed by 210 cations and 65 anions)are predicted.The effect of different IL structural characteristics including alkyl chain length,cation family/symmetry/functional group,and anion on the IL-hydrocarbon mutual solubility behaviors are further analyzed by the analyses of interaction energy and screen charge distribution.The mutual solubility databases and the structural effects identified thereon could provide useful guidance for IL selection in related applications.