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The Effect of Temperature Variation on Dyeing Tie-Dye Cotton Fabrics Dyed with Reactive Dye
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作者 Ummelewara Bristi 《Journal of Textile Science and Technology》 2018年第4期117-128,共12页
The improvement of colorfastness properties of tie dyed cotton knit fabrics with reactive dye has been studied. Pretreated cotton knit fabric is use to dyeing for easy absorption and retention of dye. Color fastness p... The improvement of colorfastness properties of tie dyed cotton knit fabrics with reactive dye has been studied. Pretreated cotton knit fabric is use to dyeing for easy absorption and retention of dye. Color fastness properties of any dyed fabric are very important aspects as the end use of fabric depends on these properties. This study is to evaluate the color fastness to washing and perspiration using the method ISO 105-2CS:2002 and ISO105-E04. The fabric is dyed with reactive dye in same concentration but in two different temperature (30&#176;C and 60&#176;C) and with different amount of sodium carbonate (15 g/l, 18 g/l and 20 g/l) respectively. It is observed that the increasing temperature and using related amount of sodium carbonate the fabric absorbs more dye. In 30&#176;C temperature the result of washing fastness is fairly good to very good where in 60&#176;C the result is very good to excellent. Perspiration fastness result is fairly good to very good both in 30&#176;C and 60&#176;C temperature. The result shows very good of all washing and perspiration fastness in 20 g/l sodium carbonate. The result is concluded that the color fastness of tie-dyed samples is improved by the increasing of temperature and higher amount of sodium carbonate. 展开更多
关键词 Tie-dyed COTTON FABRIC REACTIVE DYE Colorfastness Temperature
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Comparison of Seam Strength between Dyed and Un-Dyed Gabardine Apparels: A Research on Lapped &Superimposed Seam
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作者 Kaniz Farhana Md. Syduzzaman Dilruba Yeasmin 《Journal of Textile Science and Technology》 2015年第2期75-84,共10页
Today is the golden age of fashion. Fashion garments and apparels have been used everywhere to cope with the fashion era. These fashion garments and apparels are made of the fabrics of various structures and component... Today is the golden age of fashion. Fashion garments and apparels have been used everywhere to cope with the fashion era. These fashion garments and apparels are made of the fabrics of various structures and components through various processes. Among them gabardine is one of the most remarkable type of fabric and apparel dyeing is the latest process used for fashion apparel. From this research, the seam strength variations between dyed and un-dyed gabardine apparels after conceding the garment dyeing process can be known. It is a comparative research work which will deliver very effective knowledge about various types of seam, seam strength and seam performance. For comparative study, many dummy apparels body have been produced as samples which are dyed in Hams washing and dyeing limited. After that all samples have tested in Thermax woven dyeing laboratory. Since Bangladesh is a very potential fashion market and the fashion garments are being manufactured more and more. Hence the fashion trend is rapidly going to garments dyeing from conventional fabric/yarn dyeing processes. Gradually garments dyeing order are increasing higher to higher. 展开更多
关键词 SEAM SEAM Strength GABARDINE APPAREL Dyed APPAREL Un-dyed APPAREL APPAREL DYEING
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CHEMOSELECTIVE PREPARATION OF CHLOROSULFONYL-CONTAINING AZO-DYES WITH THIONYL CHLORIDE-N,N-DIMETHYLFORMAMIDE
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作者 汤立军 张淑芬 +2 位作者 崔志华 杨锦宗 高文涛 《化工学报》 EI CAS CSCD 北大核心 2004年第1期168-170,共3页
关键词 含磺酰氯基偶氮染料 化学合成 选择性合成 简便方法 吡唑啉酮
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Adsorption of Natural Aluminium Dye Complex from Silk-Dyeing Effluent Using Eucalyptus Wood Activated Carbon
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作者 Saowanee Chuyingsakuntip Chaiyot Tangsathitkulchai 《American Journal of Analytical Chemistry》 2013年第8期379-386,共8页
Two activated carbons with controlled pore size were prepared from Eucalyptus wood by physical activation with carbon dioxide, giving the BET surface area and pore volume of738 m2/g and0.39 cm3/g, and921 m2/g and0.53 ... Two activated carbons with controlled pore size were prepared from Eucalyptus wood by physical activation with carbon dioxide, giving the BET surface area and pore volume of738 m2/g and0.39 cm3/g, and921 m2/g and0.53 cm3/g for the carbon sample AC1 and AC2, respectively. These activated carbons were then used to remove the residual dye left after the silk-dyeing process. The dye solution used for adsorption study was a cationic aluminium dye complex of [Al(brazilein)2]+ derived from a mixture of alum and extract of the heartwood of Ceasalpinia sappan Linn., with initial dye concentration of 220 mg/l. Effects of adsorbent dosage, adsorption time and temperature in the range of 25℃40℃ on dye adsorption were investigated. It was found that the adsorption kinetics of this dye complex was best described by the pseudo-second order model. Adsorption isotherms of this dye complex were well fitted by Langmuir isotherm equation. The adsorption capacities for the uptake of this dye complex at 25℃, 30℃ and 40℃ were 718.7, 1240.4 and 1139.5 mg/g and 1010.5, 1586.1 and 1659.0 mg/g for carbon sample AC1 and AC2, respectively. From these results, it can be concluded that activated carbon containing a higher proportion of mesopores gave better dye removal efficiency, emphasizing the fact that a proper pore size distribution of carbon adsorbent is crucial for the effecttive removal of relatively large size of the dye molecules. Thermodynamic parameters, including free energy, enthalpy and entropy of adsorption, were also determined. The adsorption enthalpies for the removal of this dye complex of AC1 and AC2 were 105.3 and 55.6 kJ/mol, respectively, indicating that the adsorption is an endothermic process. It was found that the adsorption of this dye complex is spontaneous at the temperatures under investigation. 展开更多
关键词 ADSORPTION Activated Carbon DYEING EFFLUENT EUCALYPTUS Wood
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Fluorescent-Dye Doped Thin-Film Sensors for the Detection of Alcohol Vapors
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作者 Jonathan K. Fong Royce N. Dansby-Sparks +6 位作者 Adam C. Lamb Thomas W. Owen Mohammad Mushfiq Uma Sampathkumaran Kisholoy Goswami Scott L. Jensen Zi-Ling Xue 《American Journal of Analytical Chemistry》 2014年第9期566-580,共15页
Fluorescence sensors based on a trifluoroacetophone compound doped in ethyl cellulose (EC) thin films have been developed for the detection of methanol, ethanol, and 2-propanol (isopropanol, PriOH) vapors. Thin-film s... Fluorescence sensors based on a trifluoroacetophone compound doped in ethyl cellulose (EC) thin films have been developed for the detection of methanol, ethanol, and 2-propanol (isopropanol, PriOH) vapors. Thin-film sensors are prepared with 4-dibutylamino-4’-(trifluoroacetyl)stilbene (Chromoionophore IX or CIX) as the fluorescent dye and its solution in EC was spin-coated onto glass slides. The luminescence intensity of the dye (555 nm) is quenched when exposed to alcohol vapor. Tested in the range of ca. 0 - 1.5?× 104 ppm (wt) for MeOH and EtOH, and ca. 0 - 2.3 × 104 ppm for PriOH, the sensors gave detection limits of 9, 13, 21 ppm and quantification limits of 32, 43, and 70 ppm, respectively. To enhance the sensitivity of the sensors, TiO2 particles have been added to the films to induce Mie scattering, which increases the incident light interaction with the sensing films. The sensors in this work have been designed to work in a multianalyte platform for the simultaneous detection of multiple gas analytes. 展开更多
关键词 Optical Thin Film Sensors Chromoionophore IX DYE ALCOHOL Vapor DETECTION
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CW-Dye Laser Spectrometer for Ultrahigh Resolution Spectroscopy: Design and Performance
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作者 Hassan El-Kashef 《Optics and Photonics Journal》 2014年第8期228-236,共9页
This work is devoted to building-up of ultrahigh resolution cw-dye laser spectrometer system. This system used self-frequency-stabilized and temperature-compensated plano-confocal reference cavity. The one-way propaga... This work is devoted to building-up of ultrahigh resolution cw-dye laser spectrometer system. This system used self-frequency-stabilized and temperature-compensated plano-confocal reference cavity. The one-way propagation is achieved using new construction of optical diode. The laser frequency selection and tuning is accomplished using Mach-Zehnder interferometer of free spectral range 42.5 GHz. In combination with computerized tunable radio frequency technique, this system is capable of a resolution of about ±1 KHz. Applications for measuring high lying, weakly occupied metastable states of free atoms (line 548.792 nm of V-51) are investigated to a high degree of accuracy. The results of the constants A and B of the hfs as measured by fluorescence spectroscopy show that A = 160.762 and B = -17.918, while the obtained results for the hfs constants A and B as measured by laser-RF double resonance technique give A = 160.9950 and B = -17.3358. 展开更多
关键词 DYE Laser Optical Spectroscopy RADIO Frequency Technique HYPERFINE Structure of ATOMS
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Socio-Cultural Challenges of Small and Medium-Scale Batik and Tie-Dye Industry in Ghana
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作者 Kow Eduam Ghartey Eric Bruce-Amartey Jnr. Richard Acquaye 《Journal of Textile Science and Technology》 2022年第3期133-147,共15页
This paper investigates the socio-cultural challenges of the small-scale batik and tie-dye production and retailing industry in Ghana. The research is based on a qualitative research approach that employs interviews a... This paper investigates the socio-cultural challenges of the small-scale batik and tie-dye production and retailing industry in Ghana. The research is based on a qualitative research approach that employs interviews and observation for data collection. In all, sixteen (16) participants were sampled through purposive techniques. Data collected were transcribed, classified and analysed through thematic and descriptive analysis. The study found that family roles contradict the business role, pressure from family members, poor support from society members, some religious teachings, age, ethnicity and lifestyle of certain people among others. The study concludes that socio-cultural challenges have led to the collapse of most batik and tie-dye production and retailing sectors leaving thousands of Ghanaians jobless. It recommends among others that producers and retailers of batik and tie-dye must separate family roles from work responsibilities to enable them to perform effectively. Again, family members, parents and peers must desist from putting pressure on the entrepreneurs for freebies and the government must resource NBSSI, GEPA and GSB to have regular in-service training to batik and tie-dye producers and retailers to address poor financial management and technical challenges and also on product quality on the international market. 展开更多
关键词 SOCIO-CULTURAL Small and Medium-Scale RESIST DYEING
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壳聚糖复合水凝胶的制备方法及在水处理中的应用 被引量:2
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作者 冯颖 李可心 +4 位作者 张宏 于汉哲 马标 张建伟 董鑫 《工业水处理》 CAS CSCD 北大核心 2024年第2期17-26,共10页
壳聚糖由于来源广、吸附性能强和可自然降解等优点成为备受关注的天然吸附剂。壳聚糖复合水凝胶(CCH)材料是以壳聚糖为主要原料,通过化学、物理等方法改性后得到的新型复合材料。介绍了化学交联、物理交联以及互穿网络等合成壳聚糖复合... 壳聚糖由于来源广、吸附性能强和可自然降解等优点成为备受关注的天然吸附剂。壳聚糖复合水凝胶(CCH)材料是以壳聚糖为主要原料,通过化学、物理等方法改性后得到的新型复合材料。介绍了化学交联、物理交联以及互穿网络等合成壳聚糖复合水凝胶的主要方法。综述了近年来使用CCH对工业废水中常见染料、重金属离子和其他常见污染物的吸附机理和处理效果,讨论了当前利用CCH在处理工业废水中各种污染物时存在的问题及解决方法。最后对CCH在合成方法、选择性吸附、回收利用和智能改性等方面进行了展望,为深入研究提高CCH材料性能及拓宽其在工业废水处理中的应用范围提供了思路。 展开更多
关键词 壳聚糖 水凝胶 吸附 工业废水 重金属离子 染料
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漆酶催化没食子酸染色阳离子改性棉织物的性能 被引量:1
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作者 韩雪 韩冬 +2 位作者 于乐 董爱学 王润博 《印染》 CAS 北大核心 2024年第3期20-23,共4页
利用漆酶催化没食子酸,并对聚二甲基二烯丙基氯化铵改性棉织物进行染色。结果表明:漆酶可催化没食子酸聚合,采用一浴一步法和一浴二步法工艺对改性棉织物染色,二者的染色特征值相接近,染色改性棉织物的UPF≥40,亲水性能明显提升,力学性... 利用漆酶催化没食子酸,并对聚二甲基二烯丙基氯化铵改性棉织物进行染色。结果表明:漆酶可催化没食子酸聚合,采用一浴一步法和一浴二步法工艺对改性棉织物染色,二者的染色特征值相接近,染色改性棉织物的UPF≥40,亲水性能明显提升,力学性能也有所改善。 展开更多
关键词 染色 漆酶 没食子酸 阳离子改性 棉织物
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玉米芯-环糊精交联复合材料对染料分子的吸附性能 被引量:1
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作者 王丽琼 李霞 +1 位作者 侯淋 郭易豪 《应用化工》 CAS CSCD 北大核心 2024年第1期10-14,共5页
以玉米芯和β-环糊精为原料,通过一锅法制备了玉米芯-β-环糊精复合材料(CB-β-CD),通过FTIR、SEM、BET、热重分析仪对其进行了表征。考察了CB-β-CD对酸性品红(AF)和孔雀石绿(MG)在不同吸附条件下的吸附性能。结果表明,20 mL染料初始... 以玉米芯和β-环糊精为原料,通过一锅法制备了玉米芯-β-环糊精复合材料(CB-β-CD),通过FTIR、SEM、BET、热重分析仪对其进行了表征。考察了CB-β-CD对酸性品红(AF)和孔雀石绿(MG)在不同吸附条件下的吸附性能。结果表明,20 mL染料初始质量浓度为30 mg/L,加入10 mg吸附剂,吸附3 h,CB-β-CD对MG和AF的最大吸附量分别为52.16 mg/g和58.04 mg/g。MG在碱性条件下更有利于吸附剂的吸附,AF在酸性条件下更有利于吸附剂的吸附。AF和MG的吸附更符合准二级动力学模型和Langmuir等温吸附模型,整个吸附过程以单分子层化学吸附为主。经过5次循环使用,该材料的吸附性能仍可达到90%以上。 展开更多
关键词 玉米芯 Β-环糊精 复合材料 有机染料 吸附
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中国传统印染技艺研究发展现状 被引量:2
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作者 陈秀芳 《纺织科学与工程学报》 CAS 2024年第1期111-116,共6页
七项传统印染技艺被列入国家级非物质文化遗产代表性项目名录,分别是扎染技艺、蜡染技艺、蓝印花布印染技艺、香云纱染整技艺、艾德莱斯绸织染技艺、蓝夹缬以及和枫香印染技艺。当前研究重点主要有三个方面,包括纹样创新应用、产品设计... 七项传统印染技艺被列入国家级非物质文化遗产代表性项目名录,分别是扎染技艺、蜡染技艺、蓝印花布印染技艺、香云纱染整技艺、艾德莱斯绸织染技艺、蓝夹缬以及和枫香印染技艺。当前研究重点主要有三个方面,包括纹样创新应用、产品设计开发及生产性保护和数字化保护。同时,香云纱染整技艺侧重薯莨染色工艺及河泥作用机理的研究,艾德莱斯绸织染技艺侧重宽幅及双面织物织造工艺的研究。另外,各项传统印染技艺在中国知网文献数量的差异也在一定程度上反映人们对其研究重视程度的不同。 展开更多
关键词 扎染 蜡染 蓝印花布 香云纱 艾德莱斯绸 蓝夹缬 枫香染
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不同形貌CaO_(2)的制备及其降解水中结晶紫的研究 被引量:1
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作者 李亚林 黄羽 +3 位作者 靳明玉 冯十方 毛瑞月 李晓琪 《水处理技术》 CAS CSCD 北大核心 2024年第2期38-43,50,共7页
为探究不同形貌过氧化钙对染料降解去除效果的差异性,采用钙盐法在不同条件下制备不同形貌的过氧化钙,并将其用于处理结晶紫模拟的染料废水。通过X射线衍射、扫描电子显微镜和傅里叶变换红外光谱对制得的过氧化钙进行了形貌表征,证明合... 为探究不同形貌过氧化钙对染料降解去除效果的差异性,采用钙盐法在不同条件下制备不同形貌的过氧化钙,并将其用于处理结晶紫模拟的染料废水。通过X射线衍射、扫描电子显微镜和傅里叶变换红外光谱对制得的过氧化钙进行了形貌表征,证明合成了四方晶状过氧化钙和球状纳米过氧化钙,并考察了两种过氧化钙在不同条件下对模拟染料废水中结晶紫的去除效果。结果表明,在模拟染料废水初始pH为6.0,结晶紫初始浓度为10 mg/L,四方晶状过氧化钙投加量为18.0 mg,球型纳米过氧化钙投加量为30.0 mg时,结晶紫的去除率分别可以达到94.14%和85.49%。准一级动力学方程可以描述两种过氧化钙对结晶紫的降解机制,球状纳米过氧化钙对结晶紫的降解过程与准一级动力学模型的吻合度更高。 展开更多
关键词 过氧化钙 结晶紫 降解 高级氧化 染料废水
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真丝织物的植物染料染色
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作者 赵宝艳 夏建明 +4 位作者 王华清 倪宇超 孙锐 周鑫妤 金阳波 《印染》 CAS 北大核心 2024年第7期38-42,共5页
采用植物红和植物蓝染料对真丝织物进行直接染色,探讨了染液浓度、染色pH、染色温度、染色时间、元明粉用量、固色剂用量对真丝织物染色效果的影响。通过正交试验得到的最佳染色工艺为:植物红染料质量分数1.00%(omf),染液pH为3,染色温... 采用植物红和植物蓝染料对真丝织物进行直接染色,探讨了染液浓度、染色pH、染色温度、染色时间、元明粉用量、固色剂用量对真丝织物染色效果的影响。通过正交试验得到的最佳染色工艺为:植物红染料质量分数1.00%(omf),染液pH为3,染色温度90℃,染色时间40 min,元明粉质量浓度5 g/L,固色剂质量分数1%;植物蓝染料质量分数1.00%(omf),染液pH为7,染色温度90℃,染色时间55 min,元明粉质量浓度5 g/L,固色剂质量分数1%。染色织物具有较好的耐皂洗色牢度、耐摩擦色牢度和耐汗渍色牢度,基本达到3~4级以上。 展开更多
关键词 植物基染料 染色 真丝织物 植物基固色剂
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静电纺壳聚糖基纳米纤维的制备及其在水处理中应用研究进展
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作者 冯颖 于汉哲 +4 位作者 张宏 李可心 马标 董鑫 张建伟 《纺织学报》 EI CAS CSCD 北大核心 2024年第5期218-227,共10页
为提高壳聚糖的可纺性,改善壳聚糖基纳米纤维的物理形态和力学性能,对国内外利用静电纺丝技术制备壳聚糖基纳米纤维的相关研究进行了综述。介绍了壳聚糖静电纺丝液的配制要求以及不同纺丝参数对纤维形态的影响;在此基础上,详细综述了壳... 为提高壳聚糖的可纺性,改善壳聚糖基纳米纤维的物理形态和力学性能,对国内外利用静电纺丝技术制备壳聚糖基纳米纤维的相关研究进行了综述。介绍了壳聚糖静电纺丝液的配制要求以及不同纺丝参数对纤维形态的影响;在此基础上,详细综述了壳聚糖化学改性纳米纤维和壳聚糖共混改性纳米纤维的研究进展;最后,对应用壳聚糖基纳米纤维处理废水中重金属离子、染料和其它污染物的研究现状进行总结。研究发现:不同纺丝参数最终均是通过影响射流拉伸的难易程度来改变纤维形态,且通过化学改性和共混改性的方法不仅可提高壳聚糖的可纺性,还可增强壳聚糖基纳米纤维的耐酸性、热稳定性、抗菌性和吸附性;同时指出探寻新的溶剂、共混剂和功能材料以及与选择性分离技术结合来增强对水中污染物的吸附能力是壳聚糖基纳米纤维的未来发展趋势。 展开更多
关键词 壳聚糖基纳米纤维 静电纺技术 重金属 染料 吸附剂 废水处理
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抗坏血酸对番茄红素染色性能的影响
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作者 卢声 于颖 +1 位作者 侯江波 宋明姝 《针织工业》 北大核心 2024年第8期42-45,共4页
为研究番茄红素对织物的染色可行性,以抗坏血酸作为色素稳定剂,用番茄红素对涤纶仿真丝织物进行染色试验,并对染色织物的染色牢度进行评价。利用吸光度值讨论抗坏血酸对番茄红素色素稳定性的影响,根据染色织物的K/S值和L^(*)、a^(*)、b^... 为研究番茄红素对织物的染色可行性,以抗坏血酸作为色素稳定剂,用番茄红素对涤纶仿真丝织物进行染色试验,并对染色织物的染色牢度进行评价。利用吸光度值讨论抗坏血酸对番茄红素色素稳定性的影响,根据染色织物的K/S值和L^(*)、a^(*)、b^(*)值研究了染色织物的染色性能,并测定染色织物的色牢度。结果表明:抗坏血酸能提高番茄红素色素的稳定性,对番茄红素起到护色作用;在染色过程中,抗坏血酸的加入能提高染色织物的K/S值,但过量的加入并不能起到增深的作用;染色织物具有一定的色牢度。 展开更多
关键词 番茄红素 抗坏血酸 涤纶织物 染色
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茶棕染料对改性芳纶1414的染色性能
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作者 武松梅 陈秀芳 +1 位作者 金隽 张勇 《印染》 CAS 北大核心 2024年第7期55-58,共4页
芳纶1414(PPTA)染色困难,为开发PPTA织物的环保染色方法,PPTA织物经NaOH、阳离子改性剂BS改性后,投入茶棕染料与硫酸亚铁络合染液中,在常压煮沸条件下直接染色。根据染色织物的K/S值优化了改性和染色工艺:改性剂BS 5 g/L,络合染液25 g/L... 芳纶1414(PPTA)染色困难,为开发PPTA织物的环保染色方法,PPTA织物经NaOH、阳离子改性剂BS改性后,投入茶棕染料与硫酸亚铁络合染液中,在常压煮沸条件下直接染色。根据染色织物的K/S值优化了改性和染色工艺:改性剂BS 5 g/L,络合染液25 g/L,pH=4,染色时间60 min。染色织物的耐摩擦和耐皂洗色牢度均较好,阻燃性能达到阻燃织物的标准。 展开更多
关键词 芳纶1414 茶棕染料 色牢度 阻燃性
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PEFT聚酯的制备及PEFT纳滤膜的截留性能
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作者 苏坤梅 赵冬生 +1 位作者 李振环 张马亮 《天津工业大学学报》 CAS 北大核心 2024年第1期1-9,共9页
为了解决聚对苯二甲酸乙二醇酯(PET)材料制品使用后降解缓慢和聚2,5-呋喃二甲酸二甲酯(PEF)韧性差的问题,开发一种新型嵌段共聚酯聚2,5-呋喃二甲酸-乙二醇-co-对苯二甲酸酯(PEFT),可通过酯交换-熔融缩聚法合成,且PEFT拥有与PEF相媲美的... 为了解决聚对苯二甲酸乙二醇酯(PET)材料制品使用后降解缓慢和聚2,5-呋喃二甲酸二甲酯(PEF)韧性差的问题,开发一种新型嵌段共聚酯聚2,5-呋喃二甲酸-乙二醇-co-对苯二甲酸酯(PEFT),可通过酯交换-熔融缩聚法合成,且PEFT拥有与PEF相媲美的热力学性能。利用FTIR及NMR等对聚酯结构进行表征,结果表明该方法成功制备了PEFT聚酯。通过TG、DSC和紫外光照表征,结果表明PEFT聚酯热学性能优良,且在紫外光照射下可快速降解。又将PEFT聚酯材料通过非溶剂致相分离法(NIPS)制备了不同铸膜液浓度的PEFT纳滤膜,用于对染料离子及金属盐溶液的截留,而后对其表面粗糙度、水接触角、荷电性、染料和金属盐离子的截留能力等方面进行了测试。结果表明:PEFT纳滤膜对甲基蓝(Mr=799.8)染料、酸性品红(Mr=585.4)染料都具有良好的截留性能,最高截留率可达99%和87.7%,并且纳滤膜经长期循环后仍具有较高的稳定性,但对金属盐(MgSO4)溶液截留性能不佳,截留率最高不超过35%。综合研究发现PEFT纳滤膜在染料截留方面性能突出。 展开更多
关键词 呋喃基聚酯 熔融缩聚 纳滤膜 染料截留 降解
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沸石咪唑酯骨架-8的制备及其对刚果红的吸附性能
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作者 杨亮 孔韩韩 +4 位作者 李韦霖 祁小芬 张天芸 王雪梅 李文全 《纺织学报》 EI CAS CSCD 北大核心 2024年第7期140-149,共10页
为制备印染废水的吸附材料,以六水合硝酸锌和2-甲基咪唑为原材料,以去离子水作溶剂,采用水溶剂法制备沸石咪唑酯骨架-8(ZIF-8)材料。借助扫描电子显微镜、红外光谱仪、X射线衍射仪等探究ZIF-8材料的结构,测试其对阴离子刚果红染料的吸... 为制备印染废水的吸附材料,以六水合硝酸锌和2-甲基咪唑为原材料,以去离子水作溶剂,采用水溶剂法制备沸石咪唑酯骨架-8(ZIF-8)材料。借助扫描电子显微镜、红外光谱仪、X射线衍射仪等探究ZIF-8材料的结构,测试其对阴离子刚果红染料的吸附性能,并分析其吸附机制。结果表明:ZIF-8颗粒大小均匀,表面光滑,呈多面体结构;其热裂解温度为258℃,具有良好的热稳定性;ZIF-8对刚果红的吸附更符合准二级动力学模型和Langmuir吸附等温线模型,即以化学吸附为主且吸附位点等效;吸附过程为自发进行的放热反应,低温有利于吸附;在温度为20℃、pH值为7的条件下,ZIF-8对95 mg/L的刚果红溶液的吸附效果最佳,吸附量可达671.41 mg/g。 展开更多
关键词 沸石咪唑酯骨架-8 刚果红 阴离子染料 印染废水 废水处理 吸附性能 吸附机制
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农田裂隙优先流对灌水模式/初始墒情响应机制及其模拟研究
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作者 翟亚明 王冲 +2 位作者 王策 陈理政 付丽红 《中国农村水利水电》 北大核心 2024年第2期56-63,73,共9页
农田灌溉管理过程中优先流降低水肥利用效率,加剧地下水污染风险。基于碘化钾-淀粉染色示踪试验,分析了地面灌DM、微喷灌WP1(20 mm/h)、微喷灌WP2(40 mm/h)处理下的裂隙优先流特征,验证了基于水量平衡的双域渗透模型的有效性,并采用4组... 农田灌溉管理过程中优先流降低水肥利用效率,加剧地下水污染风险。基于碘化钾-淀粉染色示踪试验,分析了地面灌DM、微喷灌WP1(20 mm/h)、微喷灌WP2(40 mm/h)处理下的裂隙优先流特征,验证了基于水量平衡的双域渗透模型的有效性,并采用4组初始体积含水率(0.20、0.25、0.30、0.35 cm^(3)/cm^(3))与5组灌水强度(12.0、24.0、36.0、48.0、60.0mm/h)旋转组合设计进行模拟应用分析。结果表明,WP1、WP2处理整体上水分以均匀的基质流形式入渗;DM处理下的土壤剖面染色区域在垂直方向上可明显划分为基质流区(0~6.9 cm)和优先流区(>6.9 cm)。此外,DM处理下的基质流深度、灌水均匀度显著(P<0.05)小于WP1、WP2处理,而其优先流指数及湿润锋弯曲度均极显著大于(P<0.01)WP1、WP2处理,这表明地面灌可以激活更多的优先流路径,增大优先流发育程度和空间异质性,降低灌水质量。基于水量平衡的双域渗透模型可有效预测不同灌水强度下的基质流深度和土壤剖面染色面积比变化趋势(R2≥0.9276、NSE≥0.8844、RSR≤0.0230),初始体积含水率和灌水强度旋转组合设计模拟结果表明,增加灌水强度或减小初始含水率会增加优先流的程度而降低灌水质量,故建议在农田灌溉管理过程中采用“高频少量”的灌水模式以减少优先流导致的水肥利用效率降低。该研究成果可为农田灌溉决策提供理论依据,其试验数据可为优先流模型优化与验证提供重要的数据支撑。 展开更多
关键词 染色示踪试验 优先流 灌水强度 含水率 数值模拟
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涤纶织物分散荧光黄染色及易去污整理
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作者 杨宏林 郏奎宇 +1 位作者 项伟 陈慧媛 《印染》 北大核心 2024年第1期48-51,56,共5页
为了改善荧光黄染色涤纶织物的易去污性,以色度坐标和亮度因子β为指标,优化染色工艺和易去污整理工艺。结果表明,荧光黄10G对涤纶织物最佳染色工艺条件为:染料质量分数1.0%(omf),染浴pH为5,染色温度130℃,染色时间40 min;最佳易去污整... 为了改善荧光黄染色涤纶织物的易去污性,以色度坐标和亮度因子β为指标,优化染色工艺和易去污整理工艺。结果表明,荧光黄10G对涤纶织物最佳染色工艺条件为:染料质量分数1.0%(omf),染浴pH为5,染色温度130℃,染色时间40 min;最佳易去污整理工艺为:整理剂质量浓度40 g/L,焙烘温度150℃,焙烘时间60 s。整理后的涤纶织物经10次洗涤后易去污性仍达4级,经30次洗涤后其荧光性能仍可满足相关标准要求,且耐皂洗色牢度和耐摩擦色牢度均达到4级以上。 展开更多
关键词 染色 易去污整理 分散荧光染料 涤纶织物
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