In the given work the adsorption properties of molecule curcumin((1 E,6 E)-1,7-bis(4-hydroxy-3-methoxyphenyl)-1,6-heptadiene-3,5-dione) on CNT(8,0-6) nanotube were investigated by the density functional theory(DFT) in...In the given work the adsorption properties of molecule curcumin((1 E,6 E)-1,7-bis(4-hydroxy-3-methoxyphenyl)-1,6-heptadiene-3,5-dione) on CNT(8,0-6) nanotube were investigated by the density functional theory(DFT) in the solvent water for the first time. The non-bonded interaction effects of compounds curcumin and CNT(8,0-6) nanotube on the electronic properties, UV/Vis spectra, chemical shift tensors and natural charges were determined and discussed. The electronic spectra of the compound curcumin and the complex CNT(8,0-6)/curcumin in the solvent water were calculated by time dependent density functional theory(TD-DFT) for investigation of the maximum wavelength value of molecule Curcumin before and after the non-bonded interaction with the CNT(8,0-6) nanotube and molecular orbitals involved in the formation of absorption spectrum of the complex CNT(8,0-6)/curcumin at maximum wavelength.展开更多
背景:0-6岁儿童各类严重创伤、畸形、肿瘤、结核、炎症等均极易导致枕寰枢复合体区损伤。当出现损伤压迫延髓、上颈髓、诸多神经血管等危重情况时需手术矫治以恢复该区力学稳定,但鉴于该期儿童有不同于青少年和成人的发育特征,国内外学...背景:0-6岁儿童各类严重创伤、畸形、肿瘤、结核、炎症等均极易导致枕寰枢复合体区损伤。当出现损伤压迫延髓、上颈髓、诸多神经血管等危重情况时需手术矫治以恢复该区力学稳定,但鉴于该期儿童有不同于青少年和成人的发育特征,国内外学者对其前、后或侧路手术内固定器械方案设计、矫形固定和力学机制等至今仍无深入研究和统一认识。目的:通过分析0-6岁儿童枕寰枢复合体区形态特征基础数据综述其形态发育规律和力学机制,将填充国人儿童该区发育形态学、影像学和微结构力学数据库,并为发育性、外伤性该区疾病的预防、诊治及内固定术器械设计、研发等提供理论依据。方法:用计算机检索2004年1月至2017年12月PubMed数据库、中国知网及万方数据库的相关文章,英文检索词"0-6 years old,pediatric,occipital atlantoaxial complex,anatomy,biomechanical";中文检索词"0-6岁小儿,枕寰枢复合体,解剖,生物力学",共检索到82篇相关文献,58篇文献符合纳入标准。结果与结论:(1)0-6岁儿童寰枢椎及颅底复杂解剖结构更加细小且变异大、毗邻关系复杂,无法以成人或青少年螺钉内技术相关数据简单地应用于"非成人等比例缩小"的发育中幼儿,加之手术风险极高,故提高置钉的准确性和降低失误率已成为曾经"生命禁区"内固定能否普遍基层开展的关键所在;(2)0-6岁小儿枕寰枢复合体区严重损伤应内固定治疗,后路内固定是常用术式,因常合并多种畸形,各患儿的骨质结构差异大,内固定置钉更为困难。展开更多
基金supported by the National Academy of Sciences of Belarus
文摘In the given work the adsorption properties of molecule curcumin((1 E,6 E)-1,7-bis(4-hydroxy-3-methoxyphenyl)-1,6-heptadiene-3,5-dione) on CNT(8,0-6) nanotube were investigated by the density functional theory(DFT) in the solvent water for the first time. The non-bonded interaction effects of compounds curcumin and CNT(8,0-6) nanotube on the electronic properties, UV/Vis spectra, chemical shift tensors and natural charges were determined and discussed. The electronic spectra of the compound curcumin and the complex CNT(8,0-6)/curcumin in the solvent water were calculated by time dependent density functional theory(TD-DFT) for investigation of the maximum wavelength value of molecule Curcumin before and after the non-bonded interaction with the CNT(8,0-6) nanotube and molecular orbitals involved in the formation of absorption spectrum of the complex CNT(8,0-6)/curcumin at maximum wavelength.
文摘背景:0-6岁儿童各类严重创伤、畸形、肿瘤、结核、炎症等均极易导致枕寰枢复合体区损伤。当出现损伤压迫延髓、上颈髓、诸多神经血管等危重情况时需手术矫治以恢复该区力学稳定,但鉴于该期儿童有不同于青少年和成人的发育特征,国内外学者对其前、后或侧路手术内固定器械方案设计、矫形固定和力学机制等至今仍无深入研究和统一认识。目的:通过分析0-6岁儿童枕寰枢复合体区形态特征基础数据综述其形态发育规律和力学机制,将填充国人儿童该区发育形态学、影像学和微结构力学数据库,并为发育性、外伤性该区疾病的预防、诊治及内固定术器械设计、研发等提供理论依据。方法:用计算机检索2004年1月至2017年12月PubMed数据库、中国知网及万方数据库的相关文章,英文检索词"0-6 years old,pediatric,occipital atlantoaxial complex,anatomy,biomechanical";中文检索词"0-6岁小儿,枕寰枢复合体,解剖,生物力学",共检索到82篇相关文献,58篇文献符合纳入标准。结果与结论:(1)0-6岁儿童寰枢椎及颅底复杂解剖结构更加细小且变异大、毗邻关系复杂,无法以成人或青少年螺钉内技术相关数据简单地应用于"非成人等比例缩小"的发育中幼儿,加之手术风险极高,故提高置钉的准确性和降低失误率已成为曾经"生命禁区"内固定能否普遍基层开展的关键所在;(2)0-6岁小儿枕寰枢复合体区严重损伤应内固定治疗,后路内固定是常用术式,因常合并多种畸形,各患儿的骨质结构差异大,内固定置钉更为困难。
