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Synthesis of colloidal LaF_3: 0.04Yb^(3+), 0.01Er^(3+) nanocrystals with green upconversion luminescence 被引量:1
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作者 王 艳 秦伟平 +3 位作者 张继森 曹春燕 张继双 金叶 《Journal of Rare Earths》 SCIE EI CAS CSCD 2008年第1期40-43,共4页
A synthesis of LaF3:0.04Yb^3+,0.01Er^3+ nanocrystals with oleic acid as a capping ligand was presemed. The X-Ray Diffraction (XRD) pattern indicated that the power was a single hexagonal phase. Transmission Elect... A synthesis of LaF3:0.04Yb^3+,0.01Er^3+ nanocrystals with oleic acid as a capping ligand was presemed. The X-Ray Diffraction (XRD) pattern indicated that the power was a single hexagonal phase. Transmission Electron Microscopy (TEM) demonstrated that the average size of the nanocrystals was less than 10 nm, with a narrow size distribution. The nanocrystals were dispersible in nonpolar solvents and form a fully transparent colloidal solution, and the solution was stable for several months without any aggregates. The Yb^3+-Er^3+ codoped nanocrystal colloidal solution exhibited a bright green upconversion fluorescence under 980 nm excitation from a diode laser. The nanocrystals were potentially applicable in biolabeling and bioimaging. 展开更多
关键词 upconversion luminescence COLLOIDAL LaF3:0.04Yb^3+ 0.01Er^3+ NANOCRYSTALS rare earths
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Er^3+:V0.01Y2.99Al5N0.01F0.01O11.98/BiPO4/Pt光催化剂的制备及其在降解废水中亚甲基蓝的应用 被引量:5
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作者 赵丽敏 靳瑞发 +1 位作者 马凤英 李曙光 《分子催化》 EI CAS CSCD 北大核心 2020年第3期201-209,I0001,共10页
通过溶胶-凝胶法合成了上转换发光材料Er^3+:V0.01Y2.99Al5N0.01F0.01O11.98(Er:YAG),然后利用水热法合成了BiPO4,再利用高温煅烧法合成了Er:YAG/BiPO4/Pt复合物光催化剂.通过使用X-射线粉末衍射仪(XRD),扫描电子显微镜(SEM),透射电子... 通过溶胶-凝胶法合成了上转换发光材料Er^3+:V0.01Y2.99Al5N0.01F0.01O11.98(Er:YAG),然后利用水热法合成了BiPO4,再利用高温煅烧法合成了Er:YAG/BiPO4/Pt复合物光催化剂.通过使用X-射线粉末衍射仪(XRD),扫描电子显微镜(SEM),透射电子显微镜(TEM),光致发光光谱(PL)和上转换发射光谱对样品的组成、形貌及光学特征进行了表征.此外,还研究了不同甘油添加量、Er:YAG和BiPO4的摩尔比例和复合温度及光催化剂的循环使用次数对Er:YAG/BiPO4/Pt复合物光催化剂活性的影响.实验结果显示Er:YAG/BiPO4/Pt复合物光催化剂具有高的光催化活性和较好的稳定性,它可以作为一种高效的光催化剂用于污水中有机污染物的处理. 展开更多
关键词 上转换发光材料 Er^3+:V0.01Y2.99Al5N0.01F0.01O11.98 BiPO4 光催化活性 亚甲基蓝
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