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Axially Chiral C2-Symmetric N-Heterocyclic Carbene (NHC) Palladium Complex-Catalyzed Asymmetric Fluorination and Amination of Oxindoles
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作者 张睿 王德 +2 位作者 徐琴 姜佳俊 施敏 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2012年第6期1295-1304,共10页
Chiral C2-symmetric N-heterocyclic carbene (NHC) palladium diaquo complex 5b prepared from (S)-BINAM was found to be a fairly effective catalyst for the enantioselective asymmetric fluorination of oxindoles to giv... Chiral C2-symmetric N-heterocyclic carbene (NHC) palladium diaquo complex 5b prepared from (S)-BINAM was found to be a fairly effective catalyst for the enantioselective asymmetric fluorination of oxindoles to give the corresponding products in moderate enantioselectivities along with good to excellent yields. 展开更多
关键词 chiral C2-symmetric N-heterocyclic carbene (NHC) palladium diaquo complex (S)-B1NAM asym-metric fluorination of oxindoles N-fluorobenzenesulfonimide (NFSI) 1-chloromethyl-4-fluoro-l 4-diazoniabi-cyclo[2.2.2]octane bis(tetrafluoroborate) (selectfluor)
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