A series of thiophenyl-containing 3-thiophene derivatives (4a--4i) were prepared via the reaction of chalcone-analogua compounds (3a--3i) and thiophenol in the presence of catalytic amount of KOBu-t in CH2C12 with...A series of thiophenyl-containing 3-thiophene derivatives (4a--4i) were prepared via the reaction of chalcone-analogua compounds (3a--3i) and thiophenol in the presence of catalytic amount of KOBu-t in CH2C12 with moderate to high yields. The mechanistic pathway of the reaction was explained by the Michael-type addition of thiophenol to chalcone derivatives (3a--3i).展开更多
文摘A series of thiophenyl-containing 3-thiophene derivatives (4a--4i) were prepared via the reaction of chalcone-analogua compounds (3a--3i) and thiophenol in the presence of catalytic amount of KOBu-t in CH2C12 with moderate to high yields. The mechanistic pathway of the reaction was explained by the Michael-type addition of thiophenol to chalcone derivatives (3a--3i).