A novel 1-3-2 piezoelectric composite has been developed,which consists of piezoelectric ceramic plate and 1-3 piezoelectric composite.The composite was fabricated by dicing PZT ceramic along mutual perpendicular two ...A novel 1-3-2 piezoelectric composite has been developed,which consists of piezoelectric ceramic plate and 1-3 piezoelectric composite.The composite was fabricated by dicing PZT ceramic along mutual perpendicular two directions and then filling epoxy into grooves.The piezoelectric and electromechanical properties of the novel composite were determined. The results show a coefficient d_ (33) of 405pC/N,a vibration displacement of 113.5pm,an acoustic impendence of 13.3 Mraly, a bandwidth of 12kHz and a thickness electromechanical coupling coefficient of 0.56.展开更多
The cathode material La1-xSrxCuO3-δ(x=0.15, 0.2, 0.3, 0.4) was synthesized by a sol-gel method. X-ray diffraction reveals that a single phase of perovskite is formed. The investigation of the electrical properties su...The cathode material La1-xSrxCuO3-δ(x=0.15, 0.2, 0.3, 0.4) was synthesized by a sol-gel method. X-ray diffraction reveals that a single phase of perovskite is formed. The investigation of the electrical properties suggests that La0.7Sr0.3CuO3-δ has the highest electrical conductivity. La0.7Sr0.3CuO3-δ powder was mixed with different amount SDC (Sm0.15Ce0.85O1.925) powder (5wt.%-30wt.%) as composite cathodes. Electrochemical properties of the composite cathodes were researched further. Investigation suggests that the addition of appropriate amount SDC to La0.7Sr0.3CuO3-δ can improve the electrochemical properties and obtain better cathodic performance. Using La0.7Sr0.3CuO3-δ-SDC composite materials as a cathode based on SDC electrolyte, higher current density and power density at intermediate temperatures can be obtained.展开更多
Piezoelectric properties and related figures of merit are studied in novel 1-3-type composites based on ferroelectric domain-engineered lead-free single crystal with the relatively large longitudinal piezoelectric coe...Piezoelectric properties and related figures of merit are studied in novel 1-3-type composites based on ferroelectric domain-engineered lead-free single crystal with the relatively large longitudinal piezoelectric coefficient d_(33).Relationships between the piezoelectric properties and the set of figures of merit are analyzed for the 1-3 and 1-3-0 composites that contain the same single-crystal and polymer components.For a composite characterized by 1-3-0 connectivity,an influence of a porous piezo-passive matrix on the figures of merit and their volume-fraction behavior is considered additionally.A large anisotropy of figures of merit is observed in the 1-3-0 composite with specific porous matrices.A diagram is put forward to show volume-fraction regions of the large anisotropy of figures of merit of the studied 1-3-0 composite.Due to large figures of merit and their considerable anisotropy,the studied lead-free composites can be applied in piezoelectric energy-harvesting systems,sensors,transducers,and so on.展开更多
In the present work,piezoelectric composite films made of Polyaniline(PAni)coated Lead Zirconate Titanate(PZT)particles immersed into polyvinylidene fluoride(PVDF)matrix were characterized by mechanical tests,and the ...In the present work,piezoelectric composite films made of Polyaniline(PAni)coated Lead Zirconate Titanate(PZT)particles immersed into polyvinylidene fluoride(PVDF)matrix were characterized by mechanical tests,and the connectivity of the com-posite sample was determined using dielectric measurements and applying the Poon–Shin model.The composite was considered a binary system with coated PZT particles as one phase and the polymer matrix the other one.To support the result obtained from theoretical analysis,scanning electron microscopy of the composites were done.It was observed a decrease up to 85%on the mechanical resistance when the ceramic volume fraction increases from 0%to 40%.Furthermore,the composite film no longer can be considered with 0–3 connectivity when the ceramic content is 30 vol.%or over.展开更多
基金supported by the Beijing Natural Science Foundation of China(No.KZ200410772016)Academic Innovative Team Program of University in Beijing.
文摘A novel 1-3-2 piezoelectric composite has been developed,which consists of piezoelectric ceramic plate and 1-3 piezoelectric composite.The composite was fabricated by dicing PZT ceramic along mutual perpendicular two directions and then filling epoxy into grooves.The piezoelectric and electromechanical properties of the novel composite were determined. The results show a coefficient d_ (33) of 405pC/N,a vibration displacement of 113.5pm,an acoustic impendence of 13.3 Mraly, a bandwidth of 12kHz and a thickness electromechanical coupling coefficient of 0.56.
文摘The cathode material La1-xSrxCuO3-δ(x=0.15, 0.2, 0.3, 0.4) was synthesized by a sol-gel method. X-ray diffraction reveals that a single phase of perovskite is formed. The investigation of the electrical properties suggests that La0.7Sr0.3CuO3-δ has the highest electrical conductivity. La0.7Sr0.3CuO3-δ powder was mixed with different amount SDC (Sm0.15Ce0.85O1.925) powder (5wt.%-30wt.%) as composite cathodes. Electrochemical properties of the composite cathodes were researched further. Investigation suggests that the addition of appropriate amount SDC to La0.7Sr0.3CuO3-δ can improve the electrochemical properties and obtain better cathodic performance. Using La0.7Sr0.3CuO3-δ-SDC composite materials as a cathode based on SDC electrolyte, higher current density and power density at intermediate temperatures can be obtained.
基金The authors are grateful to Prof.Dr.I.A.Parinov and Prof.Dr.A.E.Panich(Southern Federal University,Russia),and Prof.Dr.C.R.Bowen(University of Bath,UK)for their interest in the field of modern piezo-active materials and applications.Research was financially supported by Southern Federal University,grant No.VnGr-07/2020-04-IM(Ministry of Science and Higher Education of the Russian Federation).
文摘Piezoelectric properties and related figures of merit are studied in novel 1-3-type composites based on ferroelectric domain-engineered lead-free single crystal with the relatively large longitudinal piezoelectric coefficient d_(33).Relationships between the piezoelectric properties and the set of figures of merit are analyzed for the 1-3 and 1-3-0 composites that contain the same single-crystal and polymer components.For a composite characterized by 1-3-0 connectivity,an influence of a porous piezo-passive matrix on the figures of merit and their volume-fraction behavior is considered additionally.A large anisotropy of figures of merit is observed in the 1-3-0 composite with specific porous matrices.A diagram is put forward to show volume-fraction regions of the large anisotropy of figures of merit of the studied 1-3-0 composite.Due to large figures of merit and their considerable anisotropy,the studied lead-free composites can be applied in piezoelectric energy-harvesting systems,sensors,transducers,and so on.
文摘In the present work,piezoelectric composite films made of Polyaniline(PAni)coated Lead Zirconate Titanate(PZT)particles immersed into polyvinylidene fluoride(PVDF)matrix were characterized by mechanical tests,and the connectivity of the com-posite sample was determined using dielectric measurements and applying the Poon–Shin model.The composite was considered a binary system with coated PZT particles as one phase and the polymer matrix the other one.To support the result obtained from theoretical analysis,scanning electron microscopy of the composites were done.It was observed a decrease up to 85%on the mechanical resistance when the ceramic volume fraction increases from 0%to 40%.Furthermore,the composite film no longer can be considered with 0–3 connectivity when the ceramic content is 30 vol.%or over.
