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“1+X”证书制度下新型活页式教材开发研究 被引量:1
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作者 欧阳英 皮俊 苏晓琼 《重庆电力高等专科学校学报》 2024年第2期75-78,共4页
“1+X”证书制度与活页式教材是我国职业教育的重点建设方向。“1+X”证书制度下的新型活页式教材同时服务于学历教育和职业教育,是职业院校当前开展教学的重要手段和载体。在调查高职园艺技术专业蔬菜生产技术课程教材开发现状的基础上... “1+X”证书制度与活页式教材是我国职业教育的重点建设方向。“1+X”证书制度下的新型活页式教材同时服务于学历教育和职业教育,是职业院校当前开展教学的重要手段和载体。在调查高职园艺技术专业蔬菜生产技术课程教材开发现状的基础上,探讨了新型活页式教材的开发策略,对于实践“1+X”证书制度试点工作和“三教”改革,培养复合型的园艺技术技能人才有着积极作用。 展开更多
关键词 1+X”证书制度 活页式教材 职业教育 蔬菜生产技术
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基于1+X证书制度的“岗课赛证”融通路径研究 被引量:2
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作者 王辉 李蓓 《黄河水利职业技术学院学报》 2024年第1期91-94,共4页
在教育部大力推进1+X证书制度背景下,“岗课赛证”融通成为高职教育领域的重要研究课题。针对工程造价专业“岗课赛证”融通存在的问题,结合河南建筑职业技术学院“岗课赛证”融通的工作经验,提出校企双元育人共同制订人才培养方案、构... 在教育部大力推进1+X证书制度背景下,“岗课赛证”融通成为高职教育领域的重要研究课题。针对工程造价专业“岗课赛证”融通存在的问题,结合河南建筑职业技术学院“岗课赛证”融通的工作经验,提出校企双元育人共同制订人才培养方案、构建基于1+X证书制度的“岗课赛证”融通课程体系、推进“三教”改革等解决路径,以期为高职工程造价专业“岗课赛证”融通提供参考。 展开更多
关键词 1+X证书制度 工程造价专业 “岗课赛证”融通 融通路径 双元育人 “三教”改革
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Toward high-efficiency perovskite solar cells with one-dimensional oriented nanostructured electron transport materials 被引量:1
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作者 Yinhua Lv Bing Cai +3 位作者 Ruihan Yuan Yihui Wu Quinn Qiao Wen-Hua Zhang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第7期66-87,I0003,共23页
The unique advantages of one-dimensional(1D)oriented nanostructures in light-trapping and chargetransport make them competitive candidates in photovoltaic(PV)devices.Since the emergence of perovskite solar cells(PSCs)... The unique advantages of one-dimensional(1D)oriented nanostructures in light-trapping and chargetransport make them competitive candidates in photovoltaic(PV)devices.Since the emergence of perovskite solar cells(PSCs),1D nanostructured electron transport materials(ETMs)have drawn tremendous interest.However,the power conversion efficiencies(PCEs)of these devices have always significantly lagged behind their mesoscopic and planar counterparts.High-efficiency PSCs with 1D ETMs showing efficiency over 22%were just realized in the most recent studies.It yet lacks a comprehensive review covering the development of 1D ETMs and their application in PSCs.We hence timely summarize the advances in 1D ETMs-based solar cells,emphasizing on the fundamental and optimization issues of charge separation and collection ability,and their influence on PV performance.After sketching the classification and requirements for high-efficiency 1D nanostructured solar cells,we highlight the applicability of 1D TiO_(2)nanostructures in PSCs,including nanotubes,nanorods,nanocones,and nanopyramids,and carefully analyze how the electrostatic field affects cell performance.Other kinds of oriented nanostructures,e.g.,ZnO and SnO_(2)ETMs,are also described.Finally,we discuss the challenges and propose some potential strategies to further boost device performance.This review provides a broad range of valuable work in this fast-developing field,which we hope will stimulate research enthusiasm to push PSCs to an unprecedented level. 展开更多
关键词 1D nanostructures Perovskite solar cells Electron transport materials Electrostatic field High-efficiency
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全同聚丁烯-1供热管材料性能及应用进展
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作者 宋佩儒 金吉钊 +2 位作者 杨莹 陈骏逸 赵永仙 《弹性体》 CAS 2024年第2期90-94,共5页
全同聚丁烯-1(iPB-1)是一种性能优异的热塑性树脂,具有良好的耐热性、耐蠕变性、耐应力开裂性,特别适用于做供热管材,但材料存在晶型转变慢、结晶温度低和结晶慢等问题,使其应用受到一定的限制。本文主要介绍iPB-1的材料特性、国内外的... 全同聚丁烯-1(iPB-1)是一种性能优异的热塑性树脂,具有良好的耐热性、耐蠕变性、耐应力开裂性,特别适用于做供热管材,但材料存在晶型转变慢、结晶温度低和结晶慢等问题,使其应用受到一定的限制。本文主要介绍iPB-1的材料特性、国内外的发展历史以及应用的进展,重点分析iPB-1作为供热管材与金属和其他塑料的供热管材相比的优势。 展开更多
关键词 全同聚丁烯-1 晶型转变 供热管材 材料特性
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Characterization of the negative thermal expansion material Zr_(1-x)Hf_xW_2O_8 被引量:1
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作者 SHENRong WANGCong +3 位作者 WANGTianmin DONGCheng CHENHong LIANGJingkui 《Rare Metals》 SCIE EI CAS CSCD 2003年第2期107-111,共5页
The oxide ZrW_2O_8 displays unusual property of isotropic negative thermalexpansion in a large wide temperature range, which makes it have a number of important potentialapplications. The cubic Zr_(1-x)Hf_xW_2O_8 (x v... The oxide ZrW_2O_8 displays unusual property of isotropic negative thermalexpansion in a large wide temperature range, which makes it have a number of important potentialapplications. The cubic Zr_(1-x)Hf_xW_2O_8 (x velence 0,0.3, 0.5, 0.7, and 1.0) were synthesized bystandard solid state reaction technique. The high and low temperature X-ray diffraction analysisindicate that the substitution of the Hf^(4+) for Zr^(4+) only leads to reducing the latticeconstants, and the changes of negative thermal expansion coefficients are not obvious. The linearexpansion coefficients of Zr_(1-x)Hf_xW_2O_8 (x velence 0,0.3, 0.5, 0.7, and 1.0) are about -6 X 10^(-6) K^(-1) in the temperature range of 298 to 973 K, while that of Zr_(0.5)Hf_(0.5)W_2O_8 is -9.6X 10^(-6) K_(-1) from 83 to 298 K. The phase transition temperatures from alpha-ZrW_2O_8 tobeta-ZrW_2O_8 structure were also determined by X-ray diffraction method. Thermogravimetric analysis(TGA) exhibits that Zr_(1-x)Hf_xW_2O_8 is not hygroscopic in air. 展开更多
关键词 inorganic non-metallic materials negative thermal expansion X-raydiffraction Zr_(1-x)Hf_xW_2O_8
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Facile synthesis of high capacity P2-type Na_(2/3)Fe_(1/2)Mn_(1/2)O_(2) cathode material for sodium-ion batteries 被引量:10
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作者 Mu-lan QIN Chang-yu YIN +5 位作者 Wen XU Yang LIU Jun-hao WEN Bin SHEN Wei-gang WANG Wan-min LIU 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第7期2074-2080,共7页
P2-type Na_(2/3)Fe_(1/2)Mn_(1/2)O_(2) was synthesized by a facile sol−gel method,and the effect of calcination temperature on the structure,morphology and electrochemical performance of samples was investigated.The re... P2-type Na_(2/3)Fe_(1/2)Mn_(1/2)O_(2) was synthesized by a facile sol−gel method,and the effect of calcination temperature on the structure,morphology and electrochemical performance of samples was investigated.The results show that the sample obtained at 900℃ is pure P2-type Na_(2/3)Fe_(1/2)Mn_(1/2)O_(2) phase with good crystallization,which consists of hexagon plate-shaped particles with the size and thickness of 2−4μm and 200−400 nm,respectively.The sample exhibits an initial specific discharge capacity of 243 mA·h/g at a current density of 26 mA/g with good cycling stability.The high specific capacity indicates that P2-type Na_(2/3)Fe_(1/2)Mn_(1/2)O_(2) is a promising cathode material for sodiumion batteries. 展开更多
关键词 sodium-ion battery cathode material Na_(2/3)Fe_(1/2)Mn_(1/2)O_(2) electrochemical performance sol−gel method
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Thermoelectric properties of porous (Bi_(0.15)Sb_(0.85))_2Te_3 thermoelectric materials 被引量:1
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作者 Guiying Xu, Tingjie Chen, Jianqiang Liu, and Zhangjian ZhouLaboratory of Special Ceramics and Powder Metallurgy, Materials Science and Engineering School, University of Science and Technology Beijing, Beijing 100083, China 《Journal of University of Science and Technology Beijing》 CSCD 2003年第5期39-43,共5页
In order to obtain thermoelectric materials with high figure of merit, theconcept of Hollow (Vacuum) Quantum Structure or Effect and related thermoelectric materials designwere proposed. To demonstrate the theory, the... In order to obtain thermoelectric materials with high figure of merit, theconcept of Hollow (Vacuum) Quantum Structure or Effect and related thermoelectric materials designwere proposed. To demonstrate the theory, the materials of (Bi_(0.15)Sb_(0.85))_2Te_3 with porousstructure have been fabricated. Their thermoelectric properties and the microstructure wereinvestigated and compared with their density structure. It was found that the porous structure couldimprove their properties greatly. 展开更多
关键词 thermoelectric materials Bi_xSb_(1-x) Bi_2Te_3 hollow quantum effect
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The effect of welding materials on 1Cr18Ni9Ti and 2Cr13 steel welded joints electrochemical properties 被引量:3
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作者 Zhao Yongtao Hu Yuqing +1 位作者 Dong Junhui Zhou Junwei 《China Welding》 CAS 2022年第3期42-47,共6页
By method of TIG,two kinds of welding materials were filled in and under certain welding craft conditions,1Cr18Ni9Ti and 2Cr13 were welded.The microstructure of two kinds of welded joints were observed and analyzed by... By method of TIG,two kinds of welding materials were filled in and under certain welding craft conditions,1Cr18Ni9Ti and 2Cr13 were welded.The microstructure of two kinds of welded joints were observed and analyzed by OM,SEM.Through seawater immersion test,polarization curves and AC impedance spectroscopy of two kinds of welding joints were obtained.The results show that 2Cr13 and 1Cr18Ni9Ti welded joints are typical columnar crystal,the microstructure is lath martensite+austenite+carbide.The welded joints that filled in 308 and H1Cr21Ni10Mn7Mo welding wires,corrosion resistance has same change rule:Austenite base metal>HAZ near Austenite>welded joint>HAZ near Martensite>Martensite base metal.The every zone contrast of two kinds of welded joint corrosion resistance obtains:the welded joints filled in 308>the welded joints filled in H1Cr21Ni10Mn7Mo. 展开更多
关键词 1CR18NI9TI 2Cr13 welding materials electrochemical properties
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Synthesis and electrochemical properties of Li_(1-x)V_xCr_yFe_(1-x)PO_4/C as a cathode material 被引量:1
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作者 Shi Tao Song Pei Hua Ma +2 位作者 Shi You Li Xiao Chuan Deng Chun Yan Yan 《Chinese Chemical Letters》 SCIE CAS CSCD 2008年第3期337-341,共5页
Composites Li1-xVxCryFe1-yPO4/C(x=0.01, 0.02; y = 0.01, 0.02) were synthesized by solid-state reaction method. The influence of the content of doping vanadium and chromium on the structure of Li1-xVxCryFe1-yPO4/C wa... Composites Li1-xVxCryFe1-yPO4/C(x=0.01, 0.02; y = 0.01, 0.02) were synthesized by solid-state reaction method. The influence of the content of doping vanadium and chromium on the structure of Li1-xVxCryFe1-yPO4/C was investigated by XRD, while the morphology of powders was observed by SEM. The investigation of the electrochemical performances showed that the Li0.99V0.01Cr0.02Fe0.98PO4/C material has a higher capacity. At 0.1 C discharging rate, it is capable of delivering reversible specific capacity of 163.8 mAh/g with fairly stable cycleability. 展开更多
关键词 Li1-xVxCryFe1-yPO4/C Cathode material Ion doping
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Synthesis of AgGa_(1-x)In_(x)Se_(2) Polycrystalline Materials 被引量:2
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作者 Liu Juan Zhao Beijun +7 位作者 Zhu Shifu Huang Yi Zhang Jianjun Zhu Weilin Xu Chengfu Chen Baojun Li Ming He Zhiyu 《Journal of Rare Earths》 SCIE EI CAS CSCD 2006年第z1期269-271,共3页
AgGa_(1-x)In_(x)Se_(2)polycrystals were synthesized by the method of mechanical oscillation and temperature oscillation.X-ray diffraction spectra of polycrystal powder are conformable with the JCPDS cards.Lattice cons... AgGa_(1-x)In_(x)Se_(2)polycrystals were synthesized by the method of mechanical oscillation and temperature oscillation.X-ray diffraction spectra of polycrystal powder are conformable with the JCPDS cards.Lattice constants a and c calculated from the XRD were found to obey Vegard's law.The melting point of AgGa_(0.8)In_(0.2)Se_(2)obtained by means of differential scanning calorimetry(DSC)is 796.53℃.The DSC curve also show that there are no other transformation points below the melting point.The results indicate that polycrystalline materials synthesized by the method mentioned above are high-quality and can be used to grow single crystals by the vertical Bridgman technology. 展开更多
关键词 nonlinear optical materials AgGa_(1-x)In_(x)Se_(2) polycrystal synthesis lattice constants
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Effect of lithium content on electrochemical property of Li_(1+x)(Mn_(0.6)Ni_(0.2)Co_(0.2))_(1-x)O_2(0≤x≤0.3) composite cathode materials for rechargeable lithium-ion batteries 被引量:1
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作者 Cheng-chi PAN Ying-chang YANG +4 位作者 Hong-shuai HOU Ming-jun JING Yi-rong ZHU Wei-xin SONG Xiao-bo JI 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2018年第1期145-150,共6页
In order to confirm the optimal Li content of Li-rich Mn-based cathode materials(a fixed mole ratio of Mn to Ni to Co is0.6:0.2:0.2),Li1+x(Mn0.6Ni0.2Co0.2)1-xO2(x=0,0.1,0.2,0.3)composites were obtained,which had a typ... In order to confirm the optimal Li content of Li-rich Mn-based cathode materials(a fixed mole ratio of Mn to Ni to Co is0.6:0.2:0.2),Li1+x(Mn0.6Ni0.2Co0.2)1-xO2(x=0,0.1,0.2,0.3)composites were obtained,which had a typical layered structure with R3m and C2/m space group observed from X-ray powder diffraction(XRD).Electron microscopy micrograph(SEM)reveals that the particle sizes in the range of0.4-1.1μm increase with an increase of x value.Li1.2(Mn0.6Ni0.2Co0.2)0.8O2sample delivers a larger initial discharge capacity of275.7mA·h/g at the current density of20mA/g in the potential range of2.0-4.8V,while Li1.1(Mn0.6Ni0.2Co0.2)0.9O2shows a better cycle performance with a capacity retention of93.8%at0.2C after50cycles,showing better reaction kinetics of lithium ion insertion and extraction. 展开更多
关键词 cathode material Li1+x(Mn0.6Ni0.2Co0.2)1-xO2 electrochemical property lithium-ion battery
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Comparative experiment on layered Li(Ni_(1/3)Co_(1/3)Mn_(1/3))O_2 as the alternative material for LiCoO_2 被引量:1
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作者 Jingjing Liu Weihua Qiu Lingyan Yu Hailei Zhao Tao Li 《Journal of University of Science and Technology Beijing》 CSCD 2007年第2期173-177,共5页
This work was financially supported by the National Natural Science Foundation of China (No.50472093).
关键词 Li(Ni1/3Co1/3Mn1/3)O2 cathode material lithium-ion batteries LICOO2
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1-甲基环丙烯对不同成熟度蜂糖李货架品质及挥发性物质影响的研究
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作者 田一鸣 王瑞 +5 位作者 马超 马玉华 李江阔 吉宁 雷霁卿 周集豪 《食品与发酵工业》 CAS CSCD 北大核心 2024年第12期209-219,共11页
蜂糖李因口感独特、营养价值高深受消费者的喜爱。该文以3个不同采收成熟度蜂糖李果实为试验材料,采后使用0.5、1.0μL/L的1-甲基环丙烯(1-methylcyclopropene,1-MCP)处理,然后货架(25±2)℃14 d,每隔2 d测定一次腐烂率、呼吸强度... 蜂糖李因口感独特、营养价值高深受消费者的喜爱。该文以3个不同采收成熟度蜂糖李果实为试验材料,采后使用0.5、1.0μL/L的1-甲基环丙烯(1-methylcyclopropene,1-MCP)处理,然后货架(25±2)℃14 d,每隔2 d测定一次腐烂率、呼吸强度、乙烯释放速率、硬度、色泽、可溶性固形物含量、可滴定酸含量、固酸比,并做出感官评价,最终结合GC-MS分析1-MCP对不同成熟度蜂糖李货架品质及挥发性物质的影响。结果表明,蜂糖李是典型的非呼吸跃变型果实;采收成熟度是影响蜂糖李果实在货架期间品质变化的主要原因,采收成熟度越高,蜂糖李果实在货架期间腐烂率越高、呼吸越旺盛、品质劣变越迅速;高浓度1-MCP(1.0μL/L)处理可以延缓不同成熟度蜂糖李果实货架期间品质的劣变,且对高成熟度(花后110 d)果实保鲜效果最为明显。GC-MS分析表明,醛类(“青草”味)和酯类(“果香”味)是蜂糖李果实主要的挥发性物质,且采收成熟度越高,醛类含量越低,酯类含量越高;不同浓度的1-MCP处理都可以延缓蜂糖李果实在货架期间醛类含量降低和酯类含量升高,更有效地维持蜂糖李果实的固有香气。结合固酸比与感官评价结果,高成熟度蜂糖李果实在货架期间风味最佳,1-MCP处理(1.0μL/L)可以有效延缓不同成熟度蜂糖李果实货架期间品质的劣变和风味的损失,且对高成熟度蜂糖李果实的货架保鲜效果最佳。 展开更多
关键词 蜂糖李 采收成熟度 1-甲基环丙烯 货架品质 挥发性物质
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Influence of CaxSr1-x(0≤x≤1)Substitution for Zn on Microwave Dielectric Properties of Li2ZnTi3O8 Ceramic as Temperature Stable Materials 被引量:1
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作者 TIAN Shi LIAO Zelin +1 位作者 WANG Heng WANG Weimin 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2020年第4期686-690,共5页
A temperature stable Li2Zn0.95(SrxCa1-x)0.05Ti3O8(0≤x≤1)ceramics were fabricated using a conventional solid-state route sintered at 1100℃for 4 h.The XRD results indicate that the main phase Li2ZnTi3O8 and secondary... A temperature stable Li2Zn0.95(SrxCa1-x)0.05Ti3O8(0≤x≤1)ceramics were fabricated using a conventional solid-state route sintered at 1100℃for 4 h.The XRD results indicate that the main phase Li2ZnTi3O8 and secondary phase including SrxCa1-xTiO3(0≤x≤1)solid solution and TiO2 co-exist in composite and form a stable composite system when the(CaxSr1-x)(0≤x≤1)substitutes for Zn of Li2ZnTi3O8 ceramic.As x is increased from 0 to 1,the relative permittivity(εr)increases from 26.65 to 27.12,and the quality factor(Q×f)increases from 63300 to 66600 GHz.With the increased of x,the temperature coefficient of resonant frequency(τf)increases from 0.27 to 8.23 ppm/℃,and then decreases to 3.51 ppm/℃.On the whole,the Li2Zn0.95(SrxCa1-x)0.05Ti3O8(0≤x≤1)ceramics show excellent comprehensive properties of middleεr=25-27,higher Q×f≥60000 GHz andτf≤±8.5 ppm/℃. 展开更多
关键词 Li2Zn0.95(SrxCa1-x)0.05Ti3O8(0≤x≤1) microwave dielectric properties temperature stable materials SUBSTITUTION
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一种改进型1-3-2压电复合材料的研究
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作者 井苏杰 于肇贤 王宏伟 《压电与声光》 CAS 北大核心 2024年第2期223-226,共4页
高质量的压电换能器需要具备较高的机电耦合系数和灵敏度。该文在传统型1-3-2压电复合材料的基础上提出了一种改进型1-3-2压电材料,提高了压电换能器的机电耦合系数和换能器的接收灵敏度。通过有限元仿真分析了不同间距对改进型1-3-2压... 高质量的压电换能器需要具备较高的机电耦合系数和灵敏度。该文在传统型1-3-2压电复合材料的基础上提出了一种改进型1-3-2压电材料,提高了压电换能器的机电耦合系数和换能器的接收灵敏度。通过有限元仿真分析了不同间距对改进型1-3-2压电材料敏感元件的谐振频率、反谐振频率及机电耦合系数的影响,并与传统1-3-2型压电复合材料进行了对比。结果表明,与传统型1-3-2压电复合材料相比,在相同间距条件下,改进型压电材料的机电耦合系数约大0.03。制做的3种不同间距改进型压电材料表明,间距为1 mm的改进型压电材料的机电耦合系数较大,约为0.68。 展开更多
关键词 不同间距 1-3-2型压电复合材料 改进型 谐振频率 反谐振频率 机电耦合系数
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Ag/LaNi_(x)Co_(1-x)O_(3)触点材料的制备及电接触性能研究
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作者 邵紫阳 杨芳儿 +4 位作者 王大帅 刘振武 沈涛 李跃 郑晓华 《贵金属》 CAS 北大核心 2024年第2期19-25,共7页
本文运用溶胶-凝胶燃烧法合成了双钙钛矿型LaNi_(x)Co_(1-x)O_(3)(LNCO)纳米材料,利用粉末冶金和热挤压技术制备了相应的Ag/LNCO触点材料及元件样品。重点考察了不同Ni、Co含量对Ag/LNCO触点材料微观结构、物相组成、物理性能、力学性... 本文运用溶胶-凝胶燃烧法合成了双钙钛矿型LaNi_(x)Co_(1-x)O_(3)(LNCO)纳米材料,利用粉末冶金和热挤压技术制备了相应的Ag/LNCO触点材料及元件样品。重点考察了不同Ni、Co含量对Ag/LNCO触点材料微观结构、物相组成、物理性能、力学性能及电寿命服役能力的影响,对其电弧侵蚀失效行为进行了研究,并与SnO2粉体增强Ag基触点材料进行对比。结果表明:溶胶凝胶法合成的LNCO纳米颗粒粒径为20-30 nm,经粉末冶金工艺制备的Ag/LaNi_(0.5)Co_(0.5)O_(3)触点材料电学性能和电寿命都优于Ag/SnO_(2)触点材料,其电阻率低至2.10μΩ∙cm,电寿命性能达到51287次。表明Ag/LaNi_(0.5)Co_(0.5)O_(3)触点材料性能较佳,是一种可以取代Ag/CdO的新型触点材料。 展开更多
关键词 触点材料 力学性能 电弧侵蚀 电寿命 La_(2)Ni_(1-x)Co_(x)O_(3)
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Lithium ion battery cathode material LiNi_yCo_zMn_(1-y-z)O_2
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作者 LI Nai jun(李乃军) 1, ZHAI Xiu jing(翟秀静) 2, TIAN Yan wen(田彦文) 2 1. Teachers College, Shenyang University, Shenyang 110015, P.R.China 2. College of Material and Metallurgy, Northeastern University, Shenyang 110006, P.R.China 《中国有色金属学会会刊:英文版》 CSCD 2000年第3期386-388,共3页
A new lithium ion battery cathode material, composite oxide LiNi y Co z Mn 1- y-z O 2, was synthesized. The structure and physical properties of the material, including composition, distribution of size, density and s... A new lithium ion battery cathode material, composite oxide LiNi y Co z Mn 1- y-z O 2, was synthesized. The structure and physical properties of the material, including composition, distribution of size, density and specific surface area, were discussed. The characteristic of charge and discharge, reversible specific capacity and cycle property were also studied. The relationship between the structure and properties of the composite oxides was explored. The results show that the composite oxide with a reasonable composition is beneficial to the improvement and enhancement of the properties. 展开更多
关键词 LITHIUM ION BATTERIES cathodic material LiNi Y Mn 1- y-z O 2 LiNiO 2
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Crystal structure and thermochemical properties of bis(1-octylammonium) tetrachlorochromate phase change materials
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作者 卢冬飞 邸友莹 何东华 《Chinese Physics B》 SCIE EI CAS CSCD 2012年第8期126-133,共8页
A new crystalline complex (C8H17NH3)2CdCI4(s) (abbreviated as CsCd(s)) is synthesized by liquid phase reaction. The crystal structure and composition of the complex are determined by single crystal X-ray diffr... A new crystalline complex (C8H17NH3)2CdCI4(s) (abbreviated as CsCd(s)) is synthesized by liquid phase reaction. The crystal structure and composition of the complex are determined by single crystal X-ray diffraction, chemical analysis, and elementary analysis. It is triclinic, the space group is P-1 and Z = 2. The lattice potential energy of the title complex is calculated to be UpoT (CsCd(s))=978.83 kJ.mol^-1 from crystallographic data. Low-temperature heat capacities of the complex are measured by using a precision automatic adiabatic calorimeter over a temperature range from 78 K to 384 K. The temperature, molar enthalpy, and entropy of the phase transition for the complex are determined to be 307.3±0.15 K, 10.15±0.23 kJ.mol^-1, and 33.054-0.78 J.K^-1.mol^-1 respectively for the endothermic peak. Two polynomial equations of the heat capacities each as a function of temperature are fitted by using the leastsquare method. Smoothed heat capacity and thermodynamic functions of the complex are calculated based on the fitted polynomials. 展开更多
关键词 bis(1-octylammonium) tetrachlorochromate X-ray crystallography phase change materials low-temperature heat capacity solid-solid phase transition
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Preparation and Properties of 1-octadecanol/1,3:2,4-di-(3,4-dimethyl) Benzylidene Sorbitol/Expanded Graphite Form-stable Composite Phase Change Material
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作者 XU Jun CHENG Xiaomin 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2019年第3期728-735,共8页
A 1-octadecanol(OD)/1,3:2,4-di-(3,4-dimethyl) benzylidene sorbitol(DMDBS)/expander graphite(EG) composite was prepared as a form-stable phase change material(PCM) by vacuum melting method. The results of fie... A 1-octadecanol(OD)/1,3:2,4-di-(3,4-dimethyl) benzylidene sorbitol(DMDBS)/expander graphite(EG) composite was prepared as a form-stable phase change material(PCM) by vacuum melting method. The results of field emission-scanning electron microscopy(FE-SEM) showed that 1-octadecanol was restricted in the three-dimensional network formed by DMDBS and the honeycomb network formed by EG. X-ray diffraction(XRD) and Fourier transform infrared spectroscopy(FT-IR) results showed that no chemical reaction occurred among the components of composite PCM in the preparation process. The gel-to-sol transition temperature of the composite PCMs containing DMDBS was much higher than the melting point of pure 1-octadecanol. The improvements in preventing leakage and thermal stability limits were mainly attributed to the synergistic effect of the three-dimensional network formed by DMDBS and the honeycomb network formed by EG. Differential scanning calorimeter(DSC) was used to determine the latent heat and phase change temperature of the composite PCMs. During melting and freezing process the latent heat values of the PCM with the composition of 91% OD/3% DMDBS/6% EG were 214.9 and 185.9 kJ·kg-1, respectively. Its degree of supercooling was only 0.1 ℃. Thermal constant analyzer results showed that its thermal conductivity(κ) changed up to roughly 10 times over that of OD/DMDBS matrix. 展开更多
关键词 1-octadecanol 1 3 4-di-(3 4-dimethyl) benzylidene sorbitol expander graphite composite phase change materials synergistic effect GELATOR
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OBD-1(黑色)可逆热致变色微胶囊制备及其在防伪领域的应用 被引量:1
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作者 薛盛 张玄 +5 位作者 何淋波 李莉 钟丽桢 黄少波 易耀辉 邵友元 《山东化工》 CAS 2024年第6期64-67,71,共5页
当今社会,假冒伪劣产品泛滥,给社会经济带来严重的负面影响。旨在研发一种灵敏度高、温变区间小、耐酸耐碱的OBD-1(黑色)可逆热致变色微胶囊,并将其应用在温变防伪涂料。选取黑色发色剂OBD-1、双酚A、十六醇为芯材料,脲醛树脂为壁材料,... 当今社会,假冒伪劣产品泛滥,给社会经济带来严重的负面影响。旨在研发一种灵敏度高、温变区间小、耐酸耐碱的OBD-1(黑色)可逆热致变色微胶囊,并将其应用在温变防伪涂料。选取黑色发色剂OBD-1、双酚A、十六醇为芯材料,脲醛树脂为壁材料,通过原位聚合法制备微胶囊。利用显微镜观察微胶囊的外部形貌,通过激光粒径测定仪对微胶囊粒径及粒径分布范围进行了测定,考察了微胶囊制备时的不同的制备条件对微胶囊粒径大小和样品性能的影响,并得到最佳制备比例。 展开更多
关键词 微胶囊 热敏黑OBD-1 有机热致变色材料 原位聚合法
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