It is the core to improve the electron/ion transfer features of Li_(4)Ti_(5)O_(12) for achieving high-rate anode in lithium ion batteries.By directly using graphite oxide powder,nano-Li_(4)Ti_(5)O_(12)/reduced graphit...It is the core to improve the electron/ion transfer features of Li_(4)Ti_(5)O_(12) for achieving high-rate anode in lithium ion batteries.By directly using graphite oxide powder,nano-Li_(4)Ti_(5)O_(12)/reduced graphite oxide composite with mesopore-oriented porosity is prepared through one-pot facile ball-milling method in this work.Synthesis mechanism underlying the self-nucleophilic effect of oxygen-containing functional groups in graphite oxide is substantiated.Reactants can intercalate into graphite oxide bulk and in-situ generate nanoparticles.Subsequently,graphite oxide with nanoparticles generated inside can obtain a mesopore-oriented porous structure under ball-milling.Furthermore,the synergistic effects of Li_(4)Ti_(5)O_(12) nanoparticles and mesopore-oriented porosity strengthen composites with rapid Li^(+)diffusion and electron conductive frameworks.The obtained optimal LTO/GO-1.75 composite displays excellent high-rate capability(136 mA·h/g at 7000 mA/g)and good cycling stability(a capacity retention of 72%after 1000 cycles at 7000 mA/g).Additionally,the reactants concentration in this demonstrated strategy is as high as 30 wt%−40 wt%,which is over 6 times that of traditional methods with GO suspensions.It means that the strategy can significantly increase the yield,showing big potential for large-scale production.展开更多
Weak stratospheric polar vortex(WPV)events during winter months were investigated.WPV events were identified as being weakest in December,accompanied by the most dramatic increase in geopotential height over the polar...Weak stratospheric polar vortex(WPV)events during winter months were investigated.WPV events were identified as being weakest in December,accompanied by the most dramatic increase in geopotential height over the polar region.After the onset of a December WPV event,the dynamic processes influencing Eurasian temperature can be split into two separate periods.Period I(lag of 0-25 days)is referred to as the stratosphere-troposphere interactions period,as it is mainly characterized by stratospheric signals propagating downwards.In Period I,a stratospheric negative Northern Annular Mode(NAM)pattern associated with the WPV propagates downwards,inducing a negative NAM in the troposphere.The anomalous low centers over the Mediterranean and North Pacific bring cold advection to northern Eurasia,resulting in a north-cold-south-warm dipole pattern over Eurasia.The zero line between negative and positive temperature anomalies moves southwards during days 5-20.Stratospheric cold anomalies at midlatitudes propagate downwards to high latitudes in the troposphere and contribute to the dipole structure.During PeriodⅡ(lag of 25-40 days),as downward signals from the stratosphere have vanished,the dynamic processes mainly take place within the troposphere.Specifically,a wave train is initiated from the North Atlantic region to northern Europe.The propagation of wave activity flux intensifies a cyclonic anomaly over northern Europe,which brings cold advection to Scandinavia and warm advection to central Asia.Therefore,a northwest-cold-southeast-warm dipole structure occupies Eurasia and migrates southeastwards during this period.展开更多
基金Project(21875283) supported by the the National Natural Science Foundation of China。
文摘It is the core to improve the electron/ion transfer features of Li_(4)Ti_(5)O_(12) for achieving high-rate anode in lithium ion batteries.By directly using graphite oxide powder,nano-Li_(4)Ti_(5)O_(12)/reduced graphite oxide composite with mesopore-oriented porosity is prepared through one-pot facile ball-milling method in this work.Synthesis mechanism underlying the self-nucleophilic effect of oxygen-containing functional groups in graphite oxide is substantiated.Reactants can intercalate into graphite oxide bulk and in-situ generate nanoparticles.Subsequently,graphite oxide with nanoparticles generated inside can obtain a mesopore-oriented porous structure under ball-milling.Furthermore,the synergistic effects of Li_(4)Ti_(5)O_(12) nanoparticles and mesopore-oriented porosity strengthen composites with rapid Li^(+)diffusion and electron conductive frameworks.The obtained optimal LTO/GO-1.75 composite displays excellent high-rate capability(136 mA·h/g at 7000 mA/g)and good cycling stability(a capacity retention of 72%after 1000 cycles at 7000 mA/g).Additionally,the reactants concentration in this demonstrated strategy is as high as 30 wt%−40 wt%,which is over 6 times that of traditional methods with GO suspensions.It means that the strategy can significantly increase the yield,showing big potential for large-scale production.
基金supported by the National Natural Science Foundation of China [grant numbers 41730964,41575079,and 41421004]
文摘Weak stratospheric polar vortex(WPV)events during winter months were investigated.WPV events were identified as being weakest in December,accompanied by the most dramatic increase in geopotential height over the polar region.After the onset of a December WPV event,the dynamic processes influencing Eurasian temperature can be split into two separate periods.Period I(lag of 0-25 days)is referred to as the stratosphere-troposphere interactions period,as it is mainly characterized by stratospheric signals propagating downwards.In Period I,a stratospheric negative Northern Annular Mode(NAM)pattern associated with the WPV propagates downwards,inducing a negative NAM in the troposphere.The anomalous low centers over the Mediterranean and North Pacific bring cold advection to northern Eurasia,resulting in a north-cold-south-warm dipole pattern over Eurasia.The zero line between negative and positive temperature anomalies moves southwards during days 5-20.Stratospheric cold anomalies at midlatitudes propagate downwards to high latitudes in the troposphere and contribute to the dipole structure.During PeriodⅡ(lag of 25-40 days),as downward signals from the stratosphere have vanished,the dynamic processes mainly take place within the troposphere.Specifically,a wave train is initiated from the North Atlantic region to northern Europe.The propagation of wave activity flux intensifies a cyclonic anomaly over northern Europe,which brings cold advection to Scandinavia and warm advection to central Asia.Therefore,a northwest-cold-southeast-warm dipole structure occupies Eurasia and migrates southeastwards during this period.
