The corrosion behaviors of 1420 and 2195 Al-Li alloys under 308 and 490 MPa tensile stress respectively in neutral 3.5% NaCl solution were investigated using electrochemical impedance spectroscopy(EIS) and scanning el...The corrosion behaviors of 1420 and 2195 Al-Li alloys under 308 and 490 MPa tensile stress respectively in neutral 3.5% NaCl solution were investigated using electrochemical impedance spectroscopy(EIS) and scanning electron microscope(SEM). It is found that the unstressed 1420 alloy is featured with large and discrete pits, while general corrosion and localized corrosion including intergranular corrosion and pitting corrosion occur on the unstressed 2195 alloy. As stress is applied to 1420 alloy, the pit becomes denser and its size is decreased. While, for the stressed 2195 alloy, intergranular corrosion is greatly aggravated and severe general corrosion is developed from connected pits. The EIS analysis shows that more severe general corrosion and localized corrosion occur on the stressed 2195 Al-Li alloy than on 1420 Al-Li alloy. It is suggested that tensile stress has greater effect on the corrosion of 2195 Al-Li alloy than on 1420 Al-Li alloy.展开更多
True stress-true strain curve,microstructure and texture information were obtained to investigate the superplastic deformation behavior of 1420 Al-Li alloy sheets with initial elongated grains.From the true stress-tru...True stress-true strain curve,microstructure and texture information were obtained to investigate the superplastic deformation behavior of 1420 Al-Li alloy sheets with initial elongated grains.From the true stress-true curve,the stress increases with the increase of strain to 0.15,then dramatically decreases with the increase of strain to 0.80,and finally keeps almost a horizontal line.Meanwhile,initial elongated grains are gradually changed into equiaxed grains and the initial strong Brass {0 1 1} <2 1 1> and S {1 2 3} <6 3 4> orientations are turned into nearly random orientation with increasing strain.All these results suggest that dislocation activity is the dominant mechanism during the first stage,then dynamic recrystallization occurs,and grain rotation is expected as an accommodation for grain boundary sliding(GBS).At larger strains,grain boundary migration(GBM) becomes necessary to accommodate GBS.展开更多
A nanostructured surface layer was fabricated on 1420 aluminum alloy by high-energy shot peening.Microstructures were characterized by X-ray diffractometer (XRD), transmission electron microscope (TEM) and high-resolu...A nanostructured surface layer was fabricated on 1420 aluminum alloy by high-energy shot peening.Microstructures were characterized by X-ray diffractometer (XRD), transmission electron microscope (TEM) and high-resolution electron microscope(HRTEM), and microhardness measurement was conducted along the depth from top surface layer to matrix of the sample peened for 30 min. The results show that a nanocrystalline layer about 20 μm in thickness is formed on the surface of the sample after high-energy shot peening, in which the grain size is changed from about 20 nm to 100 nm. In the surface layer of 20 -50 μm in depth, the microstructure consists of submicron grains. The surface nanocrystallization is accomplished by dislocation slip. The microhardness of the top surface nanostructured layer is enhanced obviously after high-energy shot peening(HESP) compared with that of the coarse-grained matrix.展开更多
Effect of trace rare earth Er addition on the aging behavior of 1420 alloys was studied using hardness testing. Precipitation behavior during aging was investigated by electron microscopy transmission. It is found tha...Effect of trace rare earth Er addition on the aging behavior of 1420 alloys was studied using hardness testing. Precipitation behavior during aging was investigated by electron microscopy transmission. It is found that small amounts of Er can modify the aging behavior of 1420 alloy, for example, improve the hardness and shift peak aging time. All those results may be attributed to the increase of diffusion coefficient of Li atom in the Al matrix added with Er. As a consequence, rate of nucleation and growth of δ′ (Al_3Li) was promoted; the Al_3Er particles act as preferential sites for the nucleation and growth of δ′, which in turn results in the presentation of more composite particles.展开更多
The thresholds of short fatigue cracks for aluminum-lithium alloys 2090 and 2090+Ce are quantitatively evaluated. The essential reason resulting in stronger short crack effect has been ascertained. Influence of cerium...The thresholds of short fatigue cracks for aluminum-lithium alloys 2090 and 2090+Ce are quantitatively evaluated. The essential reason resulting in stronger short crack effect has been ascertained. Influence of cerium on the threshold of short fatigue cracks for aluminum-lithium alloy 2090 was investigated. The results show that, by adding Ce into this alloy, DeltaK(i) and DeltaK(Cl.th) are increased. The influence mechanism of Ce on the threshold of short fatigue crack for alloy 2090 was explored fi om the bound energy, T, phase, the energy of anti-phase boundary, the energy of super-lattice intrinsic stacking fault and the electron bonds. By adding Ce into alloy 2090, the bound energy of Cu atom in this alloy is increased; the effect of thinning and dispersing T, phase is obtained; the effect of increasing the energy of anti-phase boundary and decreasing the energy of super-lattice intrinsic stacking fault for delta ' phase can be achieved.展开更多
Due to the large unexplored compositional space,long development cycle,and high cost of traditional trial-anderror experiments,designing high strength aluminum-lithium alloys is a great challenge.This work establishes...Due to the large unexplored compositional space,long development cycle,and high cost of traditional trial-anderror experiments,designing high strength aluminum-lithium alloys is a great challenge.This work establishes a performance-oriented machine learning design strategy for aluminum-lithium alloys to simplify and shorten the development cycle.The calculation results indicate that radial basis function(RBF)neural networks exhibit better predictive ability than back propagation(BP)neural networks.The RBF neural network predicted tensile and yield strengths with determination coefficients of 0.90 and 0.96,root mean square errors of 30.68 and 25.30,and mean absolute errors of 28.15 and 19.08,respectively.In the validation experiment,the comparison between experimental data and predicted data demonstrated the robustness of the two neural network models.The tensile and yield strengths of Al-2Li-1Cu-3Mg-0.2Zr(wt.%)alloy are 17.8 and 3.5 MPa higher than those of the Al-1Li4.5Cu-0.2Zr(wt.%)alloy,which has the best overall performance,respectively.It demonstrates the reliability of the neural network model in designing high strength aluminum-lithium alloys,which provides a way to improve research and development efficiency.展开更多
基金Project(50401012) supported by the National Natural Science Foundation of China
文摘The corrosion behaviors of 1420 and 2195 Al-Li alloys under 308 and 490 MPa tensile stress respectively in neutral 3.5% NaCl solution were investigated using electrochemical impedance spectroscopy(EIS) and scanning electron microscope(SEM). It is found that the unstressed 1420 alloy is featured with large and discrete pits, while general corrosion and localized corrosion including intergranular corrosion and pitting corrosion occur on the unstressed 2195 alloy. As stress is applied to 1420 alloy, the pit becomes denser and its size is decreased. While, for the stressed 2195 alloy, intergranular corrosion is greatly aggravated and severe general corrosion is developed from connected pits. The EIS analysis shows that more severe general corrosion and localized corrosion occur on the stressed 2195 Al-Li alloy than on 1420 Al-Li alloy. It is suggested that tensile stress has greater effect on the corrosion of 2195 Al-Li alloy than on 1420 Al-Li alloy.
基金Project(2006DFA53250) supported by the International Science and Technology Cooperation Program of ChinaProject(2005CB623706) supported by the National Basic Research Program of China
文摘True stress-true strain curve,microstructure and texture information were obtained to investigate the superplastic deformation behavior of 1420 Al-Li alloy sheets with initial elongated grains.From the true stress-true curve,the stress increases with the increase of strain to 0.15,then dramatically decreases with the increase of strain to 0.80,and finally keeps almost a horizontal line.Meanwhile,initial elongated grains are gradually changed into equiaxed grains and the initial strong Brass {0 1 1} <2 1 1> and S {1 2 3} <6 3 4> orientations are turned into nearly random orientation with increasing strain.All these results suggest that dislocation activity is the dominant mechanism during the first stage,then dynamic recrystallization occurs,and grain rotation is expected as an accommodation for grain boundary sliding(GBS).At larger strains,grain boundary migration(GBM) becomes necessary to accommodate GBS.
文摘A nanostructured surface layer was fabricated on 1420 aluminum alloy by high-energy shot peening.Microstructures were characterized by X-ray diffractometer (XRD), transmission electron microscope (TEM) and high-resolution electron microscope(HRTEM), and microhardness measurement was conducted along the depth from top surface layer to matrix of the sample peened for 30 min. The results show that a nanocrystalline layer about 20 μm in thickness is formed on the surface of the sample after high-energy shot peening, in which the grain size is changed from about 20 nm to 100 nm. In the surface layer of 20 -50 μm in depth, the microstructure consists of submicron grains. The surface nanocrystallization is accomplished by dislocation slip. The microhardness of the top surface nanostructured layer is enhanced obviously after high-energy shot peening(HESP) compared with that of the coarse-grained matrix.
文摘Effect of trace rare earth Er addition on the aging behavior of 1420 alloys was studied using hardness testing. Precipitation behavior during aging was investigated by electron microscopy transmission. It is found that small amounts of Er can modify the aging behavior of 1420 alloy, for example, improve the hardness and shift peak aging time. All those results may be attributed to the increase of diffusion coefficient of Li atom in the Al matrix added with Er. As a consequence, rate of nucleation and growth of δ′ (Al_3Li) was promoted; the Al_3Er particles act as preferential sites for the nucleation and growth of δ′, which in turn results in the presentation of more composite particles.
文摘The thresholds of short fatigue cracks for aluminum-lithium alloys 2090 and 2090+Ce are quantitatively evaluated. The essential reason resulting in stronger short crack effect has been ascertained. Influence of cerium on the threshold of short fatigue cracks for aluminum-lithium alloy 2090 was investigated. The results show that, by adding Ce into this alloy, DeltaK(i) and DeltaK(Cl.th) are increased. The influence mechanism of Ce on the threshold of short fatigue crack for alloy 2090 was explored fi om the bound energy, T, phase, the energy of anti-phase boundary, the energy of super-lattice intrinsic stacking fault and the electron bonds. By adding Ce into alloy 2090, the bound energy of Cu atom in this alloy is increased; the effect of thinning and dispersing T, phase is obtained; the effect of increasing the energy of anti-phase boundary and decreasing the energy of super-lattice intrinsic stacking fault for delta ' phase can be achieved.
基金supported by the National Natural Science Foundation of China(Nos.52074246,52275390,52205429,52201146)National Defense Basic Scientific Research Program of China(JCKY2020408B002)Key Research and Development Program of Shanxi Province(202102050201011,202202050201014).
文摘Due to the large unexplored compositional space,long development cycle,and high cost of traditional trial-anderror experiments,designing high strength aluminum-lithium alloys is a great challenge.This work establishes a performance-oriented machine learning design strategy for aluminum-lithium alloys to simplify and shorten the development cycle.The calculation results indicate that radial basis function(RBF)neural networks exhibit better predictive ability than back propagation(BP)neural networks.The RBF neural network predicted tensile and yield strengths with determination coefficients of 0.90 and 0.96,root mean square errors of 30.68 and 25.30,and mean absolute errors of 28.15 and 19.08,respectively.In the validation experiment,the comparison between experimental data and predicted data demonstrated the robustness of the two neural network models.The tensile and yield strengths of Al-2Li-1Cu-3Mg-0.2Zr(wt.%)alloy are 17.8 and 3.5 MPa higher than those of the Al-1Li4.5Cu-0.2Zr(wt.%)alloy,which has the best overall performance,respectively.It demonstrates the reliability of the neural network model in designing high strength aluminum-lithium alloys,which provides a way to improve research and development efficiency.
