Phase Equilibrium Characteristics of CO_(2)and Ionic Liquids with[FAP]-Anion Used for Absorption-Compression Refrigeration Working Pairs

The study of the phase equilibrium characteristics of CO_(2)-ionic liquids(ILs)as new absorption-compression type refrigeration working pairs is of great importance.Three kinds of ILs,i.e.,[emim][FAP],[bmim][FAP]and[hmim][FAP],were chosen as potential absorbents.The solubility of CO_(2)in these ILs was measured experimentally within 0 to 5.0 MPa at temperatures of 293.15 K to 333.15 K,and the effects of temperature,pressure,IL anion and cation structure and stirring action on CO_(2)solubility were also discussed and analyzed.The results showed that the longer alkyl chains in an identical IL family,the alkyl fluoride group in IL anions and the stirring action by a magnetic stirrer had positive effects on the solubility of CO_(2).In the three ILs,[hmim][FAP]possessed the best performance for CO_(2)absorption;the solubility of CO_(2)reached 0.7641 at a pressure of 5 MPa and temperature of 293.15 K,the maximum solubility measured in this work.The CO_(2)-[hmim][FAP]binary mixture is recommended as a potentially applicable working pair for CO_(2)absorption-compression refrigeration systems.

基于极限平衡法的金川泄洪洞稳定性分析

以金川水电站泄洪洞进口边坡稳定性分析为目标,基于三维极限平衡法,考虑金川水电站泄洪洞进口边坡附近的四组优势结构面之间不同组合形式和不同排列次序,利用赤平投影原理对优势结构面进行定性分析并利用极限平衡法进行定量分析;基于二维极限平衡理论和方法,对泄洪洞进口边坡在开挖、蓄水、蓄水+暴雨+设计地震、蓄水+暴雨+校核地震4种工况下的稳定性进行分析。计算结果表明,三维稳定性分析中楔形体按倾向和倾角分别为336°∠60°、75°∠33°和237°∠65°的结构产状组合时,所产生的楔形体在开挖、饱水、设计地震、校核地震四种工况下的安全系数最低达到1.90,但仍符合设计规范要求。二维稳定性分析中,在蓄水+暴雨+校核地震工况下,边坡安全系数最低达到1.368,开挖扰动后变形体的强度能满足工程要求。对比两种分析方法,三维稳定性分析得出的安全系数均大于二维稳定性分析得出的安全系数,说明二维极限平衡法计算的结果更加偏于安全,但是同时也会增大工程的造价。