层状KTi Nb O5因具有离子可交换、层间结构均一可控等优点而引起了广泛的关注。采用高温固相法制备的KTi Nb O5为前驱体,经H+交换、剥离改性制备出HTi Nb O5纳米片并以其作为基体材料与Fe2O3纳米粒子复合制备出e-HTi Nb O5@Fe2O3纳米复...层状KTi Nb O5因具有离子可交换、层间结构均一可控等优点而引起了广泛的关注。采用高温固相法制备的KTi Nb O5为前驱体,经H+交换、剥离改性制备出HTi Nb O5纳米片并以其作为基体材料与Fe2O3纳米粒子复合制备出e-HTi Nb O5@Fe2O3纳米复合材料。采用XRD、Raman、BET、HRTEM、TG-DSC和UV-vis DRS对样品的结构和光响应特征进行表征。结果表明,e-HTi Nb O5@Fe2O3保留了主体纳米片聚集体的孔隙结构特征,客体材料分散于主体材料表面,并与主体纳米片上的活性官能团之间发生相互作用,导致主体纳米片的热稳定性增加。另外,e-HTi Nb O5@Fe2O3的BET表面积明显增加的同时,其在可见光区有明显的吸收,禁带宽度为2.08 e V,该纳米复合材料在自然光辐射下可将乙硫醇光催化氧化为磺酸盐。展开更多
The third-order optical nonlinearities, includ- ing third-order nonlinear susceptibility χ(3), nonlinear refrac- tive index (n2) and temporal response, were measured with forward DFWM using Nd:YAG mode-locked pulse l...The third-order optical nonlinearities, includ- ing third-order nonlinear susceptibility χ(3), nonlinear refrac- tive index (n2) and temporal response, were measured with forward DFWM using Nd:YAG mode-locked pulse laser. The results show that Eu2O3 doped 5ZnO-20Nb2O5-75TeO2 glasses have large n2 and ultra-fast temporal response. Ra- man spectra show that Eu2O3 dopant induces the changes in the local structure of glasses. The higher the dopant concen- tration, the larger the nonlinear refractive n2 and the faster the temporal response. The enhancement on the third-order optical nonlinearities can be attributed to the deformation of the electronic clouds in [TeO4] enhanced by Eu2O3 dopant.展开更多
文摘层状KTi Nb O5因具有离子可交换、层间结构均一可控等优点而引起了广泛的关注。采用高温固相法制备的KTi Nb O5为前驱体,经H+交换、剥离改性制备出HTi Nb O5纳米片并以其作为基体材料与Fe2O3纳米粒子复合制备出e-HTi Nb O5@Fe2O3纳米复合材料。采用XRD、Raman、BET、HRTEM、TG-DSC和UV-vis DRS对样品的结构和光响应特征进行表征。结果表明,e-HTi Nb O5@Fe2O3保留了主体纳米片聚集体的孔隙结构特征,客体材料分散于主体材料表面,并与主体纳米片上的活性官能团之间发生相互作用,导致主体纳米片的热稳定性增加。另外,e-HTi Nb O5@Fe2O3的BET表面积明显增加的同时,其在可见光区有明显的吸收,禁带宽度为2.08 e V,该纳米复合材料在自然光辐射下可将乙硫醇光催化氧化为磺酸盐。
文摘The third-order optical nonlinearities, includ- ing third-order nonlinear susceptibility χ(3), nonlinear refrac- tive index (n2) and temporal response, were measured with forward DFWM using Nd:YAG mode-locked pulse laser. The results show that Eu2O3 doped 5ZnO-20Nb2O5-75TeO2 glasses have large n2 and ultra-fast temporal response. Ra- man spectra show that Eu2O3 dopant induces the changes in the local structure of glasses. The higher the dopant concen- tration, the larger the nonlinear refractive n2 and the faster the temporal response. The enhancement on the third-order optical nonlinearities can be attributed to the deformation of the electronic clouds in [TeO4] enhanced by Eu2O3 dopant.
