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2-巯甲基噻吩与[Mn_2(CO)_(10)]原子簇化合物反应生成[MnS(CO)_3]_4及结构表征(英文)
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作者 张岐 郝红元 DeemingAntonyJ 《无机化学学报》 SCIE CAS CSCD 北大核心 2004年第10期1241-1244,共4页
The compound reacts with 2-(Methylthio)thiophene (C5H6S2) while refluxing in xylene to afford a methylthio-tetramanganese product 4, in which C5H6S2 is cleaved with loss of thiophene. The crystal structure of 4 has be... The compound reacts with 2-(Methylthio)thiophene (C5H6S2) while refluxing in xylene to afford a methylthio-tetramanganese product 4, in which C5H6S2 is cleaved with loss of thiophene. The crystal structure of 4 has been studied by direct method. Based on the 21 685 unique reflections collected using MoKα of X-ray radiation and a CCD-based detector, it is refined to an agreement index (R1) of 0.079 0. The cell is triclinic with dimensions: a=1.719 49 nm, b=1.959 2 nm, c=2.632 6 nm and α=79.733°, β=71.407°, γ=89.387°. There are 12 unit cells of 4 in the cell, with space group P1. 展开更多
关键词 2-巯甲基噻吩 原子簇化合物 晶体结构 锰化合物 C-S键断裂 [MnS(CO)3]4
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