Polymer photovoltaic devices based on poly (2- methoxy-5-(2′ -ethyl-hexyloxy)-1,4-phenylene vinylene) (MEH- PPV) with three weight-average molecular weights (Mw) have been fabricated with the device structure of ITO/...Polymer photovoltaic devices based on poly (2- methoxy-5-(2′ -ethyl-hexyloxy)-1,4-phenylene vinylene) (MEH- PPV) with three weight-average molecular weights (Mw) have been fabricated with the device structure of ITO/PEDOT/ MEH-PPV/Ca/Ag, and the effect of the molecular weight on photovoltaic properties has been investigated. The experi- mental results show that the high molecular weight of MEH- PPV leads to low series resistance (Rs) and high short-circuit current. The low molecular weight of MEH-PPV leads to high shunt resistance (Rsh) and high open-circuit voltage. When the molecular weight is 6×105, the highest power con- version efficiency was observed.展开更多
文摘Polymer photovoltaic devices based on poly (2- methoxy-5-(2′ -ethyl-hexyloxy)-1,4-phenylene vinylene) (MEH- PPV) with three weight-average molecular weights (Mw) have been fabricated with the device structure of ITO/PEDOT/ MEH-PPV/Ca/Ag, and the effect of the molecular weight on photovoltaic properties has been investigated. The experi- mental results show that the high molecular weight of MEH- PPV leads to low series resistance (Rs) and high short-circuit current. The low molecular weight of MEH-PPV leads to high shunt resistance (Rsh) and high open-circuit voltage. When the molecular weight is 6×105, the highest power con- version efficiency was observed.
