用离子交换法分离β盐母液中2-萘磺酸钠

采用阴离子交换树脂回收β盐母液中的２－萘磺酸钠（以下简称β盐），进行了ｐＨ值、接触时间、交换温度、共存阴离子等影响因素的条件实验及树脂再生实验，得到β盐收率６０％以上。

2-萘酚生产对环境的影响及废水处理工艺研究

分析了2-萘酚生产现状、市场形势及污水特点,在总结当前2-萘酚生产废水处理工艺研究状况的基础上,提出了处理2-萘酚污水的双效蒸发—冷凝结晶工艺。该工艺回收2萘磺酸钠并加以再利用,回收率可达到50%以上,余下的浓缩液可用于生产硫酸钠。实践表明,经该工艺处理的排放污水,其净化程度达到国家污水排放二级标准。

Solubilities of 2-Naphthalenesulfonic Acid Monohydrate and Sodium 2-Naphthalenesulfonate in Sulfuric Acid Solution and Their Application for Preparing Sodium 2-Naphthalenesulfonate

The solubilities of 2-naphthalenesulfonic acid monohydrate and sodium 2-naphthalenesulfonate in sulfuric acid solutions were measured at temperatures ranging from 278.15 to 338.15 K by using a dynamic method. The concentration of sulfuric acid solution ranged from 0 to 80wt%,. The solubilities of 2-naphthalenesulfonic acid monohydrate and sodium 2-naphthalenesulfonate increased with temperature, and both of them were the lowest at 70wt %, of sulfuric acid solution(w^0_3 =0.70)while the highest in pure water. The solubility data were correlated by the modified Apelblat equation. Based on the solubility difference between 2-naphthalenesulfonic acid monohydrate and sodium 2-naphthalenesulfonate, a new technique in which sodium sulfate was used to replace sodium sulfite in the neutralization reaction was developed. The suitable mole ratio of H_2O to Na_2SO_4 in the neutralization reaction was 80∶1, and that of 2-naphthalenesulfonic acid monohydrate to Na_2SO_4 was 3.2∶1. The material balance under the suitable mole ratios was given and discussed.

溶剂对TNS与ANS荧光光谱的影响

研究了两种光谱探针TNS与ANS在不同溶剂中的荧光光谱,为此类荧光探针的应用奠定了一定的基础。结果表明溶剂对TNS与ANS荧光光谱的影响是一般溶剂效应与特殊溶剂效应共同作用的结果。