The solvothermal reaction of 3-amino-1H-1,2,4-triazole （ttr） with Zn（ClO4）2·6H2O and NaCl in a 1：1：1 molar ratio gave a new complex [Zn（ttr）Cl]n with a 3-connected （4.82） 2-D structure. The layers stack...The solvothermal reaction of 3-amino-1H-1,2,4-triazole （ttr） with Zn（ClO4）2·6H2O and NaCl in a 1：1：1 molar ratio gave a new complex [Zn（ttr）Cl]n with a 3-connected （4.82） 2-D structure. The layers stack in the -ABAB- way along the c axis with abundant hydrogen bonding interactions to form the crystal structure. The complex [Zn（ttr）Cl]n crystallizes in the orthorhombic space group Pbca with a = 9.369（1）, b = 10.049（1）, c = 11.905（1）A, V = 1120.9（3）A^3, Z = 8.00, C2N4H3ZnCl, Mr = 183.90, Dc = 2.180 g/cm^3,μ = 4.740 mm^-1, F（000） = 720, S = 1.059 and T = 293（2） K. The final R = 0.0662 and wR = 0.2457 for 956 observed reflections with Ⅰ〉 2σ（Ⅰ）, and R = 0.0689 and wR = 0.2504 for all data.展开更多
Two new coordination polymers,[Co（BYBA）2（4,4＇-bpy）（H2O）2]·H2O （1） and [Zn（BYBA）2（4,4＇-bpy）] （2） （4,4＇-bpy=4,4＇-bipyridine,BYBAH= 2-benzoylbenzoic acid）,have been synthesized by hydrothermal co...Two new coordination polymers,[Co（BYBA）2（4,4＇-bpy）（H2O）2]·H2O （1） and [Zn（BYBA）2（4,4＇-bpy）] （2） （4,4＇-bpy=4,4＇-bipyridine,BYBAH= 2-benzoylbenzoic acid）,have been synthesized by hydrothermal conditions and characterized by single-crystal X-ray diffraction,elemental analyses,IR spectra and fluorescence spectrum.Crystal data for 1：C38H32CoN2O9,Mr= 719.59,monoclinic,space group P2/c,a=22.981（2）,b=11.4438（11）,c=12.9327（12）,β=94.642（1）°,V=3390.0（5）3,Z=4,Dc=1.410 g/cm3,F（000）=1492,R=0.0488 and wR=0.1201;and those for 2：C38H26ZnN2O6,Mr=672.00,triclinic,space group P1,a=8.7032（10）,b=11.4882（13）,c=16.872（2）,α=107.146（1）,β=99.055（1）,γ=90.851（2）°,V=1588.5（3）3,Z= 2,Dc=1.405 g/cm3,F（000）=692,R=0.0409 and wR=0.0894.Complex 1 exhibits 1D polymeric chains which are linked into a 2D sheet by π···π interactions.Complex 2 is composed by 1D zigzag chains connected through C-H···π stacking interactions to generate a 2D layer.展开更多
An event-triggered scheme is proposed to solve the problems of robust guaranteed cost control for a class of two-dimensional(2-D)discrete-time systems.Firstly,an eventtriggered scheme is proposed for 2-D discrete-time...An event-triggered scheme is proposed to solve the problems of robust guaranteed cost control for a class of two-dimensional(2-D)discrete-time systems.Firstly,an eventtriggered scheme is proposed for 2-D discrete-time systems with parameter uncertainties and sector nonlinearities.Then,according to the Lyapunov functional method,the sufficient conditions for the existence of event-triggered robust guaranteed cost controller for 2-D discrete-time systems with parameter uncertainties and sector nonlinearities are given.Furthermore,based on the sufficient conditions and the linear matrix inequality(LMI)technique,the problem of designing event-triggered robust guaranteed cost controller is transformed into a feasible solution problem of LMI.Finally,a numerical example is given to demonstrate that,under the proposed event-triggered robust guaranteed cost control,the closed-loop system is asymptotically stable and fewer communication resources are occupied.展开更多
A new approach for the design of two-dimensional （2-D） linear phase FIR digital filters based on a new neural networks algorithm （NNA） is provided. A compact expression for the transfer function of a 2-D linear ph...A new approach for the design of two-dimensional （2-D） linear phase FIR digital filters based on a new neural networks algorithm （NNA） is provided. A compact expression for the transfer function of a 2-D linear phase FIR filter is derived based on its frequency response characteristic, and the NNA, based on minimizing the square-error in the frequency-domain, is established according to the compact expression. To illustrate the stability of the NNA, the convergence theorem is presented and proved. Design examples are also given, and the results show that the ripple is considerably small in passband and stopband, and the NNA-based method is of powerful stability and requires quite little amount of computations.展开更多
The main river, the Dongting Lake and river networks in the Jingjiang reach of the Yangtze River constitute a complex water system, for which a full 2-D hydrodynamic model is established instead of the traditional 1-D...The main river, the Dongting Lake and river networks in the Jingjiang reach of the Yangtze River constitute a complex water system, for which a full 2-D hydrodynamic model is established instead of the traditional 1-D or compound models for simulation of such complex systems, based on the latest developments of computer technologies and numerical methods. To better handle irregular boundaries and keep the computation cost well in a reasonable limit, unstructured grids of moderate scale are used. In addition, a dynamic boundary tracking method is proposed to simulate variable flow domains at different floods, especially, when the moderate scale gird can not describe flows in narrow river-network channels at low water levels. The t9 semi-implicit method and the Eulerian-Lagrangian Method （ELM） are adopted, which make the model unconditionally stable with respect to the gravity wave speed and Courant number restrictions. Properties and efficiency of the model are discussed, and it is concluded that the new model is robust and efficient enough for the simulation of a big, complex water system. Validation tests show that the simulation results agree well with field data. It takes about 0.96 h to complete the computation of a 76 d flood, which indicates that the model is efficient enough for engineering applications.展开更多
A coupled one-dimensional （1-D） and two-dimensional （2-D） channel network mathematical model is proposed for flow calculations at nodes in a channel network system in this article. For the 1-D model, the finite di...A coupled one-dimensional （1-D） and two-dimensional （2-D） channel network mathematical model is proposed for flow calculations at nodes in a channel network system in this article. For the 1-D model, the finite difference method is used to discretize the Saint-Venant equations in all channels of a looped network. The Alternating Direction Implicit （ADI） method is adopted for the 2-D model at the nodes. In the coupled model, the 1-D model provides a good approximation with small computational effort, while the 2-D model is applied for complex topography to achieve a high accuracy. An Artificial Neural Network （ANN.） method is used for the data exchange and the connectivity between the 1-D and 2-D models. The coupled model is applied to the Jingjiang-Dongting Lake region, to simulate the tremendous looped channel network system, and the results are compared with field data. The good agreement shows that the coupled hydraulic model is more effective than the conventional 1-D model.展开更多
A novel 2-D supramolecular network formed by the Fe3O building unit through three hydrogen bonds [Fe3O(O2CCH2OC6H5)6(3H2O)]NO3·2H2O (1) are presented. The title complex crystallizes in monoclinic, space group P21...A novel 2-D supramolecular network formed by the Fe3O building unit through three hydrogen bonds [Fe3O(O2CCH2OC6H5)6(3H2O)]NO3·2H2O (1) are presented. The title complex crystallizes in monoclinic, space group P21/n, with a=1.709 3(2) nm, b=3.152 9(3) nm, c=1.021 2(2) nm, V=5.503 5(14) nm3, Z=4, D(calc)=1.500 g·cm-3, F(000)=2 564. Each Fe3O unit is connected by three NO3-ions and inversely each NO3-ion is surrounded by three Fe3O moieties. It shows that the well-known Fe3O unit is a potential three H-donors and may be able to be a three-connected linker. This complex displays weak anti-ferromagnetic coupling between Fe(Ⅲ) centers. Electrochemical experiments were carried out to obtain the character of its redox reaction. CCDC: 222011.展开更多
Comprehensive Summary Polycatenane gels have attracted extensive attention due to their high degree of freedom and mobility.However,the syntheses of poly[2]catenane gels reported to date all rely on the polymer as the...Comprehensive Summary Polycatenane gels have attracted extensive attention due to their high degree of freedom and mobility.However,the syntheses of poly[2]catenane gels reported to date all rely on the polymer as the backbone.Herein,we prepared poly[2]catenane gels based on entirely sequential assembly of small molecules.Monomer M1 with two unclosed rings was first prepared,which self-assembled to form supramolecular polymers(SPs)via hydrogen bonding andπ-πinteractions.Upon adding small molecule monomers M2 and M3 with aldehyde groups,ring closing of SPs occurred because the amino groups in the SPs reacted with M2 to form imine bonds.In addition,M3,which had twice the number of aldehyde groups as M2,enabled SPs to ring-close,causing the proceeding of crosslinking process at the same time.Thus linear SPs were transformed into poly[2]catenane gel networks.Due to the presence of hydrogen bonds in the poly[2]catenane gel,the gel also possessed stimulus responsiveness and self-healing properties.展开更多
基金The project was supported by the NNSFC (20571075, 20521101)the NSF for Distinguished Young Scientists of China (20425104) the NSF of Fujian Province (A0420002)
文摘The solvothermal reaction of 3-amino-1H-1,2,4-triazole （ttr） with Zn（ClO4）2·6H2O and NaCl in a 1：1：1 molar ratio gave a new complex [Zn（ttr）Cl]n with a 3-connected （4.82） 2-D structure. The layers stack in the -ABAB- way along the c axis with abundant hydrogen bonding interactions to form the crystal structure. The complex [Zn（ttr）Cl]n crystallizes in the orthorhombic space group Pbca with a = 9.369（1）, b = 10.049（1）, c = 11.905（1）A, V = 1120.9（3）A^3, Z = 8.00, C2N4H3ZnCl, Mr = 183.90, Dc = 2.180 g/cm^3,μ = 4.740 mm^-1, F（000） = 720, S = 1.059 and T = 293（2） K. The final R = 0.0662 and wR = 0.2457 for 956 observed reflections with Ⅰ〉 2σ（Ⅰ）, and R = 0.0689 and wR = 0.2504 for all data.
基金supported by the NNSFC (No. 20771023)the State 863 Program Project (No. 2007AA03z218)Analysis and Testing Foundation of Northeast Normal University
文摘Two new coordination polymers,[Co（BYBA）2（4,4＇-bpy）（H2O）2]·H2O （1） and [Zn（BYBA）2（4,4＇-bpy）] （2） （4,4＇-bpy=4,4＇-bipyridine,BYBAH= 2-benzoylbenzoic acid）,have been synthesized by hydrothermal conditions and characterized by single-crystal X-ray diffraction,elemental analyses,IR spectra and fluorescence spectrum.Crystal data for 1：C38H32CoN2O9,Mr= 719.59,monoclinic,space group P2/c,a=22.981（2）,b=11.4438（11）,c=12.9327（12）,β=94.642（1）°,V=3390.0（5）3,Z=4,Dc=1.410 g/cm3,F（000）=1492,R=0.0488 and wR=0.1201;and those for 2：C38H26ZnN2O6,Mr=672.00,triclinic,space group P1,a=8.7032（10）,b=11.4882（13）,c=16.872（2）,α=107.146（1）,β=99.055（1）,γ=90.851（2）°,V=1588.5（3）3,Z= 2,Dc=1.405 g/cm3,F（000）=692,R=0.0409 and wR=0.0894.Complex 1 exhibits 1D polymeric chains which are linked into a 2D sheet by π···π interactions.Complex 2 is composed by 1D zigzag chains connected through C-H···π stacking interactions to generate a 2D layer.
基金supported by the National Natural Science Foundation of China(61573129 U1804147)+2 种基金the Innovative Scientists and Technicians Team of Henan Provincial High Education(20IRTSTHN019)the Innovative Scientists and Technicians Team of Henan Polytechnic University(T2019-2 T2017-1)
文摘An event-triggered scheme is proposed to solve the problems of robust guaranteed cost control for a class of two-dimensional(2-D)discrete-time systems.Firstly,an eventtriggered scheme is proposed for 2-D discrete-time systems with parameter uncertainties and sector nonlinearities.Then,according to the Lyapunov functional method,the sufficient conditions for the existence of event-triggered robust guaranteed cost controller for 2-D discrete-time systems with parameter uncertainties and sector nonlinearities are given.Furthermore,based on the sufficient conditions and the linear matrix inequality(LMI)technique,the problem of designing event-triggered robust guaranteed cost controller is transformed into a feasible solution problem of LMI.Finally,a numerical example is given to demonstrate that,under the proposed event-triggered robust guaranteed cost control,the closed-loop system is asymptotically stable and fewer communication resources are occupied.
文摘A new approach for the design of two-dimensional （2-D） linear phase FIR digital filters based on a new neural networks algorithm （NNA） is provided. A compact expression for the transfer function of a 2-D linear phase FIR filter is derived based on its frequency response characteristic, and the NNA, based on minimizing the square-error in the frequency-domain, is established according to the compact expression. To illustrate the stability of the NNA, the convergence theorem is presented and proved. Design examples are also given, and the results show that the ripple is considerably small in passband and stopband, and the NNA-based method is of powerful stability and requires quite little amount of computations.
基金supported by the Eleventh"Five-Year Plan" Science and Technology Program of China(Grant No. 2008BAB29B08)the National Key Basic Research Program of China(973 Program,Grant No.2007CB714100)supported by the Yangtze River Scientific Research Institute project(Grant No.CKSQ2010075)
文摘The main river, the Dongting Lake and river networks in the Jingjiang reach of the Yangtze River constitute a complex water system, for which a full 2-D hydrodynamic model is established instead of the traditional 1-D or compound models for simulation of such complex systems, based on the latest developments of computer technologies and numerical methods. To better handle irregular boundaries and keep the computation cost well in a reasonable limit, unstructured grids of moderate scale are used. In addition, a dynamic boundary tracking method is proposed to simulate variable flow domains at different floods, especially, when the moderate scale gird can not describe flows in narrow river-network channels at low water levels. The t9 semi-implicit method and the Eulerian-Lagrangian Method （ELM） are adopted, which make the model unconditionally stable with respect to the gravity wave speed and Courant number restrictions. Properties and efficiency of the model are discussed, and it is concluded that the new model is robust and efficient enough for the simulation of a big, complex water system. Validation tests show that the simulation results agree well with field data. It takes about 0.96 h to complete the computation of a 76 d flood, which indicates that the model is efficient enough for engineering applications.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.10872110,10902061)
文摘A coupled one-dimensional （1-D） and two-dimensional （2-D） channel network mathematical model is proposed for flow calculations at nodes in a channel network system in this article. For the 1-D model, the finite difference method is used to discretize the Saint-Venant equations in all channels of a looped network. The Alternating Direction Implicit （ADI） method is adopted for the 2-D model at the nodes. In the coupled model, the 1-D model provides a good approximation with small computational effort, while the 2-D model is applied for complex topography to achieve a high accuracy. An Artificial Neural Network （ANN.） method is used for the data exchange and the connectivity between the 1-D and 2-D models. The coupled model is applied to the Jingjiang-Dongting Lake region, to simulate the tremendous looped channel network system, and the results are compared with field data. The good agreement shows that the coupled hydraulic model is more effective than the conventional 1-D model.
文摘A novel 2-D supramolecular network formed by the Fe3O building unit through three hydrogen bonds [Fe3O(O2CCH2OC6H5)6(3H2O)]NO3·2H2O (1) are presented. The title complex crystallizes in monoclinic, space group P21/n, with a=1.709 3(2) nm, b=3.152 9(3) nm, c=1.021 2(2) nm, V=5.503 5(14) nm3, Z=4, D(calc)=1.500 g·cm-3, F(000)=2 564. Each Fe3O unit is connected by three NO3-ions and inversely each NO3-ion is surrounded by three Fe3O moieties. It shows that the well-known Fe3O unit is a potential three H-donors and may be able to be a three-connected linker. This complex displays weak anti-ferromagnetic coupling between Fe(Ⅲ) centers. Electrochemical experiments were carried out to obtain the character of its redox reaction. CCDC: 222011.
基金X.Ji acknowledges funding from the National Natural Science Foundation of China(No.22001087)X.Ji also appreciates the support from the Huazhong University of Science and Technology,where he is being supported by Fundamental Research Funds for the Central Universities(Grant 2020kfyXJJS013)X.Ji appreciates support from the Interdisciplinary Research Program of HUST(2023JCYJ013).
文摘Comprehensive Summary Polycatenane gels have attracted extensive attention due to their high degree of freedom and mobility.However,the syntheses of poly[2]catenane gels reported to date all rely on the polymer as the backbone.Herein,we prepared poly[2]catenane gels based on entirely sequential assembly of small molecules.Monomer M1 with two unclosed rings was first prepared,which self-assembled to form supramolecular polymers(SPs)via hydrogen bonding andπ-πinteractions.Upon adding small molecule monomers M2 and M3 with aldehyde groups,ring closing of SPs occurred because the amino groups in the SPs reacted with M2 to form imine bonds.In addition,M3,which had twice the number of aldehyde groups as M2,enabled SPs to ring-close,causing the proceeding of crosslinking process at the same time.Thus linear SPs were transformed into poly[2]catenane gel networks.Due to the presence of hydrogen bonds in the poly[2]catenane gel,the gel also possessed stimulus responsiveness and self-healing properties.
