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Preparation of Composite Microporous Silica Membranes Using TEOS and 1,2-Bis(triethoxysilyl)ethane as Precursors for Gas Separation 被引量:2
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作者 漆虹 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2011年第3期404-409,共6页
This paper reports on a new microporous composite silica membrane prepared via acid-catalyzed polymeric route of sol-gel method with tetraethylorthosilicate(TEOS)and a bridged silsesquioxane[1,2-bis(triethoxysilyl)eth... This paper reports on a new microporous composite silica membrane prepared via acid-catalyzed polymeric route of sol-gel method with tetraethylorthosilicate(TEOS)and a bridged silsesquioxane[1,2-bis(triethoxysilyl)ethane, BTESE]as precursors.A stable nano-sized composite silica sol with a mean volume size of^5 nm was synthesized. A 150 nm-thick defect-free composite silica membrane was deposited on disk support consisting of macroporous α-Al2O3 and mesoporousγ-Al2O3 intermediate layer by using dip-coating approach,followed by calcination under pure nitrogen atmosphere.The composite silica membranes exhibit molecular sieve properties for small gases like H2,CO2,O2,N2,CH4 and SF6 with hydrogen permeances in the range of(1-4)×10 -7mol·m -2·s -1·Pa -1(measured at 200°C,3.0×105 Pa).With respect to the membrane calcined at 500°C,it is found that the permselectivities of H 2 (0.289 nm)with respect to N2(0.365 nm),CH4(0.384 nm)and SF6(0.55 nm)are 22.9,42 and>1000,respectively, which are all much higher than the corresponding Knudsen values(H2/N2=3.7,H2/CH4=2.8,and H2/SF6=8.5). 展开更多
关键词 TETRAETHYLORTHOSILICATE 1 2-bis(triethoxysilyl)ethane composite silica membranes gas separation mo- lecular sieving
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Kinetics on Thermal Decomposition of Iron(III) Complexes of 1,2-Bis(Imino-4’-Antipyrinyl)Ethane with Varying Counter Anions
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作者 Fikre Elemo Tesfay Gebretsadik +2 位作者 Mamo Gebrezgiabher Yosef Bayeh Madhu Thomas 《Advances in Chemical Engineering and Science》 2019年第1期1-10,共10页
A comparative thermal decomposition kinetic investigation on Fe(III) complexes of a antipyrine Schiff base ligand, 1,2-Bis(imino-4’-antipyrinyl)ethane (GA)), with varying counter anions viz. CIO4-, NO3-, SCN-, Cl-, a... A comparative thermal decomposition kinetic investigation on Fe(III) complexes of a antipyrine Schiff base ligand, 1,2-Bis(imino-4’-antipyrinyl)ethane (GA)), with varying counter anions viz. CIO4-, NO3-, SCN-, Cl-, and Br-, has been done by thermogravimetric analysis by using Coats-Redfern equation. The kinetic parameters like activation energy (E), pre-exponential factor (A) and entropy of activation (ΔS) were quantified. On comparing the various kinetic parameters, lower activation energy was observed in second stage as compared to first thermal decomposition stage. The same trend has been observed for pre-exponential factor (A) and entropy of activation (ΔS). The present results show that the starting materials having higher activation energy (E), are more stable than the intermediate products, however;the intermediate products possess well-ordered chemical structure due to their highly negative entropy of activation (ΔS) values. The present investigation proves that the counter anions play an important role on the thermal decomposition kinetics of the complexes. 展开更多
关键词 Iron(III) COMPLEXES 1 2-bis(Imino-4’-Antipyrinyl)ethane Thermal Decomposition KINETICS
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One-Pot Synthesis of N-Boc-2, 5-bis(trimethylsilyl)pyrrolidine
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作者 Dong, JC Li, RT Cheng, TM 《Chinese Chemical Letters》 SCIE CAS CSCD 2001年第12期1061-1064,共4页
N-Boc-2, 5-bis(trimethylsilyl)pyrrolidine 4 was synthesized from the reaction of N-Boc-pyrrolidine 1 with trimethylsilyl chloride (TMSCl) at optional temperature in one-pot in good yield.
关键词 N-Boc-2 5-bis(trimethylsilyl)pyrrolidine trimethylsilylATION ONE-POT
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An In Vitro and In Vivo Study of Thyroid Disruption of 1,2-Bis(2,4,6-tribromophenoxy)ethane(BTBPE)�A Novel Brominated Flame Retardant
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作者 Na Zheng Na Li +9 位作者 Lei Lei Biran Zhu Kun Qiao Qiangwei Wang Chengqian Liang Yongyong Guo Lihua Yang Jian Han Yuxi Zhou Bingsheng Zhou 《Environment & Health》 2024年第1期42-51,共10页
The novel brominated flame retardant,1,2-bis-(2,4,6-tribromophenoxy)ethane(BTBPE),is an emerging environ-mental pollutant with undetermined toxicity.We investigated how BTBPE causes thyroid endocrine disruption with i... The novel brominated flame retardant,1,2-bis-(2,4,6-tribromophenoxy)ethane(BTBPE),is an emerging environ-mental pollutant with undetermined toxicity.We investigated how BTBPE causes thyroid endocrine disruption with integrated in silico,in vitro,and in vivo assays.In yeast two-hybrid and T-Screen assays,BTBPE interacted with zebrafish thyroid hormone receptors with binding energies weaker than the TR agonist-3,3′,5-Triiodo-L-thyronine(T3),and disrupted thyroid function as a thyroid receptor(TR)agonist.We examined the bioconcentra-tion,developmental toxicity,and thyroid endocrine disruption in zebrafish after a 14-day exposure to BTBPE(1,3,10μg/L).Thyroxine(T4)was lower in BTBPE-treated larvae,whereas corticotropin-releasing hormone(CRH)and thyroid-stimulating hormone(TSH)were higher.The gene transcription alterations along the hypothalamic-pituitary-thyroid(HPT)axis were observed.Furthermore,reduced locomotion suggested that BTBPE imparts developmental neurotoxicity at zebrafish early developmental stage.Establishing that BTBPE has thyroid endocrine-disrupting effects is an important step for understanding and managing BTBPE toxicity. 展开更多
关键词 1 2-bis(4 6-tribromophenoxy)ethane THYROID endocrine disrupting developmental neurotoxicity yeast two-hybrid assay T-screen assay zebrafish larvae
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Synthesis,Spectra,X-ray Diffraction and Thermal Studies of New Zn(Ⅱ) Compounds Based on Dibenzoylmethane
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作者 FARZIN Marandi NASTARAN Shahinpour +1 位作者 QUAH CHING Kheng HOONG KUN Fun 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2016年第10期1582-1592,共11页
Two new zinc(Ⅱ) compounds with dibenzoylmethane and N-donor ancillary ligands,[Zn(μ-pyz)(dbm)_2]_n(1) and [Zn(dbm)_2(μ-bpe)Zn(dbm)_2](2)(Hdbm = dibenzoylmethane,pyz = pyrazine and bpe = 1,2-bis(4-... Two new zinc(Ⅱ) compounds with dibenzoylmethane and N-donor ancillary ligands,[Zn(μ-pyz)(dbm)_2]_n(1) and [Zn(dbm)_2(μ-bpe)Zn(dbm)_2](2)(Hdbm = dibenzoylmethane,pyz = pyrazine and bpe = 1,2-bis(4-pyridyl)ethane),have been prepared and characterized using elemental analysis,IR,~1H NMR and 13 C NMR spectroscopy,and studied by thermal gravimetric analysis as well as single-crystal X-ray diffraction. The crystal and molecular structures of 1 and 2 have been solved by X-ray diffraction and they turned out to be a one-dimensional coordination polymer with linear dispositions of metal atoms and binuclear compound,respectively. These one-dimensional polymers are further connected to form a 3D supramolecular network by C–H···O(only in 2) and π-π interactions. 展开更多
关键词 dibenzoylmethane 1 2-bis(4-pyridyl)ethane pyrazine zinc(Ⅱ)
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Oxidation reactivity of 1,2-bis(2,4,6-tribromophenoxy)ethane(BTBPE)by CompoundⅠmodel of cytochrome P450s 被引量:2
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作者 Zhongyu Wang Zhiqiang Fu +1 位作者 Qi Yu Jingwen Chen 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2017年第12期11-21,共11页
Alternative brominated flame retardants(BFRs) have become prevalent as a consequence of restrictions on the use of polybrominated diphenyl ethers(PBDEs). For risk assessment of these alternatives, knowledge of the... Alternative brominated flame retardants(BFRs) have become prevalent as a consequence of restrictions on the use of polybrominated diphenyl ethers(PBDEs). For risk assessment of these alternatives, knowledge of their metabolism via cytochrome P450 enzymes is needed.We have previously proved that density functional theory(DFT) is able to predict the metabolism of PBDEs by revealing the molecular mechanisms. In the current study, the reactivity of 1,2-bis(2,4,6-tribromophenoxy)ethane and structurally similar chemicals with the Compound I model representing the active site of P450 enzymes was investigated. The DFT calculations delineated reaction pathways which lead to reasonable explanations for products that were detected by wet experiments, meanwhile intermediates which cannot be determined were also proposed. Results showed that alkyl hydrogen abstraction will lead to bis(2,4,6-tribromophenoxy)ethanol, which may undergo hydrolysis yielding2,4,6-tribromophenol, a neurotoxic compound. In addition, a general pattern of oxidation reactivity regarding the 2,4,6-tribromophenyl moiety was observed among several model compounds. Our study has provided insights for convenient evaluation of the metabolism of other structurally similar BFRs. 展开更多
关键词 1 2-bis2 4 6-tribromophenoxy)ethane(BTBPE) Alternative brominated flame retardants Metabolic reactivity P450 Compound
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Syntheses,Structures and Luminescent Properties of Cd(Ⅱ)/Zn(Ⅱ) Coordination Polymers Based on the Flexible 4-Substituted Bis(1,2,4-triazole) Ligand 被引量:3
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作者 彭艳芬 刘天宝 吴秋艳 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2017年第7期1156-1163,共8页
Two new cadmium(II) and zinc(II) coordination polymers, {[Cd(btre)0.5- (mip)(H2O)2]·H2O}n (1) and [Zn(btre)(mip)]n (2), were synthesized at room temperature condition and characterized by IR spe... Two new cadmium(II) and zinc(II) coordination polymers, {[Cd(btre)0.5- (mip)(H2O)2]·H2O}n (1) and [Zn(btre)(mip)]n (2), were synthesized at room temperature condition and characterized by IR spectra, elemental analyses, single-crystal and powder X-ray diffractions (btre = 1,2-bis(1,2,4-triazol-4-yl)ethane, H2mip = 5-methyl-1,3-benzenedicarboxylic acid). Complex 1 belongs to the triclinic system, P space group, with a = 8.9830(6), b = 10.0579(6), c = 10.2479(9) , α = 98.837(6), β = 115.975(8), γ = 106.370(6)°, V = 756.30(11) 3 and Z = 2; complex 2 crystallizes in monoclinic, space group P21/c, with a = 7.0332(3), b = 14.9947(7), c = 15.9689(7) ?, β = 97.1170(10)°, V = 1671.12(13) ?3 and Z = 4. Compounds 1 and 2 based on the same N/O-donor ligands show different structures. The one-dimensional chains of 1 are further linked by hydrogen bonding and π-π interactions to yield a three-dimensional supramolecular structure. The two-dimensional (6,3) networks of 2 are further extended into a 3D framework via π-π interactions. Thermal stabilities and luminescence of 1 and 2 were investigated. 展开更多
关键词 1 2-bis(1 2 4-triazol-4-yl)ethane 2D (6 3) network luminescence coordination polymer
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Syntheses, Crystal Structures, and Fluorescence Properties of Two 2D→2D Coordination Polymers Based on the Flexible 4-Substituted Bis(1,2,4-triazole) Ligand
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作者 PENG Yanfen LIU Tianbao WU Qiuyan 《Wuhan University Journal of Natural Sciences》 CAS CSCD 2019年第1期8-14,共7页
Two new 2 D → 2 D zinc(II) coordination polymers, [Zn(btre)0.5(nbdc)(H2 O)]n(1) and {[Zn(btre)0.5(Me Oip)(H2 O)2]·H2 O}n(2)(btre = 1,2-bis(1,2,4-triazol-4-yl)ethane, nbdc=3-nitro-1, 2-benzenedicarboxylate, Me Oi... Two new 2 D → 2 D zinc(II) coordination polymers, [Zn(btre)0.5(nbdc)(H2 O)]n(1) and {[Zn(btre)0.5(Me Oip)(H2 O)2]·H2 O}n(2)(btre = 1,2-bis(1,2,4-triazol-4-yl)ethane, nbdc=3-nitro-1, 2-benzenedicarboxylate, Me Oip=4-methoxybenzene-1, 3-dicarboxylate) were synthesized at room temperature condition and characterized by IR spectra, elemental analyses, single-crystal and powder X-ray diffractions. Three sets of equivalent 2 D(6, 3) networks parallel polycatenated with each other to give a 2 D → 2 D network in 1 and 2. There are strong π-π interactions and hydrogen bonding interactions between adjacent parallel polycatenated 2 D(6, 3) network in 1. Only hydrogen bonding interactions exist in 2. Thermal stabilities and luminescence of 1 and 2 were investigated. 展开更多
关键词 3-fold INTERPENETRATION 1 2-bis(1 2 4-triazol-4-yl)ethane 2D(6 3)network luminescence
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