Garnet megacryst with a multiphase inclusion from intraplate alkali basalts of the Shavaryn Tsaram(Tariat,Mongolia)was the object of the study.This unusual aggregate consists of porous glass,Ti-rich biotite,orthopyrox...Garnet megacryst with a multiphase inclusion from intraplate alkali basalts of the Shavaryn Tsaram(Tariat,Mongolia)was the object of the study.This unusual aggregate consists of porous glass,Ti-rich biotite,orthopyroxene,spinel,clinopyroxene,olivine,and ilmenite.Win TWQ 2.32 thermodynamic simulation of this system revealed a few intervals of equilibrium.Pressure and temperature adjustment reflected in the paragenetic minerals of the melt pocket.The capture of already crystallised garnet megacryst was at P=0.8-1 GPa and T=1120-1160℃.Mineral crystallisation inside the melt pocket,accompanied by external inputs,occurred at P=0.75-0.95 GPa;T=790-1120℃.Symplectite assemblage formed in the garnet megacryst due to decomposition at(P=0.55-0.7 GPa;T=850-930℃).The study of the oxygen isotope content in primary garnet and biotite of the melt pocket showed that the δ^(18)O_(VSMOW) values are the same and correspond to that of typical mantle xenoliths.However,the chemical and microcomponent composition of the melt pocket minerals reveals a material that differs from basalts and peridotites.Thus,it has been revealed that the multiphase inclusion in the garnet megacryst formed not only on account of the garnet’s substance,but also due to the entrapped material of the Earth’s interior.展开更多
Currently,bimetallic selenates have attracted much attention as a prominent electrode composite material for supercapacitors owing to their higher redox chemistry and superior electrical conductivity.Herein,we synthes...Currently,bimetallic selenates have attracted much attention as a prominent electrode composite material for supercapacitors owing to their higher redox chemistry and superior electrical conductivity.Herein,we synthesized cobalt-magnesium selenates (CoSeO3-Mg Se O4,CMS) via a facile hydrothermal process,followed by selenization.At first,cobalt-magnesium oxide (Co2.32Mg0.68O4,CMO) was in situ prepared by a one-pot hydrothermal method.An investigation on the morphological change was performed by synthesizing the same CMO samples at different growth times by keeping the temperature constant.The CMO electrode designed for 8 h of growth time (CMO-8 h)with an attractive morphology showed a higher areal capacity of 101.7μAh cm-2(at 3 m A cm-2) than the other CMO electrodes prepared for 6 and 10 h.Further exalted performance was achieved by the selenization of the CMO-8 h sample to form the CMS material.At 3 m A cm-2,the resulted CMS exhibited nearly three times higher capacity,i.e.,385.4μAh cm-2,than the CMO-8 h electrode.Additionally,an asymmetric cell fabricated with CMS as a positive electrode also revealed good energy storage performance.Within the applied voltage between 0 and 1.5 V,the asymmetric cell demonstrated maximum energy density of 0.159 m Wh cm-2(18.6 Wh kg-1) and maximum power density of 18.47 m W cm-2(1938 W kg-1),respectively.Thus,novel magnesium-based metal selenates can act as an efficient electrode for energy storage.展开更多
文摘Garnet megacryst with a multiphase inclusion from intraplate alkali basalts of the Shavaryn Tsaram(Tariat,Mongolia)was the object of the study.This unusual aggregate consists of porous glass,Ti-rich biotite,orthopyroxene,spinel,clinopyroxene,olivine,and ilmenite.Win TWQ 2.32 thermodynamic simulation of this system revealed a few intervals of equilibrium.Pressure and temperature adjustment reflected in the paragenetic minerals of the melt pocket.The capture of already crystallised garnet megacryst was at P=0.8-1 GPa and T=1120-1160℃.Mineral crystallisation inside the melt pocket,accompanied by external inputs,occurred at P=0.75-0.95 GPa;T=790-1120℃.Symplectite assemblage formed in the garnet megacryst due to decomposition at(P=0.55-0.7 GPa;T=850-930℃).The study of the oxygen isotope content in primary garnet and biotite of the melt pocket showed that the δ^(18)O_(VSMOW) values are the same and correspond to that of typical mantle xenoliths.However,the chemical and microcomponent composition of the melt pocket minerals reveals a material that differs from basalts and peridotites.Thus,it has been revealed that the multiphase inclusion in the garnet megacryst formed not only on account of the garnet’s substance,but also due to the entrapped material of the Earth’s interior.
基金supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIP) (No. 2017H1D8A2031138 and No. 2018R1A6A1A03025708)。
文摘Currently,bimetallic selenates have attracted much attention as a prominent electrode composite material for supercapacitors owing to their higher redox chemistry and superior electrical conductivity.Herein,we synthesized cobalt-magnesium selenates (CoSeO3-Mg Se O4,CMS) via a facile hydrothermal process,followed by selenization.At first,cobalt-magnesium oxide (Co2.32Mg0.68O4,CMO) was in situ prepared by a one-pot hydrothermal method.An investigation on the morphological change was performed by synthesizing the same CMO samples at different growth times by keeping the temperature constant.The CMO electrode designed for 8 h of growth time (CMO-8 h)with an attractive morphology showed a higher areal capacity of 101.7μAh cm-2(at 3 m A cm-2) than the other CMO electrodes prepared for 6 and 10 h.Further exalted performance was achieved by the selenization of the CMO-8 h sample to form the CMS material.At 3 m A cm-2,the resulted CMS exhibited nearly three times higher capacity,i.e.,385.4μAh cm-2,than the CMO-8 h electrode.Additionally,an asymmetric cell fabricated with CMS as a positive electrode also revealed good energy storage performance.Within the applied voltage between 0 and 1.5 V,the asymmetric cell demonstrated maximum energy density of 0.159 m Wh cm-2(18.6 Wh kg-1) and maximum power density of 18.47 m W cm-2(1938 W kg-1),respectively.Thus,novel magnesium-based metal selenates can act as an efficient electrode for energy storage.
